Method for recycling perovskite-based photoelectric conversion element
US-10847324-B2 · Nov 24, 2020 · US
US2025382547A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2025382547-A1 |
| Application number | US-202418746373-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jun 18, 2024 |
| Priority date | Jun 18, 2024 |
| Publication date | Dec 18, 2025 |
| Grant date | — |
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A composition including a plurality of particles, the plurality of particles comprising: about 25% to about 93% by weight a water soluble carrier; about 5% to about 45% by weight a first hydrophobic conditioning compound having a weight average molecular weight greater than 1000 Da; about 0.5% to about 10% by weight a cationic polysaccharide; and nonionic surfactant; and wherein individual particles of the plurality of particles have a mass from about 1 mg to about 1 g.
Opening claim text (preview).
What is claimed: 1 . A composition comprising a plurality of particles, said plurality of particles comprising: about 25% to about 93% by weight a water soluble carrier; about 5% to about 45% by weight a first hydrophobic conditioning compound having a weight average molecular weight greater than 1000 Da; about 0.5% to about 10% by weight a cationic polysaccharide; and about 0.5% to about 20% by weight a nonionic surfactant; wherein individual particles of said plurality of particles have a mass from about 1 mg to about 1 g. 2 . The composition according to claim 1 , wherein said first hydrophobic conditioning compound comprises a branched polyester selected from the group of: a) a branched polyester having Formula 1 wherein: each A is independently a branched hydrocarbon chain comprising 4 to 100 carbon atoms; Q is selected from an alkyl chain comprising 1 to 30 carbon atoms and a hydrogen atom; T is a hydrogen atom or a —C(O)—R wherein each R is an alkyl chain comprising 1 to 30 carbon atoms; and n is an integer from 1 to about 100; b) a branched polyester having Formula 2 wherein: each n is independently an integer from 1 to about 100; each A is independently a branched hydrocarbon chain comprising 4 to 100 carbon atoms; each T is independently a hydrogen atom or a —C(O)—R wherein each R is an alkyl chain comprising 1 to 30 carbon atoms; each Y is independently a linking group selected from the group of oxygen and NR 2 , wherein each R 2 is independently selected from the group of hydrogen, or a C 1 -C 8 alkyl; and M is a polyalkylene glycol group; c) a branched polyester having Formula 3 wherein: the index n is an integer from 1 to about 100; T is a hydrogen or —C(O)—R 1 where in R 1 is an alkyl chain comprising from 7 to 21 carbon atoms; each A is independently a branched hydrocarbon chain comprising from 4 to 40 carbon atoms; Y is selected from the group of oxygen and NR 2 , wherein each R 2 is independently selected from the group of hydrogen, or a C 1 -C 5 alkyl; Q is selected from the group of: i) -B, ii) Z-X-Z-W, and iii) V-U-Z-X-Z-W; wherein B is a substituted C 1 -C 24 alkyl group; each Z is independently a substituted or unsubstituted divalent C 2 -C 40 alkylene radical; X is polysiloxane moiety; W is selected from the group of —OR 4 , each R 2 is independently selected from the group of hydrogen or a C 1 -C 8 alkyl; R 4 is selected from a hydrogen atom, a C 1 -C 24 alkyl group or a substituted C 1 -C 24 alkyl group; V is a C 1 -C 24 divalent alkylene radical or a substituted C 1 -C 24 divalent alkylene; U is —C(O)O— or —C(O)NH—; and d) a branched polyester having Formula 4 wherein: each index n is independently an integer from 1 to about 100; T is a hydrogen atom or —C(O)—R 1 where in R 1 is an alkyl chain comprising from 7 to 21 carbon atoms; each A is independently a branched hydrocarbon chain comprising from 4 to 40 carbon atoms; each Y is independently selected from the group of oxygen and NR 2 , wherein each R 2 is independently selected from the group of hydrogen or a C 1 -C 8 alkyl; M is selected from the group of: i) a C 1 -C 24 divalent linear or branched alkylene radical; ii) Z-X-Z, and iii) --(D-U-Z-X-Z-U) m -D- wherein: m is an integer from 1 to about 10; each Z is independently a substituted or unsubstituted divalent C 2 -C 40 alkylene radical; X is polysiloxane moiety; U is —C(O)O— or —C(O)NH—; and each D is independently a C 1 -C 24 divalent linear or branched alkylene radical; e) and mixtures thereof. 3 . The composition according to claim 2 , wherein said nonionic surfactant has a HLB from 8 to 15. 4 . The composition according to claim 3 , wherein said nonionic surfactant has a molecular weight less than 1000 Da. 5 . The composition according to claim 4 , wherein said plurality of particles comprises individual particles that comprise said water soluble carrier, said first hydrophobic conditioning compound, and said nonionic surfactant. 6 . The composition according to claim 1 , wherein said first hydrophobic conditioning compound comprises silicone. 7 . The composition according to claim 1 , wherein said plurality of particles further comprises a second hydrophobic conditioning compound having a weight average molecular weight greater than 1000 Da. 8 . The composition according to claim 7 , wherein said first hydrophobic conditioning compound comprises a branched polyester selected from the group of: a) a branched polyester having Formula 1 wherein: each A is independently a branched hydrocarbon chain comprising 4 to 100 carbon atoms; Q is selected from an alkyl chain comprising 1 to 30 carbon atoms and a hydrogen atom; T is a hydrogen atom or a —C(O)—R wherein each R is an alkyl chain comprising 1 to 30 carbon atoms; and n is an integer from 1 to about 100; b) a branched polyester having Formula 2 wherein: each n is independently an integer from 1 to about 100; each A is independently a branched hydrocarbon chain comprising 4 to 100 carbon atoms; each T is independently a hydrogen atom or a —C(O)—R wherein each R is an alkyl chain comprising 1 to 30 carbon atoms; each Y is independently a linking group selected from the group of oxygen and NR 2 , wherein each R 2 is independently selected from the group of hydrogen, or a C 1 -C 8 alkyl; and M is a polyalkylene glycol group; c) a branched polyester having Formula 3 wherein: the index n is an integer from 1 to about 100; is a hydrogen or —C(O)—R 1 where in R 1 is an alkyl chain comprising from 7 to 21 carbon atoms; each A is independently a branched hydrocarbon chain comprising from 4 to 40 carbon atoms; Y is selected from the group of oxygen and NR 2 , wherein each R 2 is independently selected from the group of hydrogen, or a C 1 -C 8 alkyl; Q is selected from the group of: i) -B, ii) Z-X-Z-W, and iii) V-U-Z-X-Z-W wherein B is a substituted C 1 -C 24 alkyl group; each Z is independently a substituted or unsubstituted divalent C 2 -C 40 alkylene radical; X is polysiloxane moiety; W is selected from the group of —OR 4 , each R 2 is independently selected from the group of hydrogen or a C 1 -C 8 alkyl; R
Powder; Flakes; Free-flowing mixtures; Sheets · CPC title
containing silicones · CPC title
Polyesters or polycarbonates · CPC title
Mixtures of non-ionic with cationic compounds · CPC title
Soft surfaces, e.g. textile · CPC title
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