Preparation method of positive electrode active material

Patent metadata

Field	Value
Publication number	US-2025336948-A1
Application number	US-202519187497-A
Country	US
Kind code	A1
Filing date	Apr 23, 2025
Priority date	Apr 25, 2024
Publication date	Oct 30, 2025
Grant date	—

Abstract

A method of preparing a positive electrode active material is disclosed. The method may include performing a co-precipitation reaction including a first step of reacting at a pH range of about pH 11 to about pH 12 and a second step of reacting at a pH lower than the first step for a mixture of a nickel precursor and a metal precursor to obtain a nickel-based composite hydroxide, mixing the nickel-based composite hydroxide, an anhydrous lithium hydroxide, an aluminum raw material, and a zirconium raw material and subjecting to a first heat treatment to produce hollow secondary particles, pulverizing the secondary particles, and adding and mixing the pulverized resultant, a cobalt coating raw material, and a zirconium coating raw material into an aqueous (e.g., water-soluble) solvent, and then performing a second heat treatment to obtain a positive electrode active material.

First claim

What is claimed is:

1 . A method of preparing a positive electrode active material, comprising:
performing a co-precipitation reaction comprising a first step of reacting at a pH range of about pH 11 to about pH 12 and a second step of reacting at a pH lower than the first step for a mixture of a nickel precursor and a metal precursor to obtain a nickel-based composite hydroxide having an average particle diameter of about 10 μm to about 20 μm, mixing the nickel-based composite hydroxide, an anhydrous lithium hydroxide, an aluminum raw material, and a zirconium raw material and subjecting to a first heat treatment to produce hollow secondary particles comprising layered lithium nickel-based composite oxide and having pores inside as secondary particles made by agglomerating a plurality of primary particles, pulverizing the secondary particles, and adding and mixing the pulverized resultant, a cobalt coating raw material, and a zirconium coating raw material into an aqueous solvent, and then performing a second heat treatment to obtain a positive electrode active material.

2 . The method as claimed in claim 1 , wherein:
a metal of the metal precursor is B, Ba, Ca, Ce, Co, Cr, Cu, Fe, Mg, Mn, Mo, Nb, Si, Sn, Sr, Ti, V, W, Y, Zn, or a combination thereof.

3 . The method as claimed in claim 1 , wherein:
an aluminum content of the aluminum raw material is about 0.8 mol % to about 1.5 mol % and a zirconium content of the zirconium raw material is about 0.1 mol % to about 0.3 mol % based on 100 mol % of a total metal of the nickel-based composite hydroxide, aluminum of the aluminum raw material, and zirconium of the zirconium raw material, and a ratio (Al/Zr) of the aluminum content to the zirconium content is greater than or equal to about 5.

4 . The method as claimed in claim 1 , wherein:
the nickel-based composite hydroxide is in an amorphous state.

5 . The method as claimed in claim 1 , wherein:
the aluminum raw material is aluminum oxide, and the zirconium raw material is zirconium oxide.

6 . The method as claimed in claim 1 , wherein:
based on 100 mol % of a total metal of the nickel-based composite hydroxide, aluminum of the aluminum raw material, zirconium of the zirconium raw material, cobalt of the cobalt coating raw material, and zirconium of the zirconium coating raw material, a cobalt content of the cobalt coating raw material is adjusted to be about 0.5 mol % to about 5 mol % and a zirconium content of the zirconium coating raw material is adjusted to be about 0.1 mol % to about 3 mol %.

7 . The method as claimed in claim 1 , wherein:
the first heat treatment is performed at about 700° C. to about 900° C. for about 4 hours to about 20 hours in an oxidizing gas atmosphere, and the second heat treatment is performed at about 500° C. to about 900° C. for about 10 hours to about 20 hours in an oxidizing gas atmosphere.

8 . The method as claimed in claim 1 , wherein:
the nickel-based composite hydroxide is represented by Chemical Formula 1:

wherein, in Chemical Formula 1, 0.6≤x1≤1, 0≤y1≤0.4, 0.9≤x1+y1≤1.1, and M 1 is one or more elements selected from among B, Ba, Ca, Ce, Co, Cr, Cu, Fe, Mg, Mn, Mo, Nb, Si, Sn, Sr, Ti, V, W, Y, and Zn.

9 . The method as claimed in claim 1 , wherein:
in the nickel-based composite hydroxide, based on 100 mol % of a total metal excluding lithium, a nickel content is about 80 mol % to about 99 mol %.

10 . The method as claimed in claim 1 , wherein:
an average particle diameter of the secondary particles is about 10 μm to about 20 μm, an average particle diameter of the plurality of primary particles constituting the secondary particles is about 1 μm to about 4 μm, and an average size of the pores inside the secondary particles is about 1 μm to about 9 μm.

11 . The method as claimed in claim 1 , wherein:
the positive electrode active material comprises core particles comprising layered lithium nickel-based composite oxide and in a form of single particles; and a coating layer on the surface of the core particles, wherein the coating layer comprises cobalt and zirconium.

12 . The method as claimed in claim 11 , wherein:
a cobalt content of the coating layer is about 0.5 mol % to about 5 mol % based on 100 mol % of a total metal excluding lithium in the positive electrode active material, and a zirconium content of the coating layer is about 0.1 mol % to about 3 mol % based on 100 mol % of a total metal excluding lithium in the positive electrode active material.

13 . The method as claimed in claim 11 , wherein:
the lithium nickel-based composite oxide of the core particles comprises aluminum and zirconium and has a nickel content of greater than or equal to about 60 mol %, an aluminum content of about 0.8 mol % to about 1.5 mol %, and a zirconium content of about 0.1 mol % to about 0.3 mol % based on 100 mol % of a total metal excluding lithium and a ratio (Al/Zr) of the aluminum content to the zirconium content of greater than or equal to about 5.

14 . The method as claimed in claim 11 , wherein:
the lithium nickel-based composite oxide is represented by Chemical Formula 11:

wherein, in Chemical Formula 11, 0.9≤a11≤1.2, 0.6≤x11≤0.991, 0≤y11≤0.391, 0.008≤z11≤0.015, 0.001≤w11≤0.003, 0.9≤x11+y11+z11+w11≤1.1, and 0≤b11≤0.1, M 1 is one or more elements selected from among B, Ba, Ca, Ce, Co, Cr, Cu, Fe, Mg, Mn, Mo, Nb, Si, Sn, Sr, Ti, V, W, Y, and Zn, and X is one or more elements selected from among F, P, and S.

15 . The method as claimed in claim 11 , wherein:
an average particle diameter of the core particles is about 1 μm to about 4 μm, and a thickness of the coating layer is about 5 nm to about 500 nm.

16 . A rechargeable lithium battery, comprising:
a positive electrode comprising a positive electrode active material prepared by the method as claimed in claim 1 ; a negative electrode; and an electrolyte.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Choi Seungyeon
• Kim Soohyeon
• Shin Dongwook
• Hong Soonkie
• Ha Jeuk
• Cha Minah
• Kim Minhan
• Lee Soonrewl

Classifications

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01G53/506

  with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8 · CPC title

• H01M10/052

  Li-accumulators · CPC title