Methane-oxygen battery system and method of use thereof

Patent metadata

Field	Value
Publication number	US-2025323298-A1
Application number	US-202519175341-A
Country	US
Kind code	A1
Filing date	Apr 10, 2025
Priority date	Apr 10, 2024
Publication date	Oct 16, 2025
Grant date	—

Abstract

A methane-oxygen battery system including an electrochemical cell including a positive electrode, a negative electrode, and an electrolyte; a reactor in fluid communication with the negative electrode; a fuel gauge; and a gas store including a first compartment in fluid communication with the positive electrode and configured to store oxygen, a second compartment in fluid communication with the negative electrode and configured to store carbon dioxide and water, a third compartment in fluid communication with the negative electrode or the reactor and configured to store methane, a first barrier between the first compartment and the second compartment, and a second barrier between the second compartment and the third compartment. The gas store and the electrochemical cell form a closed system. The fuel gauge is configured to determine a state of charge based on a position of at least one of the first barrier or the second barrier.

First claim

What is claimed is:

1 . A methane-oxygen battery system, comprising:
an electrochemical cell comprising
a positive electrode,
a negative electrode, and
an electrolyte between the positive electrode and the negative electrode;
a reactor in fluid communication with the negative electrode;
a fuel gauge; and
a gas store comprising
a first compartment in fluid communication with the positive electrode and configured to store oxygen,
a second compartment in fluid communication with the negative electrode and configured to store carbon dioxide and water,
a third compartment in fluid communication with the negative electrode or the reactor and configured to store methane,
a first barrier between the first compartment and the second compartment, and
a second barrier between the second compartment and the third compartment,
wherein the gas store and the electrochemical cell form a closed system; and

wherein the fuel gauge is configured to determine a state of charge based on a position of at least one of the first barrier or the second barrier.

2 . The methane-oxygen battery system of claim 1 , wherein the closed system has a constant volume;
wherein the reactor is a steam reforming reactor configured to convert methane and water to carbon monoxide and hydrogen, and to convert carbon monoxide and hydrogen to carbon dioxide and water; wherein the first barrier and the second barrier are each independently a movable piston, moveable partition, a flexible diaphragm, an elastic diaphragm, an inflatable bladder, or a combination thereof, wherein the methane-oxygen battery system is configured to passively generate a gas flow between the electrochemical cell and the gas store; wherein the electrochemical cell is configured to operate passively; wherein the electrolyte comprises a solid oxide electrolyte; wherein the electrolyte has an oxygen ion conductivity of 0.1 to 100 siemens per meter at 700° C.; wherein at least one of the reactor and the electrochemical cell are disposed in a thermal chamber; or a combination thereof.

3 . The methane-oxygen battery system of claim 1 , wherein the reactor is
configured to convert methane and water to carbon monoxide and hydrogen on discharge; and configured to convert carbon monoxide and hydrogen to methane and water on charge.

4 . The methane-oxygen battery system of claim 1 , wherein the (i) the oxygen; (ii) the carbon dioxide and the water; and (iii) the methane are configured to be pressure balanced in the gas store.

5 . The methane-oxygen battery system of claim 1 , wherein the (i) the oxygen; (ii) the carbon dioxide and the water; and (iii) the methane are configured to have a same pressure in the gas store.

6 . The methane-oxygen battery system of claim 1 , wherein the first compartment and the second compartment are configured to be pressure balanced, and the second compartment and the third compartment are configured to be pressure balanced.

7 . The methane-oxygen battery system of claim 1 , wherein the first compartment, the second compartment, the third compartment are configured to have the same pressure.

8 . The methane-oxygen battery system of claim 1 , wherein
the second compartment is in fluid communication with an outlet of the negative electrode of the electrochemical cell, and the third compartment is in fluid communication with an inlet of the negative electrode.

9 . The methane-oxygen battery system of claim 1 , wherein
the first compartment is configured to provide oxygen to the positive electrode on discharge, and is configured to store oxygen on charge, the second compartment is configured to store carbon dioxide and water on discharge, and is configured to provide carbon dioxide and water on charge, and the third compartment is configured to provide methane to the reactor on discharge, and is configured to store methane on charge.

10 . The methane-oxygen battery system of claim 1 , further comprising a heat exchanger configured to exchange heat between the reactor and the electrochemical cell.

11 . The methane-oxygen battery system of claim 1 , wherein the electrochemical cell comprises a plurality of electrochemical cells, wherein at least one electrochemical cell of the plurality of electrochemical cells is in electrical contact with an external circuit.

12 . The methane-oxygen battery system of claim 11 , wherein at least one electrochemical cell of the plurality of electrochemical cells is a removable electrochemical cell.

13 . The methane-oxygen battery system of claim 12 , wherein the at least one removable electrochemical cell is configured to be selectively isolated from the methane-oxygen battery system.

14 . The methane-oxygen battery system of claim 12 , wherein the at least one removable electrochemical cell is configured to be selectively isolated from the gas store.

15 . The methane-oxygen battery system of claim 12 , wherein the methane-oxygen battery system is configured to operate when the at least one removable electrochemical cell is isolated from the system and at least one electrochemical cell is not isolated from the system.

16 . The methane-oxygen battery system of claim 1 , further comprising a processor configured to receive information relating to the position of the first barrier and/or the second barrier, and to determine the state of charge based on the position of the first barrier and/or the second barrier.

17 . The methane-oxygen battery system of claim 1 , further comprising a second fuel gauge configured to determine a state of charge based on a mass of a gas in the gas store,
wherein the mass of the gas in the gas store comprises a mass of oxygen in the first compartment, a mass of carbon dioxide and water in the second compartment, a mass of methane in the third compartment, or a combination thereof.

18 . A battery fuel gauge configured to determine a state of charge of a methane-oxygen battery,
wherein the battery fuel gauge comprises (i) a processor configured to receive information relating to a position of a first barrier and/or a position of a second barrier of a gas store and to determine the state of charge based on the position of the first barrier and/or the position of the second barrier or (ii) a processor configured to receive information relating to a mass of a gas in a gas store, wherein the mass of the gas in the gas store comprises a mass of oxygen in a first compartment, a mass of carbon dioxide and water in a second compartment, a mass of methane in a third compartment, or a combination thereof, and to determine the state of charge based on the mass of the gas in the gas store; wherein the methane-oxygen battery comprises: an electrochemical cell comprising
a positive electrode,
a negative electrode, and
an electrolyte between the positive electrode and the negative electrode;
a reactor in fluid communication with the negative electrode; and the gas store comprising
a first compartment in fluid communication with the positive electrode and configured to store oxygen,
a second compartment in fluid communication with an outlet of the negative electrode and configured to store carbon dioxide and water,
a third compartment in fluid communication with an inlet of the negative electrode and configured to store methane,
the first barrier between the first compartment and the second compartment, and
the second barrier between the second compartment and the third compartment,
wherein the gas store and the electrochemical cell form a closed system.

Assignees

• Form Energy Inc

Inventors

• Manser Joseph S
• Reynolds Christopher Thomas
• Su Liang
• Perkins Nicholas

Classifications

• H01M8/0618

  Reforming processes, e.g. autothermal, partial oxidation or steam reforming · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/04007

  related to heat exchange · CPC title

• H01M8/0631 Primary

  Reactor construction specially adapted for combination reactor/fuel cell (hydrogen C01B3/00; reactors for physicochemical processes B01J19/00) · CPC title

• H01M8/2457

  with both reactants being gaseous or vaporised · CPC title