Urea synthesis process and plant
US-9512069-B2 · Dec 6, 2016 · US
US8927770B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8927770-B2 |
| Application number | US-201214116258-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 3, 2012 |
| Priority date | May 10, 2011 |
| Publication date | Jan 6, 2015 |
| Grant date | Jan 6, 2015 |
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A process for the direct synthesis of urea from ammonia and carbon dioxide at high pressures and temperatures, with the formation of ammonium carbamate as intermediate, comprising a decomposition step of the ammonium carbamate and stripping of the gases formed, operating substantially at the same pressure as the synthesis step, wherein the recycled liquid streams are fed, at least partially, to the same decomposition and stripping step after being preheated by heat exchange with a stream included in the high-pressure synthesis cycle.
Opening claim text (preview).
The invention claimed is: 1. A process for the synthesis of urea from ammonia and carbon dioxide with the formation of ammonium carbamate as intermediate, comprising the following steps: (a) reacting ammonia and carbon dioxide as such or in the form of ammonium carbamate, with a NH 3 /CO 2 molar ratio ranging from 2.3 to 6, at temperatures ranging from 140 to 215° C. and pressures ranging from 12 to 25 MPa, with the formation of a first liquid mixture containing urea, ammonium ca…
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