Electrode catalyst substrate and method for producing the same, and polymer electrolyte fuel cell

Patent metadata

Field	Value
Publication number	US-8940452-B2
Application number	US-66600308-A
Country	US
Kind code	B2
Filing date	Jun 25, 2008
Priority date	Jun 28, 2007
Publication date	Jan 27, 2015
Grant date	Jan 27, 2015

Abstract

A method for producing an electrode catalyst substrate is provided herein, which comprises a carbon film forming step of forming a porous carbon film on a base, a hydrophilization step of hydrophilizing the porous carbon film, an immersion step of immersing the base in a solution prepared by dissolving catalytic metal ions in a polar solvent, and a reduction step of adding a reducing agent to the solution and thus reducing the catalytic metal ions. An electrode catalyst substrate obtained by the method and a polymer electrolyte fuel cell in which the electrode catalyst obtained by the method is used for anodes and/or cathodes are also provided herein. In the electrode catalyst of the present invention, fine catalyst particles are loaded in a uniform and highly dispersed manner.

First claim

The invention claimed is:

1. A method for producing an electrode catalyst substrate, comprising:
a carbon film forming step of forming a porous carbon film on a base;
a hydrophilization step of hydrophilizing the porous carbon film;
an immersion step of immersing the porous carbon film in a liquid solution prepared by dissolving catalytic metal ions in a polar solvent; and
a reduction step of adding a liquid reducing agent to the liquid solution and then reducing the catalytic metal ions, wherein the temperature is increased while convecting the liquid solution in the coexistence of the liquid reducing agent.

2. The method for producing an electrode catalyst substrate according to claim 1 , wherein the carbon film forming step comprises forming a porous film of carbon nanotubes vertically aligned on the base.

3. The method for producing an electrode catalyst substrate according to claim 1 , wherein the hydrophilization step comprises hydrophilizing the porous carbon film by UV ozonation.

4. The method for producing an electrode catalyst substrate according to claim 1 , wherein the polar solvent is a liquid polar solvent.

5. The method for producing an electrode catalyst substrate according to claim 4 , wherein the liquid polar solvent is chosen from water, ethanol, methanol, 1-propanol, 2-propanol, butanol, ethylene glycol, and propylene glycol.

6. The method for producing an electrode catalyst substrate according to claim 1 , wherein the liquid reducing agent is chosen from ethanol, methanol, ethylene glycol, and propylene glycol.

Assignees

• Shinozaki Kazuma
• Okamoto Atsuhito
• Hatanaka Tatsuya
• Takahashi Hiroaki
• Terada Tomoaki
• Nagata Takahiro
• Toyota Motor Co Ltd
• Cataler Corp

Inventors

• Shinozaki Kazuma
• Okamoto Atsuhito
• Hatanaka Tatsuya
• Takahashi Hiroaki
• Terada Tomoaki
• Nagata Takahiro

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M4/885

  followed by reduction of the catalyst salt precursor · CPC title

• H01M4/8842

  Coating using a catalyst salt precursor in solution followed by evaporation and reduction of the precursor · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• H01M4/8605 Primary

  Porous electrodes · CPC title