Method for activating solid polymer electrolyte for use in solid-state polymer battery

Patent metadata

Field	Value
Publication number	US-2025201916-A1
Application number	US-202418981164-A
Country	US
Kind code	A1
Filing date	Dec 13, 2024
Priority date	Dec 14, 2023
Publication date	Jun 19, 2025
Grant date	—

Abstract

Disclosed herein is a method for activating a solid polymer electrolyte (SPE) to facilitate making and using a solid-state polymer battery that can be operated at room temperature. The activation method disclosed herein comprises exposing the SPE to activating conditions that facilitate converting the SPE into an activated SPE that exhibits improved properties relative to the SPE prior to activation. The activated SPE can be used in solid-state polymer batteries that exhibit improved performance at room temperature. The SPE can be activated separately from any battery in which it is used, or it can be activated after having been combined with components of the battery.

First claim

We claim:

1 . A method for activating a solid polymer electrolyte (SPE) for use in a solid-state polymer battery, the method comprising exposing the SPE to activating conditions selected from (i) heat and pressure, or (ii) sonication to produce an activated SPE, wherein the activated SPE exhibits a higher ambient temperature ionic conductivity than the SPE prior to activation.

2 . The method of claim 1 , wherein the activated SPE exhibits fewer crystalline phases and/or fewer grain boundaries than the SPE prior to activation.

3 . The method of claim 2 , wherein crystalline phases and/or grain boundaries of the activated SPE are evaluated using backscattered electron imaging, differential scanning calorimetry, or a combination thereof.

4 . The method of claim 1 , wherein the activated SPE exhibits increased interfacial contact with an electrode active material of the solid-state polymer battery relative to the SPE prior to activation.

5 . The method of claim 4 , wherein interfacial contact is evaluated by measuring resistance between the electrode active material and the SPE.

6 . The method of claim 1 , wherein exposing the SPE to activating conditions comprises heating the SPE at a temperature ranging from a temperature greater than 40° C. to a temperature of 100° C. and applying a pressure ranging from 0.1 MPa to 10 MPa.

7 . The method of claim 6 , wherein pressure is applied for a time period ranging from greater than or equal to 15 minutes.

8 . The method of claim 1 , wherein the SPE is present in combination with an electrode active material, an anode, a cathode, a membrane, a separator, or any combination thereof.

9 . The method of claim 1 , wherein the SPE is activated after introducing the SPE into a cell to first form the SPE-containing solid-state battery, and wherein the activating conditions are applied to the SPE-containing solid-state battery.

10 . The method of claim 9 , wherein the SPE-containing solid-state battery comprising the activated SPE exhibits a specific capacity that is greater than or equal to 100 mAh/g after 100 charge-discharge cycles when operated at ambient temperature or lower.

11 . The method of claim 1 , wherein heating comprises using elevated temperature or microwaves.

12 . The method of claim 1 , wherein the SPE further comprises an additive, wherein the additive comprises a metal oxide, a metal sulfide, a metal halide, or a combination thereof.

13 . The method of claim 12 , wherein the SPE comprises the additive in an amount ranging from 1 wt. % to 80 wt. %.

14 . The method of claim 1 , wherein the SPE is provided as a coating layer on an electrode active material.

15 . An all-solid-state polymer battery, comprising:
a cathode; an anode; and an activated solid polymer electrolyte (SPE), wherein the activated SPE has been activated according to the method of claim 1 .

16 . The polymer-containing solid-state battery of claim 15 , wherein (i) the activated SPE exhibits fewer crystalline phases and/or fewer grain boundaries than an SPE that has not been activated; and/or (ii) the activated SPE exhibits increased interfacial contact with an electrode active material of the polymer electrolyte solid-state battery relative to an SPE that has not been activated.

17 . The polymer-containing solid-state battery of claim 15 , wherein the SPE-containing solid-state battery has an ambient temperature specific capacity of greater than or equal to 100 mAh/g after 100 charge-discharge cycles.

18 . The polymer-containing solid-state battery of claim 15 , wherein the SPE comprises a mixture of a polymer and an alkali salt, wherein the polymer is selected from polyethylene oxide, polyacrylonitrile, polymethyl methacrylate, polyvinylidene fluoride, polycarbonate; and the alkali salt is selected from lithium bis(trifluoromethane)sulfonimide, lithium perchlorate (LiClO 4 ), lithium hexafluorophosphate (LiPF 6 ), lithium bis(fluorosulfonyl)imide (LiCF 3 SO 3 ) (LiFSI), lithium bis(pentafluoroethanesulfonyl)imide (Li(C 2 F 5 SO 2 ) 2 N) (LiBETI), lithium trifluoromethanesulfonate (LiCF 3 SO 3 ) (LiTf), lithium bis(oxalato)borate (LiB(C 2 O 4 ) 2 ) (LiBOB), lithium difluoro (oxalato) borate (LiBF 2 (C 2 O 4 )) (LiODFB), lithium nitrate (LiNO 3 ), lithium iodide (LiI), sodium perchlorate (NaClO 4 ), sodium bis(trifluoromethanesulfonyl)imide (NaTFSI), magnesium bis(trifluoromethanesulfonimide) (Mg(TFSI) 2 ), or a combination thereof.

19 . A method for activating a solid polymer electrolyte (SPE) for use in a solid-state polymer battery, the method comprising:
exposing the SPE to a temperature ranging from a temperature higher than 40° C. to a temperature of 100° C. and a pressure ranging from 0.5 MPa to 10 MPa, to produce an activated SPE; and allowing the SPE to cool to ambient temperature prior to operating any solid-state polymer to which the SPE is added,
wherein the activated SPE exhibits a higher ambient temperature ionic conductivity than the SPE prior to activation.

20 . An activated solid polymer electrolyte (SPE) comprising an alkali salt and a polymer component, wherein the activated SPE is free of crystalline regions and that exhibits an ambient temperature ionic conductivity that is three to ten times higher than an ambient temperature ionic conductivity exhibited by an untreated SPE having the alkali salt and polymer component as the activated SPE.

Assignees

• Battelle Memorial Institute

Inventors

• Shi Lili
• Xu Hongliang
• Xiao Jie
• Lu Dongping

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• H01M10/0565 Primary

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• H01M10/052

  Li-accumulators · CPC title