Compound, drying agent, sealing structure, and organic el element
US-2015368279-A1 · Dec 24, 2015 · US
US8940905B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8940905-B2 |
| Application number | US-201013503292-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 6, 2010 |
| Priority date | Oct 23, 2009 |
| Publication date | Jan 27, 2015 |
| Grant date | Jan 27, 2015 |
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A process is described for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a hybrid solid with an organic-inorganic matrix, MOF—NH 2 , comprising: i/ introduction, in a polar solvent S1, of said crystallized hybrid solid MOF—NH 2 , of at least one organic compound Q containing a nitride function N 3 and at least one intermediate reagent R containing a nitrite function NO 2 , ii/ reaction of said reaction mixture, iii/ introduction in the reaction mixture of at least one reagent A bearing an alkyne function or an activated cyanide function, at least one Cu-based catalyst C and at least one polar solvent S2, iv/ reaction of said reaction mixture, v/ filtration and then washing and vi/ drying of said crystallized functionalized hybrid solid.
Opening claim text (preview).
The invention claimed is: 1. Process for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a crystallized hybrid solid with an organic-inorganic matrix, MOF—NH 2 , containing an inorganic network of metallic sites joined together at least by organic ligands comprising at least one aromatic ring, at least two carboxylate functions CO 2 − and at least one amine functio…
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