Solid electrolytes

Patent metadata

Field	Value
Publication number	US-2025343260-A1
Application number	US-202318865771-A
Country	US
Kind code	A1
Filing date	May 11, 2023
Priority date	May 17, 2022
Publication date	Nov 6, 2025
Grant date	—

Abstract

A solution for forming a solid electrolyte, includes: a plurality of silicon oxide particles dissolved in a liquid medium. The silicon oxide particles are functionalized with organic moieties including: at least four non-hydrogen atoms, of which one atom is covalently bonded to a silicon atom of the silicon oxide particles, and a linkable functional group capable, after activation by a radical species, of forming a covalent bond by reaction with another identical linkable functional group. The organic moiety has at least two atoms, not part of the linkable functional group, that are bonded by a x bond to each other. A ratio of the number of the organic moieties to the number of silicon atoms comprised in the plurality of silicon oxide particles is at least 0.3, and an electrolyte compound.

First claim

1 .- 15 . (canceled)

16 . A solution for forming a solid electrolyte, the solution comprising:
a plurality of silicon oxide particles dissolved in a liquid medium, the silicon oxide particles being functionalized with organic moieties comprising: at least four non-hydrogen atoms, of which one atom is covalently bonded to a silicon atom of the silicon oxide particles, and a linkable functional group capable, after activation by a radical species, of forming a covalent bond by reaction with another identical linkable functional group, wherein the organic moiety comprises at least two atoms, not part of the linkable functional group, that are bonded by a π bond to each other, wherein a ratio of the number of said organic moieties to the number of silicon atoms comprised in the plurality of silicon oxide particles is at least 0.3, and an electrolyte compound.

17 . The solution according to claim 16 , wherein said ratio is from 0.4 to 0.9.

18 . The solution according to claim 16 , wherein the at least two atoms that are bonded by a π bond to each other are part of a π-conjugated system.

19 . The solution according to claim 16 , wherein the organic moiety comprises a linear organic chain comprising at least four atoms.

20 . The solution according to claim 16 , wherein the linkable functional group is separated from the silicon atom to which the organic moiety is bonded by an organic connector chain of at most 20 atoms.

21 . The solution according to claim 16 , wherein the linkable functional group is a vinyl group or a vinylidene group.

22 . The solution according to claim 16 , wherein the functionalized silicon oxide particles are obtainable by aging a precursor solution comprising an organosilane comprising a silicon atom attached to four groups, the four groups comprising the organic moiety and at least two alkoxy groups.

23 . The solution according to claim 22 , wherein the organosilane comprises 3-trimethoxysilylpropyl methacrylate.

24 . The solution according to claim 22 , wherein the precursor solution further comprises a tetra-alkoxysilane.

25 . A method for forming a solid electrolyte, the method comprising:
a) obtaining the solution for forming a solid electrolyte, the solution comprising: a plurality of silicon oxide particles dissolved in a liquid medium, the silicon oxide particles being functionalized with organic moieties comprising: at least four non-hydrogen atoms, of which one atom is covalently bonded to a silicon atom of the silicon oxide particles, and a linkable functional group capable, after activation by a radical species, of forming a covalent bond by reaction with another identical linkable functional group, wherein the organic moiety comprises at least two atoms, not part of the linkable functional group, that are bonded by a x bond to each other, wherein a ratio of the number of said organic moieties to the number of silicon atoms comprised in the plurality of silicon oxide particles is at least 0.3, and an electrolyte compound, b) adding, to the solution, a radical initiator adapted for forming the radical species for inducing said activation, and c) converting the radical initiator into the radical species.

26 . The method according to claim 25 , wherein step c) is performed while the solution has a pH of from 5 to 7.

27 . The method according to claim 25 , wherein said converting comprises illumination or heating of the solution.

28 . The method according to claim 25 , wherein the radical initiator comprises dimethoxy-2-phenylacetophenone, dibenzyol peroxide, or azobisisobutyronitril.

29 . A solid electrolyte comprising a porous silicon oxide matrix, and an electrolyte compound, covering walls of pores of the porous silicon oxide matrix,
wherein at least 30% of silicon atoms comprised in the silicon oxide matrix is separated from another silicon atom in the silicon oxide matrix by at least 4 atoms comprised in an organic linking chain.

30 . A battery comprising a solid electrolyte, the solid electrolyte comprising:
a porous silicon oxide matrix, and an electrolyte compound, covering walls of pores of the porous silicon oxide matrix, wherein at least 30% of silicon atoms comprised in the silicon oxide matrix is separated from another silicon atom in the silicon oxide matrix by at least 4 atoms comprised in an organic linking chain.

Assignees

• Imec Vzw
• Univ Hasselt

Inventors

• De Sloovere Dries
• Hardy An
• Van Bael Marlies
• Vereecken Philippe

Classifications

• H01M2300/0071

  Oxides · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• C08K5/07

  Aldehydes; Ketones · CPC title

• C08G77/02

  Polysilicates · CPC title

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title