Method and system for estimating electrode density in secondary batteries

Patent metadata

Field	Value
Publication number	US-2025244219-A1
Application number	US-202418789174-A
Country	US
Kind code	A1
Filing date	Jul 30, 2024
Priority date	Jan 30, 2024
Publication date	Jul 31, 2025
Grant date	—

Abstract

A method of estimating an electrode density in secondary batteries according to one or more embodiments of the present disclosure includes: preparing an electrode comprising a current collector and first and second coating layers coated on the current collector; measuring first characteristic values of the electrode; removing the first coating layer of the electrode; measuring second characteristic values of the electrode from which the first coating layer has been removed; removing the second coating layer of the electrode from which the first coating layer has been removed; measuring third characteristic values of the electrode from which the first and second coating layer have been removed; and estimating at least one of a density of the first or second coating layer, a thickness of the current collector, or a weight of the current collector, based on the first characteristic values, the second characteristic values, and the third characteristic values.

First claim

What is claimed is:

1 . A method of estimating an electrode density in secondary batteries, the method comprising:
preparing an electrode comprising a current collector and first and second coating layers coated on the current collector; measuring first characteristic values of the electrode; removing the first coating layer of the electrode; measuring second characteristic values of the electrode from which the first coating layer has been removed; removing the second coating layer of the electrode from which the first coating layer has been removed; measuring third characteristic values of the electrode from which the first coating layer and the second coating layer have been removed; and estimating at least one of a density of the first coating layer, a density of the second coating layer, a thickness of the current collector, or a weight of the current collector, based on the first characteristic values, the second characteristic values, and the third characteristic values.

2 . The method as claimed in claim 1 , wherein the first characteristic values, the second characteristic values, and the third characteristic values each comprise a weight value and a thickness value.

3 . The method as claimed in claim 1 , wherein the current collector comprises at least one of an aluminum (Al) foil and a copper (Cu) foil.

4 . The method as claimed in claim 1 , wherein the electrode is cut to a set size using a punching machine or a laser cutter.

5 . The method as claimed in claim 1 , wherein each of the first coating layer and the second coating layer comprises at least one of nickel (Ni), cobalt (Co), manganese (Mn), and iron (Fe).

6 . The method as claimed in claim 1 , wherein each of the first coating layer and the second coating layer comprises graphite or silicon (Si).

7 . The method as claimed in claim 1 , wherein the removing of the first coating layer comprises removing the first coating layer by repeatedly emitting a pulsed laser toward the first coating layer.

8 . The method as claimed in claim 4 , wherein the estimating comprises determining whether there is a measurement anomaly associated with the electrode, based on an estimated thickness of the current collector, an estimated weight of the current collector, a theoretical weight of the current collector, and a theoretical thickness of the current collector.

9 . The method as claimed in claim 8 , wherein the determining of whether there is the measurement anomaly comprises determining that the electrode is not cut to the set size or the current collector is stretched in a case where the estimated weight of the current collector is about equal to the theoretical weight of the current collector and the estimated thickness of the current collector is not equal to the theoretical thickness of the current collector.

10 . The method as claimed in claim 8 , wherein the determining of whether there is the measurement anomaly comprises determining that the electrode is not cut to the set size in a case where the estimated thickness of the current collector is about equal to the theoretical thickness of the current collector and the estimated weight of the current collector is not equal to the theoretical weight of the current collector.

11 . The method as claimed in claim 8 , wherein the determining of whether there is the measurement anomaly comprises determining that the current collector is stretched in a case where the estimated thickness of the current collector is not equal to the theoretical thickness of the current collector and the estimated weight of the current collector is not equal to the theoretical weight of the current collector.

12 . The method as claimed in claim 8 , wherein the estimating comprises:
in response to determining that there is no measurement anomaly, estimating the density of the first coating layer and the density of the second coating layer; comparing the estimated density of the first coating layer to a target coating layer density; and comparing the estimated density of the second coating layer to a target coating layer density.

13 . The method as claimed in claim 1 , wherein the estimating comprises estimating the density of the first coating layer based on the first characteristic values and the second characteristic values.

14 . The method as claimed in claim 1 , wherein the estimating comprises estimating the density of the second coating layer based on the second characteristic values and the third characteristic values.

15 . The method as claimed in claim 1 , wherein the estimating comprises estimating the weight and thickness of the current collector based on the third characteristic values.

16 . The method as claimed in claim 1 , wherein the estimating comprises:
estimating the weight and thickness of the first coating layer based on the first characteristic values and the second characteristic values; estimating the weight and thickness of the second coating layer based on the second characteristic values and the third characteristic values; estimating the weight of the current collector based on at least a portion of the first characteristic values, the weight of the first coating layer, and the weight of the second coating layer; and estimating the thickness of the current collector based on at least a portion of the first characteristic values, the thickness of the first coating layer, and the thickness of the second coating layer.

17 . The method as claimed in claim 16 , further comprising:
estimating the density of the current collector based on the weight of the current collector and the thickness of the current collector; and comparing the density of the current collector to a normal density range.

18 . The method as claimed in claim 1 , wherein a first side of the current collector is coated with the first coating layer, and
a second side of the current collector opposite the first side is coated with the second coating layer.

19 . A non-transitory computer-readable recording medium storing instructions for executing the method as claimed in claim 1 on a computer.

20 . A system for estimating electrode density for secondary batteries, the system comprising:
a measuring device configured to measure characteristic values related to an electrode comprising a current collector and first and second coating layers coated on the current collector; a remover configured to remove at least one of the first coating layer or the second coating layer of the electrode; and at least one processor configured to estimate data related to the electrode, wherein: the measuring device is configured to measure first characteristic values of the electrode, to measure second characteristic values of the electrode from which the first coating layer has been removed by the remover, and to measure third characteristic values of the electrode from which the first coating layer and the second coating layer have been removed by the remover, and the at least one processor is configured to estimate at least one of a density of the first coating layer, a density of the second coating layer, a thickness of the current collector, or a weight of the current collector, based on the first characteristic values, the second characteristic values, and the third characteristic values.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Sohn Myungbeom
• You Yongchan
• Lee Youngjun
• Yoo Kwangyong
• Park Seongin

Classifications

• H01M4/24

  Electrodes for alkaline accumulators · CPC title

• H01M4/14

  Electrodes for lead-acid accumulators · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• G01D21/02 Primary

  Measuring two or more variables by means not covered by a single other subclass · CPC title