Stabilizing aqueous inkjet ink compositions
US-2024400846-A1 · Dec 5, 2024 · US
US2025270411A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2025270411-A1 |
| Application number | US-202318857279-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 1, 2023 |
| Priority date | May 10, 2022 |
| Publication date | Aug 28, 2025 |
| Grant date | — |
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An aqueous inkjet ink composition containing a pigment, an anionic group-containing resin, a resin emulsion, a surfactant, a water-soluble solvent, and water, in which a water-soluble solvent having a boiling point of at most 200° C. under 1 atm accounts for at least 90 mass % of the water-soluble solvent; the surfactant contains a polyoxyethylene alkyl ether and a silicone-based surfactant satisfying a specific condition; and the polyoxyethylene alkyl ether has an HLB value of 7-12. The aqueous inkjet ink composition has excellent discharge stability, favorable filling in a solid part and no unevenness even when printed and recorded on a non-absorptive print medium, and excellent drying properties on a paper surface.
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What is claimed is: 1 . An aqueous inkjet ink composition comprising a pigment; an anionic group-containing resin; a resin emulsion; a surfactant; a water-soluble solvent; and water, wherein the water-soluble solvent contains a water-soluble solvent having a boiling point of 200° C. or less at 1 atmospheric pressure at 90% by mass or more, the surfactant contains a polyoxyethylene alkyl ether and a silicone-based surfactant, the polyoxyethylene alkyl ether has an HLB value of 7 or more and 12 or less, and the silicone-based surfactant satisfies the following requirements: a maximum value of a transmittance of a mixture composed of 99.9 parts by mass of water and 0.1 parts by mass of the silicone-based surfactant at 25° C. and a wavelength of 380 nm to 780 nm is 30% or less, and a maximum value of a transmittance of a mixture composed of 89.9 parts by mass of water, 10 parts by mass of diethylene glycol monobutyl ether, and 0.1 parts by mass of the silicone-based surfactant at 25° C. and a wavelength of 380 nm to 780 nm is 95% or more. 2 . The aqueous inkjet ink composition according to claim 1 , further comprising one or more surfactants selected from the group consisting of an acetylene diol-based surfactant and an alkane diol-based surfactant. 3 . The aqueous inkjet ink composition according to claim 1 , wherein the water-soluble solvent having a boiling point of 200° C. or less at 1 atmospheric pressure is propylene glycol. 4 . The aqueous inkjet ink composition according to claim 1 , wherein the resin emulsion is one or more selected from the group consisting of an acrylic resin emulsion and a styrene-acrylic resin emulsion. 5 . The aqueous inkjet ink composition according to claim 1 , wherein a glass transition temperature of a resin in the resin emulsion is-35° C. or more and 35° C. or less. 6 . The aqueous inkjet ink composition according to claim 1 , wherein the polyoxyethylene alkyl ether is a branched chain having an alkyl group having 10 or more and 15 or less carbon atoms, and has an average number of moles of ethyleneoxy groups added of 3 or more and 10 or less. 7 . A printed matter obtained by performing printing using the aqueous inkjet ink composition according to claim 1 . 8 . The aqueous inkjet ink composition according to claim 2 , wherein the water-soluble solvent having a boiling point of 200° C. or less at 1 atmospheric pressure is propylene glycol. 9 . The aqueous inkjet ink composition according to claim 2 , wherein the resin emulsion is one or more selected from the group consisting of an acrylic resin emulsion and a styrene-acrylic resin emulsion. 10 . The aqueous inkjet ink composition according to claim 2 , wherein a glass transition temperature of a resin in the resin emulsion is −35° C. or more and 35° C. or less. 11 . The aqueous inkjet ink composition according to claim 2 , wherein the polyoxyethylene alkyl ether is a branched chain having an alkyl group having 10 or more and 15 or less carbon atoms, and has an average number of moles of ethyleneoxy groups added of 3 or more and 10 or less. 12 . A printed matter obtained by performing printing using the aqueous inkjet ink composition according to claim 2 .
from unsaturated acids or derivatives thereof · CPC title
Pigment inks · CPC title
characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title
Silicon compounds · CPC title
Ethers, e.g. polyglycol ethers of alcohols or phenols · CPC title
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