Hydrocracking catalyst for hydrocarbon oil, method for producing hydrocracking catalyst, and method for hydrocracking hydrocarbon oil with hydrocracking catalyst
US-9221036-B2 · Dec 29, 2015 · US
US8940652B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8940652-B2 |
| Application number | US-201213668429-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 5, 2012 |
| Priority date | Nov 4, 2011 |
| Publication date | Jan 27, 2015 |
| Grant date | Jan 27, 2015 |
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A phosphorus modification of an FCC catalyst is provided by reducing the sodium content of the as formed catalyst, a first treatment with a phosphate solution, a second ammonium exchange to further reduce the sodium content of the phosphorus solution treated catalyst and a second treatment with a phosphate solution.
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The invention claimed is: 1. A process for modifying an FCC zeolite catalyst with phosphorous comprising: exchanging an as-crystalized catalyst with an ammonium salt, so as to provide the catalyst with a sodium content of less than about 2% by weight Na 2 O, treating the ammonium-exchanged catalyst with a first phosphate solution, sufficient to add 0.5 to 2% by weight P 2 O 5 on the catalyst, ammonium ion exchanging the phosphorous treated catalyst to yield a low sodium catalyst h…
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