Phenolic epoxy resin and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-2025333562-A1
Application number	US-202418751072-A
Country	US
Kind code	A1
Filing date	Jun 21, 2024
Priority date	Apr 29, 2024
Publication date	Oct 30, 2025
Grant date	—

Abstract

A phenolic epoxy resin and a method for manufacturing the same are provided. The method for manufacturing the phenolic epoxy resin includes: reacting cardanol and vanillin for a polycondensation reaction at a temperature ranging from 60° C. to 90° C. so as to form a phenolic resin; injecting the phenolic resin, epichlorohydrin, and a surfactant into a reactor; adding a first basic solution for a dehydration reaction at a temperature ranging from 55° C. to 65° C.; when an equivalent of a hydroxyl group of the phenolic resin is lower than 3% of the original equivalent of the hydroxyl group of the phenolic resin, adding a second basic solution for a ring-closure reaction at a temperature ranging from 60° C. to 70° C., so as to obtain a phenolic epoxy resin. The surfactant is an alcohol ether solvent.

First claim

What is claimed is:

1 . A method for manufacturing a phenolic epoxy resin, comprising:
reacting cardanol and vanillin for a polycondensation reaction at a temperature ranging from 60° C. to 90° C., so as to form a phenolic resin; injecting the phenolic resin, epichlorohydrin, and a surfactant into a reactor, wherein the surfactant is an alcohol ether solvent; adding a first basic solution into the reactor for a dehydration reaction at a temperature ranging from 55° C. to 65° C.; and when an equivalent of a hydroxyl group of the phenolic resin is lower than 3% of the original equivalent of the hydroxyl group of the phenolic resin, adding a second basic solution into the reactor for a ring-closure reaction at a temperature ranging from 60° C. to 70° C., so as to obtain a phenolic epoxy resin.

2 . The method according to claim 1 , wherein, based on a total weight of the phenolic resin being 100 phr, an addition amount of the epichlorohydrin ranges from 400 phr to 800 phr.

3 . The method according to claim 1 , wherein a molecular weight of the phenolic resin ranges from 4,000 g/mol to 10,000 g/mol.

4 . The method according to claim 1 , wherein the surfactant is selected from the group consisting of: ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, and propylene glycol monoethyl ether.

5 . The method according to claim 1 , wherein the first basic solution is added in a dropwise manner, and a total dripping time of the first basic solution ranges from 1.5 hours to 3.5 hours.

6 . The method according to claim 1 , wherein the second basic solution is added in a dropwise manner, and a total dripping time of the second basic solution ranges from 1 hour to 2.5 hours.

7 . The method according to claim 1 , wherein, after the dehydration reaction, the reactor is heated to over 65° C., and a pressure in the reactor ranges from 5 Torr to 400 Torr for dehydration.

8 . The method according to claim 1 , wherein, after the ring-closure reaction, the reactor is heated to over 75° C., and a pressure in the reactor ranges from 5 Torr to 400 Torr for dehydration.

9 . The method according to claim 8 , wherein, after the dehydration, the epichlorohydrin remained in the reactor is removed at a temperature ranging from 120° C. to 130° C.

10 . The method according to claim 9 , wherein, after removing the epichlorohydrin, an extract solvent is added into the reactor at a temperature ranging from 70° C. to 80° C., so as to obtain the phenolic epoxy resin.

11 . The method according to claim 10 , wherein the extract solvent is selected from the group consisting of: ethyl acetate, toluene, and methyl isobutyl ketone.

12 . The method according to claim 1 , wherein an equivalent of an epoxy group of the phenolic epoxy resin ranges from 250 g/equivalent to 350 g/equivalent.

13 . The method according to claim 1 , wherein a viscosity of the phenolic epoxy resin ranges from 10,000 cps to 15,000 cps.

14 . A phenolic epoxy resin formed from the method as claimed in claim 1 .

Assignees

• Nan Ya Plastics Corp

Inventors

• Yuan Ching-Yao
• Chen Chung-Yu
• Wu Chen-Hua
• Wu Jung-Tsu

Classifications

• C08G8/04

  of aldehydes · CPC title

• C08G59/022 Primary

  characterised by the preparation process or apparatus used · CPC title

• C08G59/08 Primary

  from phenol-aldehyde condensates · CPC title

• C08G59/025

  characterised by the purification methods used · CPC title

• C08G59/063 Primary

  with epihalohydrins · CPC title