Phase change system with modular crucibles and flow control nozzles

Patent metadata

Field	Value
Publication number	US-2025207218-A1
Application number	US-202418987554-A
Country	US
Kind code	A1
Filing date	Dec 19, 2024
Priority date	Dec 20, 2023
Publication date	Jun 26, 2025
Grant date	—

Abstract

A phase change system comprising a reduction assembly, a cold sublimation assembly, and a hot sublimation assembly. The reduction assembly comprises a reduction crucible, a first modular crucible, and a reduction control nozzle and, when assembled, the reduction control nozzle is positioned between an open end of the reduction crucible and an open end of the first modular crucible and a protruding outlet of the reduction control nozzle extends into an activity chamber of the first modular crucible. The cold sublimation assembly comprises a collection crucible and a cold sublimation control nozzle and, when assembled, the cold sublimation control nozzle extends into an activity chamber of the collection crucible. In addition, the hot sublimation assembly comprises a hot sublimation crucible and a second modular crucible and, when assembled, the hot sublimation crucible is fluidly coupled to the second modular crucible.

First claim

What is claimed is:

1 . A phase change system comprising a reduction assembly, a cold sublimation assembly, and a hot sublimation assembly, wherein:
the reduction assembly comprises a reduction crucible, a first modular crucible, and a reduction control nozzle and, when assembled, the reduction control nozzle is positioned between an open end of the reduction crucible and an open end of the first modular crucible and a protruding outlet of the reduction control nozzle extends into an activity chamber of the first modular crucible; the cold sublimation assembly comprises a collection crucible and a cold sublimation control nozzle and, when assembled, the cold sublimation control nozzle extends into an activity chamber of the collection crucible; and the hot sublimation assembly comprises a hot sublimation crucible and a second modular crucible and, when assembled, the hot sublimation crucible is fluidly coupled to the second modular crucible.

2 . The phase change system of claim 1 , wherein the reduction assembly further comprises a crucible heater having a crucible receiving recess terminating at a heater base.

3 . The phase change system of claim 2 , wherein the crucible heater of the reduction assembly is a resistive heater.

4 . The phase change system of claim 2 , wherein the reduction crucible comprises a base surface at a closed end of the reduction crucible and when the reduction assembly is assembled, the reduction crucible is positioned in the crucible receiving recess of the crucible heater and a non-conductive washer is positioned between the base surface of the reduction crucible and the heater base, thereby blocking current flow from the heater base to the base surface.

5 . The phase change system of claim 1 , wherein the reduction control nozzle comprises a flow channel extending from an inlet opening to an outlet opening, wherein the outlet opening is located at the protruding outlet, and a mesh screen is positioned in the flow channel, such that fluid flowing from the inlet opening to the outlet opening traverses the mesh screen.

6 . The phase change system of claim 1 , wherein the reduction control nozzle comprises a nozzle body and a flow channel extending through the nozzle body from an inlet opening to an outlet opening, the nozzle body comprising a barrier portion positioned radially outward from the flow channel, and the barrier portion comprising a lipped edge.

7 . The phase change system of claim 6 , wherein when the reduction assembly is assembled, the lipped edge of the reduction control nozzle engages with the reduction crucible, forming a tortious interface between the reduction control nozzle and the reduction crucible.

8 . The phase change system of claim 1 , wherein the hot sublimation assembly further comprises a crucible heater having a crucible receiving recess terminating at a heater base.

9 . The phase change system of claim 8 , wherein the crucible heater of the hot sublimation assembly is a resistive heater.

10 . The phase change system of claim 8 , wherein the hot sublimation crucible comprises a base surface at a closed end of the hot sublimation crucible and when the hot sublimation assembly is assembled, the hot sublimation crucible is positioned in the crucible receiving recess of the crucible heater and a non-conductive washer is positioned between the base surface of the hot sublimation crucible and the heater base, thereby blocking current flow from the heater base to the base surface.

11 . The phase change system of claim 1 , wherein the hot sublimation crucible comprises an open end opposite a closed end, the open end including a throat comprising a throat channel extending from a throat inlet to a throat outlet and, when the hot sublimation assembly is assembled, the throat outlet extends into an activity chamber of the second modular crucible.

12 . The phase change system of claim 11 , wherein a mesh screen is positioned in the throat channel of the hot sublimation crucible, such that fluid flowing from the throat inlet to the throat outlet traverses the mesh screen.

13 . The phase change system of claim 1 , wherein the hot sublimation assembly comprises a hot sublimation control nozzle and, when assembled, the hot sublimation control nozzle extends into an activity chamber of the second modular crucible.

14 . The phase change system of claim 13 , wherein:
the hot sublimation control nozzle comprises a flow channel comprising an inlet opening and an outlet opening; and a mesh screen is positioned in the flow channel, such that fluid flowing from the inlet opening to the outlet opening traverses the mesh screen.

15 . The phase change system of claim 1 , wherein when the cold sublimation assembly is assembled, the cold sublimation control nozzle is positioned between an open end of the collection crucible and the open end of the first modular crucible or the second modular crucible.

16 . The phase change system of claim 15 , wherein the first modular crucible and the second modular crucible each comprise:
a crucible body; a closed end opposite the open end; an activity chamber; and an end shoulder comprising an interfacing edge terminating at the open end.

17 . A method comprising:
heating a powder mixture comprising a rare earth oxide powder and a lanthanum powder in a reduction crucible, wherein heating the powder mixture reduces the rare earth oxide powder into a rare earth metal composition that collects in a first modular crucible, wherein the rare earth metal composition comprises a rare earth metal and a lanthanum metal; positioning the first modular crucible on a crucible heater while the rare earth metal composition is disposed in the first modular crucible; fluidly coupling the first modular crucible to a collection crucible using a sublimation control nozzle, such that the sublimation control nozzle is positioned between the first modular crucible and the collection crucible, the sublimation control nozzle comprising a flow channel; and heating the first modular crucible using the crucible heater, thereby heating the rare earth metal composition and phase separating the rare earth metal from the lanthanum metal leaving a higher weight percentage of the of the lanthanum metal in the first modular crucible than was present in the rare earth metal composition and collecting a refined rare earth element composition in the collection crucible, wherein the refined rare earth element composition comprises a higher weight percentage of the rare earth metal than the rare earth metal composition.

18 . The method of claim 17 , wherein the rare earth metal is a first rare earth metal and the method further comprises irradiating the refined rare earth element composition thereby forming an irradiated composition comprising the first rare earth metal and a second rare earth metal.

19 . The method of claim 18 , wherein the first rare earth metal comprises lutetium and the second rare earth metal comprises ytterbium.

20 . The method of claim 18 , further comprising positioning the irradiated composition in a sublimation crucible and fluidly coupling the sublimation crucible to a second modular crucible.

21 . The method of claim 20 , further comprising:
heating the irradiated composition for a first heating period, thereby phase separating the first rare earth metal from the irradiated composition to leave a higher weight percentage of the second rare earth metal than was present in the irradiated composition; a

Assignees

• Shine Technologies Llc

Inventors

• Childs Zachary
• Kearney Kenneth
• Van Abel Eric
• Szymski Matthew

Classifications

• G21G2001/0094

  Other isotopes not provided for in the groups listed above · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• C22B4/08

  Apparatus ({C22B4/005 takes precedence; } electric heating elements H05B) · CPC title

• C22B5/16 Primary

  with volatilisation or condensation of the metal being produced · CPC title

• C22B5/04

  by aluminium, other metals or silicon · CPC title