Lithium-Ion Secondary Battery And Method For Forming Positive Electrode Active Material Particle

Patent metadata

Field	Value
Publication number	US-2025391843-A1
Application number	US-202519242066-A
Country	US
Kind code	A1
Filing date	Jun 18, 2025
Priority date	Jun 24, 2024
Publication date	Dec 25, 2025
Grant date	—

Abstract

A lithium-ion secondary battery with favorable charge and discharge cycle performance is provided. The lithium-ion secondary battery includes a positive electrode and a negative electrode. The positive electrode includes positive electrode active material particles containing magnesium, fluorine, and lithium cobalt oxide. When a surface of the positive electrode active material particle observed in a cross-sectional STEM image of a plane where lithium is inserted and extracted is a first layer, the positive electrode active material particle includes a region where magnesium is substituted for part of cobalt sites in a second layer to a sixth layer. Magnesium has a function of relieving a distortion between the layered rock-salt crystal structure and the rock-salt crystal structure, and fluorine has a function of promoting transfer of the magnesium into an inner portion of the positive electrode active material particle.

First claim

What is claimed is:

1 . A lithium-ion secondary battery comprising:
a positive electrode; and a negative electrode, wherein the positive electrode comprises a positive electrode active material particle comprising magnesium, fluorine, and lithium cobalt oxide, and wherein when a surface of the positive electrode active material particle observed in a cross-sectional STEM image of a plane where lithium is inserted and extracted is a first layer, the positive electrode active material particle comprises a region where magnesium is substituted for part of cobalt sites in a second layer, a third layer, a fourth layer, a fifth layer, and a sixth layer of the positive electrode active material particle, and wherein the fluorine exists closer to the surface than the region does.

2 . The lithium-ion secondary battery according to claim 1 ,
wherein the positive electrode active material particle comprises a region where part of the cobalt sites in the fourth layer observed in the cross-sectional STEM image of the plane where lithium is inserted and extracted is substituted with magnesium.

3 . The lithium-ion secondary battery according to claim 1 ,
wherein, in STEM-EDX line analysis on a surface portion of the positive electrode active material particle, a position of a maximum concentration (atomic %) of magnesium is closer to an inner portion than a position of a maximum concentration (atomic %) of fluorine is.

4 . The lithium-ion secondary battery according to claim 1 ,
wherein an atomic ratio of magnesium to cobalt (Mg/Co) in an inner portion is greater than or equal to 0.01 in electron probe microanalysis of the positive electrode active material particle.

5 . A lithium-ion secondary battery comprising:
a positive electrode; and a negative electrode, wherein the positive electrode comprises a positive electrode active material particle comprising magnesium, fluorine, aluminum, nickel, and lithium cobalt oxide, wherein the positive electrode active material particle comprises a layered rock-salt crystal structure in an inner portion and comprises a rock-salt crystal structure in a surface portion, and wherein when a surface of the positive electrode active material particle observed in a cross-sectional STEM image of a plane where lithium is inserted and extracted is a first layer, the positive electrode active material particle comprises a region where magnesium is substituted for part of cobalt sites in a second layer, a third layer, a fourth layer, a fifth layer, and a sixth layer of the positive electrode active material particle, and wherein the fluorine exists closer to the surface than the region does, wherein the aluminum exists in the inner portion of the positive electrode active material particle, and wherein the nickel exists in the surface portion of the positive electrode active material particle.

6 . The lithium-ion secondary battery according to claim 5 ,
wherein the positive electrode active material particle comprises a region where part of the cobalt sites in the fourth layer observed in the cross-sectional STEM image of the plane where lithium is inserted and extracted is substituted with magnesium.

7 . The lithium-ion secondary battery according to claim 5 ,
wherein, in STEM-EDX line analysis on a surface portion of the positive electrode active material particle, a position of a maximum concentration (atomic %) of magnesium is closer to an inner portion than a position of a maximum concentration (atomic %) of fluorine is.

8 . The lithium-ion secondary battery according to claim 5 ,
wherein an atomic ratio of magnesium to cobalt (Mg/Co) in an inner portion is greater than or equal to 0.01 in electron probe microanalysis of the positive electrode active material particle.

9 . A method for forming a positive electrode active material particle, the method comprising:
mixing lithium cobalt oxide, a magnesium source, a fluorine source, and a lithium source to form a mixture; and heating the mixture at higher than or equal to 650° C. and lower than or equal to 950° C. for longer than 100 hours.

10 . The method for forming a positive electrode active material particle according to claim 9 ,
wherein the heating is performed at higher than or equal to 826° C. and lower than or equal to 920° C. for longer than 100 hours and shorter than or equal to 150 hours.

Assignees

• Semiconductor Energy Lab

Inventors

• Takahashi Masahiro
• Momma Yohei
• Mikami Mayumi
• Saito Jo

Classifications

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/366

  as layered products · CPC title