Liquid crystal compound, liquid crystal composition and liquid crystal display device
US-2015376504-A1 · Dec 31, 2015 · US
US8933237B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8933237-B2 |
| Application number | US-201414156916-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 16, 2014 |
| Priority date | Jul 19, 2012 |
| Publication date | Jan 13, 2015 |
| Grant date | Jan 13, 2015 |
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Methods for synthesizing deuterated vinylpyridine compounds of the Formula (1), wherein the method includes: (i) deuterating an acyl pyridine of the Formula (2) in the presence of a metal catalyst and D 2 O, wherein the metal catalyst is active for hydrogen exchange in water, to produce a deuterated acyl compound of Formula (3); (ii) reducing the compound of Formula (3) with a deuterated reducing agent to convert the acyl group to an alcohol group, and (iii) dehydrating the compound produced in step (ii) with a dehydrating agent to afford the vinylpyridine compound of Formula (1). The resulting deuterated vinylpyridine compounds are also described.
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What is claimed is: 1. A method for synthesizing deuterated vinylpyridine compounds of the formula: wherein one of A 2 , A 3 , A 4 , A 5 , and A 6 is a vinyl group of the formula: wherein R 1 and R 2 are each independently either a deuterium atom or a perdeuterat…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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