Method of refining metal and method of fabricating positive electrode active material using the same

Patent metadata

Field	Value
Publication number	US-2025270673-A1
Application number	US-202519063480-A
Country	US
Kind code	A1
Filing date	Feb 26, 2025
Priority date	Feb 27, 2024
Publication date	Aug 28, 2025
Grant date	—

Abstract

Methods of refining metals and methods of manufacturing positive electrode active materials are disclosed. The methods of refining metal comprise preparing an acid solution that includes an impurity and metal, adding a filtration aid to the acid solution to make a precipitation reaction solution, and filtering the precipitation reaction solution to separate a liquid including the metal and a solid including the impurity and the filtration aid. The filtration aid includes one or more of silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), calcium hydroxide (Ca(OH) 2 ).

First claim

What is claimed is:

1 . A method of refining metal, the method comprising:
preparing an acid solution that includes a metal and an impurity; adding a filtration aid to the acid solution to make a precipitation reaction solution; and filtering the precipitation reaction solution to separate a liquid that includes the metal and a solid that includes the impurity and the filtration aid, wherein the filtration aid includes one or more of silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), and calcium hydroxide (Ca(OH) 2 ).

2 . The method of claim 1 , wherein the acid solution includes a lithium sulfate solution.

3 . The method of claim 1 , wherein making the precipitation reaction solution includes:
adding a neutralizer to the acid solution to prepare a neutralization solution; and adding the filtration aid to the neutralization solution to make the precipitation reaction solution, wherein neutralization solution is prepared at about 60° C. to about 90° C. for about 30 minutes to about 3 hours, and wherein the neutralizer includes one or more of NaOH, Na 2 CO 3 , NH 4 OH, and KOH.

4 . The method of claim 1 , wherein the acid solution has a pH of about 1 to about 5, and the precipitation reaction solution has a pH of about 8 to about 12.

5 . The method of claim 1 , wherein the precipitation reaction solution is made at about 20° C. to about 60° C. for about 20 minutes to about 1 hour.

6 . The method of claim 1 , wherein the filtration aid is added in an amount of about 1 to 30 parts by weight relative to 100 parts by weight of the precipitation reaction solution.

7 . The method of claim 1 , wherein the impurity has an average particle diameter (D 50 ) of about 0.1 μm to about 20 μm, and the filtration aid has an average particle diameter (D 50 ) of about 1 μm to about 50 μm.

8 . The method of claim 1 , wherein the acid solution is added with calcium hydroxide (Ca(OH) 2 ) or calcium carbonate (CaCO 3 ) to thereby produce gypsum (CaSO 4 ).

9 . The method of claim 1 , wherein filtering the precipitation reaction solution includes using a filter having a cut-off diameter (D 50 ) in a range of about 0.5 μm to about 10 μm.

10 . The method of claim 1 , wherein the liquid is reused in a second filtering of the precipitation reaction solution.

11 . A method of refining metal, the method comprising:
preparing a filter using an aqueous solution that includes a filtration aid such that the filter is coated with the filtration aid; preparing an acid solution that includes a metal and an impurity; adding a neutralizer to the acid solution to make a precipitation reaction solution; and filtering the precipitation reaction solution with the filter to separate a liquid including the metal and a solid including the impurity, wherein the filtration aid includes one or more of silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ).

12 . The method of claim 11 , wherein the filtration aid is included in the aqueous solution in an amount of about 1 to 30 parts by weight relative to 100 parts by weight of a solvent.

13 . The method of claim 11 , wherein the acid solution includes a lithium sulfate solution.

14 . The method of claim 11 , wherein the neutralizer includes one or more of NaOH, Na 2 CO 3 , NH 4 OH, and KOH.

15 . The method of claim 11 , wherein the acid solution has a pH of about 1 to about 5, and the precipitation reaction solution has a pH of about 8 to about 12.

16 . The method of claim 11 , wherein the precipitation reaction solution is made at about 60° C. to about 90° C. for about 30 minutes to about 3 hours.

17 . The method of claim 11 , wherein the impurity has an average particle diameter (D 50 ) of about 0.1 μm to about 20 μm, and the filtration aid has an average particle diameter (D 50 ) of about 1 μm to about 50 μm.

18 . The method of claim 11 , wherein the filter has a cut-off diameter of about 0.5 μm to about 10 μm.

19 . The method of claim 11 , wherein the liquid reused in a second filtering of a precipitation reaction solution.

20 . A method of manufacturing a positive electrode active material, the method comprising:
preparing a mixture of lithium and transition metal by mixing a transition metal precursor with a lithium precursor that is refined by the method of claim 1 ; and calcinating the mixture of lithium and transition metal.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Park Seongin
• Lee Youngjun
• Yoo Kwangyong
• Sohn Myungbeom
• Son Jongsung
• You Yongchan

Classifications

• B01J20/041

  Oxides or hydroxides · CPC title

• C22B23/0461

  by chemical methods · CPC title

• C22B47/00

  Obtaining manganese · CPC title

• C22B26/12

  Obtaining lithium · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title