Flowable luminescent coating composition and use thereof

Patent metadata

Field	Value
Publication number	US-2025236740-A1
Application number	US-202418421109-A
Country	US
Kind code	A1
Filing date	Jan 24, 2024
Priority date	Jan 24, 2024
Publication date	Jul 24, 2025
Grant date	—

Abstract

A flowable luminescent coating composition includes a curable thermoset resin, a filler material, two or more solvents, a plasticizer, a stabilizer, phosphorescent aluminate particles. The phosphorescent aluminate particles are present in the flowable luminescent coating composition at a concentration of 30 to 70% by weight of the composition. The composition in a cured form has an intensity of glow of 1-50 candelas per square meter for a period of 0.1 to 2 hours upon excitation with ultraviolet light for 5 to 120 seconds. A glow-in-the-dark (GiD) film, a GiD traffic sign, and a GiD system.

First claim

1 : A flowable luminescent coating composition, comprising:
a curable thermoset resin; a filler material; two or more solvents; a plasticizer; a stabilizer; phosphorescent aluminate particles; wherein the phosphorescent aluminate particles are present in the flowable luminescent coating composition at a concentration of 30 to 70 wt. % based on a total weight of the flowable luminescent coating composition; wherein the phosphorescent aluminate particles and the filler material are suspended in a liquid mixture comprising the curable thermoset resin, the two or more solvents, the plasticizer, and the stabilizer; and wherein the flowable luminescent coating composition in a cured form has an intensity of glow of 1-50 candelas per square meter for a period of 0.1 to 2 hours upon excitation with ultraviolet (UV) light for 5 to 120 seconds.

2 : The flowable luminescent coating composition of claim 1 , wherein the phosphorescent aluminate particles have an average particle size of 5 to 25 micrometers (μm).

3 : The flowable luminescent coating composition of claim 1 , wherein the phosphorescent aluminate particles comprise a rare earth element doped strontium aluminate.

4 : The flowable luminescent coating composition of claim 3 , wherein the rare earth element is at least one selected from the group consisting of cerium, dysprosium, europium, and neodymium.

5 : The flowable luminescent coating composition of claim 3 , wherein the rare earth element doped strontium aluminate further comprises a promoter selected from the group consisting of boron, lithium, sodium, potassium, magnesium, calcium, barium, chromium, and manganese.

6 : The flowable luminescent coating composition of claim 1 , wherein the curable thermoset resin comprises an epoxy component and an amine curing agent.

7 : The flowable luminescent coating composition of claim 6 , wherein the epoxy component comprises at least one resin selected from the group consisting of a bisphenol A epoxy resin, a bisphenol F epoxy resin, a novolak epoxy resin, an aliphatic epoxy resin, a glycidylamine epoxy resin, and an epoxidized vegetable oil.

8 : The flowable luminescent coating composition of claim 6 , wherein the amine curing agent comprises at least one selected from the group consisting of piperazine, aminoethylpiperazine, pentaethylenehexamine (PEHA), ethylenediamine, ethyleneimine, diethylenetriamine (DETA), hexaethyleneheptamine (HEHA), tetraethylenepentamine (TEPA), and triethylenetetramine (TETA).

9 : The flowable luminescent coating composition of claim 6 , wherein a volume ratio of the epoxy component and the amine curing agent is in a range of 1:1 to 10:1.

10 : The flowable luminescent coating composition of claim 1 , wherein the filler material is at least one selected from the group consisting of fused silica, crystalline silica, glass powder, alumina, calcium carbonate, barium sulfate, barium titanate, talc, clay, magnesium carbonate, aluminum oxide, aluminum hydroxide, magnesium hydroxide, and mica.

11 : The flowable luminescent coating composition of claim 1 , wherein each of the two or more solvents are independently selected from the group consisting of a ketone solvent, an ester solvent, an alcohol solvent, an amide solvent, an ether solvent, an aromatic hydrocarbon solvent, and water.

12 : The flowable luminescent coating composition of claim 11 , wherein the two or more solvents comprise a benzene solvent and water, and wherein a volume ratio of the benzene solvent and water is in a range of 50:1 to 5:1.

13 : The flowable luminescent coating composition of claim 1 , wherein the plasticizer is at least one selected from the group consisting of a phthalate-based plasticizer, a polyol-based plasticizer, and a citrate-based plasticizer.

14 : The flowable luminescent coating composition of claim 1 , wherein the stabilizer is at least one selected from the group consisting of an antioxidant, a light stabilizer, and a heat stabilizer.

15 : A glow-in-the-dark (GiD) film, comprising the flowable luminescent coating composition of claim 1 in a cured form.

16 : A GiD traffic sign, comprising:
a polymer film at least partially covering a surface of a metal substrate; a binder layer at least partially covering a surface of the polymer film; and the GiD film of claim 15 at least partially covering a surface of the binder layer.

17 : A GiD system, comprising:
the GiD traffic sign of claim 16 ; a plurality of solar panels; wherein the plurality of solar panels are supported on a base plate; a rechargeable battery pack; a microcontroller; a plurality of switches; a plurality of UV light sources; and wherein the plurality of UV light sources are in optical communication with the GiD traffic sign.

18 : The GiD system of claim 17 , wherein each of the plurality of solar panels is operatively connected to the rechargeable battery pack, and wherein the rechargeable battery pack is operatively connected to the microcontroller.

19 : The GiD system of claim 17 , wherein each of the plurality of UV light sources is operatively connected to the microcontroller via each of the plurality of switches, and wherein the microcontroller comprises a memory for saving or installing an application program, or a software program, and wherein the application program or the software program from an internet or a cloud server is downloaded for controlling ON and OFF of each of the plurality of switches.

20 : The GiD system of claim 17 , wherein each of the plurality of UV light sources has a wavelength of maximum intensity in a range of 365 and 395 nanometers (nm).

Assignees

• Univ Imam Abdulrahman Bin Faisal

Inventors

• Saleem Muhammad

Classifications

• B32B27/36

  comprising polyesters · CPC title

• B32B27/308

  comprising acrylic (co)polymers · CPC title

• B32B15/09

  comprising polyesters · CPC title

• B32B15/082

  comprising vinyl resins; comprising acrylic resins · CPC title

• B32B2255/10

  on synthetic resin layer or on natural or synthetic rubber layer · CPC title