Process and system for additive manufacturing of carbon scaffolds

Patent metadata

Field	Value
Publication number	US-2025262794-A1
Application number	US-202318857615-A
Country	US
Kind code	A1
Filing date	Apr 20, 2023
Priority date	Apr 20, 2022
Publication date	Aug 21, 2025
Grant date	—

Abstract

A process for additive manufacturing of a nanocomposite is disclosed. The process includes providing a uniform filament comprising a carbon fiber material and a polymer binder; dispensing the uniform filament to form a preform architecture that defines a first 3-dimensional bulk structure having a first set of volume-defining dimensions; heating the preform architecture to remove the polymer binder, thereby forming a porous carbon scaffold; and incorporating a matrix material into the porous carbon scaffold to form a third 3-dimensional bulk structure. The carbon scaffold defines a second 3-dimensional bulk structure having a second bulk volume, wherein the second bulk volume is equal to the first bulk volume within a tolerance of 10%. A system for additive manufacturing of a fiber reinforced composite is also disclosed. The system has a filament dispenser; means for moving the filament dispenser; a heater; and a matrix material applicator.

First claim

What is claimed:

1 . A process for additive manufacturing of a nanocomposite, comprising:
providing a uniform filament comprising a carbon fiber material and a polymer binder; dispensing the uniform filament to form a preform architecture that defines a first 3-dimensional bulk structure having a first set of volume-defining dimensions; heating the preform architecture to remove the polymer binder, thereby forming a porous carbon scaffold that defines a second 3-dimensional bulk structure having a second bulk volume, wherein the second bulk volume is equal to the first bulk volume within a tolerance of 10%; and incorporating a matrix material into the porous carbon scaffold to form a third 3-dimensional bulk structure.

2 . The process of claim 1 , wherein the carbon fiber material comprises one or more carbon nanopowder, carbon nanotubes (CNTs), nanoflakes, graphene, graphite, copper, micro diamonds, aluminum nitride, boron nitride, SiC fibers, and chopped virgin or recycled carbon fibers.

3 . The process of claim 1 , wherein the matrix material comprises a material selected from the group consisting of: thermosetting polymer, thermoplastic, metal, ceramic material, and combinations thereof.

4 . The process of claim 3 , wherein the matrix material comprises a material selected from the group consisting of: epoxy, polysiloxane, and combinations thereof.

5 . The process of claim 3 , wherein when the matrix material comprises thermosetting polymer or metal, and the matrix material is infiltrated into the porous carbon scaffold in a liquid or molten form.

6 . The process of claim 3 , wherein when the matrix material comprises ceramic, and the matrix material is incorporated into the porous carbon scaffold as a ceramic precursor solution or preceramic polymer.

7 . The process of claim 1 , wherein the matrix material comprises a thermosetting polymer, the thermosetting polymer comprising an epoxy.

8 . The process of claim 7 , wherein the epoxy comprises a two-part system comprising a resin and a curing agent, and the method comprises mixing the resin and the curing agent prior to incorporating the matrix material into the porous carbon scaffold.

9 . The process of claim 1 , wherein providing the uniform filament comprises mixing the carbon fiber material and the polymer binder into a homogenous mixture, drying the homogenous mixture to form pellets, and extruding the pellets to form the uniform filament.

10 . The process of claim 9 , wherein the carbon fiber material comprises carbon nanotubes (CNTs) and the uniform filament is extruded in a printing direction, wherein the CNTs in the extruded filament are oriented along the printing direction.

11 . The process of claim 10 , wherein the uniform filament is extruded through a nozzle that causes shear-induced alignment of the CNTs.

12 . The process of claim 11 , wherein the CNTs in the extruded uniform filament form a locally aligned, globally distributed structure, in which the CNTs and the polymer binder form an interconnected molecular network with CNT/polymer-binder entanglement.

13 . The process of claim 12 , wherein the fiber material is a functionalized fiber material comprising a percentage of functional groups that form hydrogen bonds between the polymer binder and the functional groups in the interconnected molecular network.

14 . The process of claim 9 , wherein heating the preform architecture comprises carbonizing the preform architecture in an inert atmosphere at 1100° C.

15 . The process of claim 1 , wherein the step of dispensing the matrix material comprises applying vacuum pressure to drive the matrix material into the carbon scaffold.

16 . The process of claim 16 , further comprising curing the matrix material to form the nanocomposite after dispensing the matrix material into the carbon scaffold.

17 . The process of any one of the foregoing claims , wherein the fiber material comprises carbon nanotubes and the polymer binder comprises a polylactic-acid (PLA) biopolymer.

18 . The process of claim 18 , wherein the uniform filament comprises greater than 25% fiber material by weight.

19 . The process of claim 18 wherein the uniform filament comprises greater than 30% fiber material by weight.

20 . The process of claim 1 , wherein dispensing the uniform filament to form the preform architecture comprises dispensing a plurality of layers of uniform filament, one layer on top of another.

21 . The process according to claim 1 , comprising performing the process using a printing head attached to an automated robot arm having at least three degrees of freedom, wherein the printing head includes the uniform filament, a guide for disposing the filament in a desired location, a heater spaced from the guide for curing the polymer material in the uniform filament, and a dispenser for dispensing the matrix material at a distance from the heater.

22 . The process of claim 1 , including forming the 3-dimensional structure with a tunable geometry.

23 . A nanocomposite material comprising a product of the process of claim 1 .

24 . The nanocomposite material of claim 23 , wherein the nanocomposite material comprises a monolithic catalyst, a battery electrode, a sensor, or a combination thereof.

25 . A system for additive manufacturing of a fiber reinforced composite, the system comprising:
a filament dispenser configured to extrude a homogenous mixture of fiber material comprising carbon nanotubes (CNTs) and polymer binder through a nozzle to form a uniform filament; means for moving the filament dispenser relative to a dispensing location in a filament deposition direction to form a preform architecture defining a bulk 3-dimensional structure having a first bulk volume with the CNTs shear-aligned in the filament deposition direction; a heater configured to heat the preform architecture to remove the polymer binder, thereby forming a porous carbon scaffold defining a second 3-dimensional bulk structure having a second bulk volume, wherein the second bulk volume is equal to the first bulk volume within a tolerance of 10%; and a matrix material applicator configured to incorporate a matrix material into the porous carbon scaffold.

Assignees

• Univ Delaware

Inventors

• Fu Kun
• Zhang Chunyan

Classifications

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• B28B11/00

  Apparatus or processes for treating or working the shaped {or preshaped} articles (specially adapted for tubular articles B28B21/92; decoration or surface treatment in general B05, B44; compacting concrete in situ in connection with building E04G21/06; drying F26) · CPC title

• C08J5/243

  using carbon fibres · CPC title

• B33Y40/20

  Post-treatment, e.g. curing, coating or polishing · CPC title

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title