Decorative glow-in-the-dark concrete block
US-2024360047-A1 · Oct 31, 2024 · US
US2025275316A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2025275316-A1 |
| Application number | US-202318858287-A |
| Country | US |
| Kind code | A1 |
| Filing date | Feb 15, 2023 |
| Priority date | Apr 21, 2022 |
| Publication date | Aug 28, 2025 |
| Grant date | — |
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A light-emitting device, a spectroscope, and a method for producing a light-emitting member are provided. A light-emitting device including: a light-emitting element configured to emit first light; a light-emitting member disposed on a light emission side of the light-emitting element and including a resin and a light-emitting material, the light-emitting material being configured to absorb the first light and configured to emit second light having an emission peak wavelength from 800 nm to 1100 nm; and an optical thin film disposed on a light emission side of the light-emitting member and configured to reflect the first light and transmit the second light. In an emission spectrum of the light-emitting device, a first integrated value ratio Ib/Ia that is an integrated value Ib of emission intensity at a wavelength in a range from 550 nm to 600 nm with respect to an integrated value Ia of emission intensity at a wavelength in a range from 200 nm to less than 550 nm is in a range from 0 to 0.05, and a second integrated value ratio Ic/Ia that is an integrated value Ic of emission intensity at a wavelength in a range from 800 nm to 1100 nm with respect to the integrated value Ia is in a range from 0.75 to 30.
Opening claim text (preview).
What is claimed is: 1 .- 26 . (canceled) 27 . A light-emitting device comprising: a light-emitting element configured to emit first light having an emission peak wavelength in a range of 200 nm to 550 nm; a light-emitting member comprising a resin and a light-emitting material disposed on a light emission side of the light-emitting element and configured to absorb at least part of the first light, the light-emitting material being configured to emit second light having an emission peak wavelength in a range of 780 nm to 1100 nm; and an optical thin film disposed on a light emission side of the light-emitting member and configured to reflect the first light and transmit the second light, wherein in an emission spectrum of the light-emitting device, a first integrated value ratio Ib/Ia of an integrated value Ib of emission intensity at a wavelength in a range of 550 nm to 600 nm with respect to an integrated value Ia of emission intensity at a wavelength in a range of 200 nm to less than 550 nm is in a range of 0 to 0.05, and a second integrated value ratio Ic/Ia that is an integrated value Ic of emission intensity at a wavelength in a range of 800 nm to 1100 nm with respect to the integrated value Ia is in a range of 0.75 to 30. 28 . The light-emitting device according to claim 27 , further comprising: a light-transmissive member on the light emission side of the light-emitting member from which the second light exits, wherein the optical thin film is provided on one of an incident side of the light-transmissive member on which the second light is incident and a light emission side of the light-transmissive member from which the second light exits. 29 . The light-emitting device according to claim 27 , wherein the optical thin film is a dielectric multilayer film. 30 . The light-emitting device according to claim 27 , wherein the light-emitting material comprises a phosphor. 31 . The light-emitting device according to claim 30 , wherein the phosphor comprises an oxide phosphor having a composition represented by the following formula (I). (Mg 1-t1 M 1 t1 ) u1 (Ga 1-v1-x1-y1 M 2 v1 ) 2 O w1 :Cr x1 ,M 3 y1 (I) wherein M 1 is at least one element selected from the group consisting of Ca, Sr, Ba, Ni, and Zn, M 2 is at least one element selected from the group consisting of B, Al, In, and Sc, M 3 is at least one element selected from the group consisting of Eu, Ce, Tb, Pr, Nd, Sm, Yb, Ho, Er, Tm, and Mn, and t1, u1, v1, w1, x1, and y1 satisfy 0≤t1≤0.8, 0.7≤u1≤1.3, 0≤v1≤0.8, 3.7≤w1≤4.3, 0.02<x1≤0.3, 0≤y1≤0.2, and y1<x1. 32 . A light-emitting device comprising: a light-emitting element configured to emit first light having an emission peak wavelength in a range of 200 nm to 550 nm; and a light-emitting member disposed on a light emission side of the light-emitting element and comprising a resin and a light-emitting material, wherein the light-emitting material is configured to absorb at least part of the first light and configured to emit second light having an emission peak wavelength in a range of 780 nm to 1100 nm, the light-emitting member contains the light-emitting material in a range of 250 parts by mass to 500 parts by mass with respect to 100 parts by mass of the resin, and in an emission spectrum of the light-emitting device, a first integrated value ratio Ib/Ia that is an integrated value Ib of emission intensity at a wavelength in a range of 550 nm to 600 nm with respect to an integrated value Ia of emission intensity at a wavelength in a range of 200 nm to less than 550 nm is in a range of 0 to 0.05, and a second integrated value ratio Ic/Ia that is an integrated value Ic of emission intensity at a wavelength in a range of 800 nm to 1100 nm with respect to the integrated value Ia is in a range of 0.75 to 30. 33 . The light-emitting device according to claim 32 , wherein the light-emitting member comprises a scattering agent in an amount that is 1.0 mass % to 5.0 mass % with respect to a total amount of the light-emitting member. 34 . The light-emitting device according to claim 32 , further comprising an optical thin film disposed on a light emission side of the light-emitting member and configured to reflect the first light and transmit the second light. 35 . The light-emitting device according to claim 32 , further comprising a light-transmissive member on a light emission side of the light-emitting member from which the second light exits. 36 . The light-emitting device according to claim 34 , wherein the optical thin film is a dielectric multilayer film. 37 . The light-emitting device according to claim 32 , wherein the light-emitting material comprises a phosphor. 38 . The light-emitting device according to claim 33 , wherein the phosphor comprises an oxide phosphor having a composition represented by the following formula (I). (Mg 1-t1 M 1 t1 ) u1 (Ga 1-v1-x1-y1 M 2 v1 ) 2 O w1 :Cr x1 ,M 3 y1 (I) wherein M 1 is at least one element selected from the group consisting of Ca, Sr, Ba, Ni, and Zn, M 2 is at least one element selected from the group consisting of B, Al, In, and Sc, M 3 is at least one element selected from the group consisting of Eu, Ce, Tb, Pr, Nd, Sm, Yb, Ho, Er, Tm, and Mn, and t1, u1, v1, w1, x1, and y1 satisfy 0≤t1≤0.8, 0.7≤u1≤1.3, 0≤v1≤0.8, 3.7≤w1≤4.3, 0.02<x1≤0.3, 0≤y1≤0.2, and y1<x1. 39 . A light-emitting device comprising: a light-emitting element configured to emit first light having an emission peak wavelength in a range of 200 nm to 550 nm; and a light-emitting member disposed on a light emission side of the light-emitting element and comprising a resin and a light-emitting material, wherein, the light-emitting material is configured to absorb at least part of the first light and configured to emit second light having an emission peak wavelength in a range of 780 nm to 1100 nm, and in an emission spectrum of the light-emitting element, a third integrated value ratio Ic/Ia′ that is an integrated value Ic of emission intensity at a wavelength in a range of 800 nm to 1100 nm in an emission spectrum of the light-emitting device with respect to an integrated value Ia′ of emission intensity at a wavelength in a range of 200 nm to less than 550 nm is 0.13 or more. 40 . The light-emitting device according to claim 39 , further comprising an optical thin film disposed on a light emission side of the light-emitting member and configured to reflect the first light and transmit the second light. 41 . The light-emitting device according to claim 39 , wherein the light-emitting member comprises the light-emitting material in an amount that is 250 parts by mass to 500 parts by mass with respect to 100 parts by mass of the resin. 42 . The light-emitting device according to claim 39 , wherein the light-emitting member comprises a scattering agent in an amount that is 1.0 mass % to 5.0 mass % with respect to a total amount of the light-emitting member. 43 . The light-emitting device according to claim 39 , further comprising a light-transmissive member on a light emission side of the light-emitting member from which the second light exits. 44 . The light-emitting device according to claim 40 , wherein the optical thin film is a dielectric multilayer film. 45 . The light-emitting device according to claim 39 , wherein the light-emitting material comprises a phosphor. 46 . The light-emitting device according to claim 39 , wherein the phosphor comprises an oxide phosphor having a composition represe
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