Hydrogen production system and hydrogen production method

Patent metadata

Field	Value
Publication number	US-2025333853-A1
Application number	US-202318866720-A
Country	US
Kind code	A1
Filing date	Sep 14, 2023
Priority date	Dec 23, 2022
Publication date	Oct 30, 2025
Grant date	—

Abstract

A hydrogen production system and a hydrogen production method includes: a heat exchanger that heats steam by using a heating medium heated by thermal energy at 600° C. or higher; a high-temperature steam electrolysis device that electrolyzes steam at 600° C. or higher to produce hydrogen by applying, to a high-temperature steam electrolysis cell, a voltage lower than an electric potential at a thermal neutral point at which Joule heating caused by application of a current and heat absorption caused by electrolysis reaction are balanced; and a heating device that heats the high-temperature steam electrolysis device by the steam.

First claim

1 . A hydrogen production system comprising:
a heat exchanger that heats, when a heating medium is heated by thermal energy at 600° C. or higher, steam by using the heated heating medium; and a high-temperature steam electrolysis device that electrolyzes the steam at 600° C. or higher to produce hydrogen by applying, to a high-temperature steam electrolysis cell, a voltage lower than a voltage at a thermal neutral point at which Joule heating caused by application of a current and heat absorption caused by electrolysis reaction are balanced such that heat balance becomes 0.

2 . The hydrogen production system according to claim 1 , wherein the heat exchanger includes a first heat exchanger disposed on a steam supply path, and a second heat exchanger disposed on a downstream side with respect to the first heat exchanger on the steam supply path.

3 . The hydrogen production system according to claim 1 , wherein the heat exchanger heats the high-temperature steam electrolysis device by the steam at a temperature higher than an operating temperature of the high-temperature steam electrolysis device.

4 . The hydrogen production system according to claim 1 , wherein the heat exchanger compensates for thermal energy that is lost by endothermic reaction when the high-temperature steam electrolysis device produces hydrogen.

5 . The hydrogen production system according to claim 1 , wherein the high-temperature steam electrolysis device electrolyzes the steam to produce hydrogen by applying a voltage higher than OCV and lower than the voltage at the thermal neutral point to the high-temperature steam electrolysis cell.

6 . The hydrogen production system according to claim 1 , wherein steam having number of moles equal to or larger than number of moles required for producing hydrogen is supplied to the high-temperature steam electrolysis device.

7 . The hydrogen production system according to claim 1 , wherein the high-temperature steam electrolysis device includes an electrolyte layer, a hydrogen gas diffusion electrode layer, and an oxygen gas diffusion electrode layer, and the heat exchanger heats the hydrogen gas diffusion electrode layer by the steam and heats the oxygen gas diffusion electrode layer by at least one of the steam and heated air.

8 . The hydrogen production system according to claim 1 , wherein the heat exchanger controls at least one of a flow rate of the steam and a flow rate of the heating medium so that a temperature of the steam supplied to the high-temperature steam electrolysis device is higher than an operating temperature of the high-temperature steam electrolysis device.

9 . The hydrogen production system according to claim 1 , wherein a high-temperature gas cooled reactor is disposed as a heat source that is able to generate the thermal energy, and the heat exchanger heats steam by using a heating medium heated by thermal energy of high-temperature helium generated in the high-temperature gas cooled reactor.

10 . A hydrogen production method comprising the steps of:
generating thermal energy at 600° C. or higher; superheating steam to 600° C. or higher by using a heating medium heated by the thermal energy; heating a high-temperature steam electrolysis cell by the steam; and electrolyzing the steam to produce hydrogen by applying, to the high-temperature steam electrolysis cell, a voltage lower than a voltage at a thermal neutral point at which Joule heating caused by application of a current and heat absorption caused by electrolysis reaction are balanced such that heat balance becomes 0.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Matsuo Takeshi
• Asano Koji
• Nakagiri Motohiro
• Koshiro Ikumasa
• Hara Nobuhide
• Katta Masafumi
• Shimada Hiroyuki
• Mizutani Yasunobu
• Shin Woosuck

Classifications

• C25B9/23

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• C25B9/67

  Heating or cooling means · CPC title

• C25B11/031

  Porous electrodes · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B15/027

  Temperature · CPC title