Recycling and recovery of used liquefied gas electrolyte and battery salt, and compositions of fire-extinguishing electrolytes for batteries

Patent metadata

Field	Value
Publication number	US-2025192258-A1
Application number	US-202318843096-A
Country	US
Kind code	A1
Filing date	Mar 6, 2023
Priority date	Mar 4, 2022
Publication date	Jun 12, 2025
Grant date	—

Abstract

Methods, materials, and devices that pertain to recycling liquefied gas electrolyte, recovering battery salt from spent battery materials and fire-extinguishing electrolytes for batteries are disclosed. In some embodiments of the disclosed technology, a device includes a first battery module including a first liquefied gas electrolyte, a second battery module structured to store a second liquefied gas electrolyte, a temperature controller configured to separately control a first temperature of the first battery module and a second temperature of the second battery module to evaporate the first liquefied gas electrolyte into a gas electrolyte and liquefy the gas into the second liquefied gas electrolyte, and a flow channel coupled between the first battery module and the second battery module to convey the gas electrolyte from the first battery module to the second battery module. For salt recycling technology, the salt from the spent battery materials is solvated using Me2O under its vapor pressure and thus formed salt solution is separated. The salt from the recovered feed solution is extracted using heating/vacuum technology.

First claim

1 . A device, comprising:
a first battery module including a first liquefied gas electrolyte; a second battery module structured to store a second liquefied gas electrolyte; a temperature controller coupled to the first battery module and to the second battery module and configured to separately control a first temperature of the first battery module and a second temperature of the second battery module to allow evaporation of the first liquefied gas electrolyte into a gas electrolyte and liquefication of the gas into the second liquefied gas electrolyte; and a flow channel coupled between the first battery module and the second battery module to convey the gas electrolyte from the first battery module to the second battery module.

2 . The device of claim 1 , comprising:
a mass flow controller coupled to the flow channel to control a flow of the gas electrolyte from the first battery module to the second battery module.

3 . The device of claim 2 , wherein the mass flow controller is configured to open the flow channel to: evaporate the first liquefied gas electrolyte; transfer the evaporated first liquefied gas electrolyte to the second battery module; and liquefy the evaporated first liquefied gas electrolyte into the second liquefied gas electrolyte to be stored in the second battery module.

4 . The device of claim 1 , wherein the first battery module includes spent liquefied gas electrolytes.

5 . The device of claim 1 , wherein the second battery module includes an empty space to accommodate the second liquefied gas electrolyte.

6 . The device of claim 1 , wherein the first temperature is higher than the second temperature to create a pressure difference between the first battery module and the second battery module.

7 . The device of claim 1 , wherein the first liquefied gas electrolyte includes spent liquefied gas solvent molecules, and the second liquefied gas electrolyte includes liquefied gas solvent molecules converted from the spent liquefied gas solvent molecules for reuse.

8 . The device of claim 1 , wherein the first liquefied gas electrolyte includes dimethyl ether (Me 2 O).

9 . The device of claim 1 , wherein the first liquefied gas electrolyte includes a fire-extinguishing solvent.

10 . The device of claim 9 , wherein the fire-extinguishing solvent includes dimethyl ether (Me 2 O).

11 . The device of claim 10 , wherein the fire-extinguishing solvent further includes at least one of tetrafluoroethane (TFE) and pentafluoroethane (PFE).

12 . The device of claim 11 , wherein the first liquefied gas electrolyte includes at least one of lithium bis(fluorosulfonyl)imide (LiFSI) or lithium bis(trifluoromethanesulfonyl)imide (LiTFSI).

13 . A recycling method, comprising:
controlling a first temperature of a first battery module, wherein the first battery module includes a first liquefied gas electrolyte and is coupled, via a flow channel, to a second battery module; opening the flow channel to evaporate the first liquefied gas electrolyte into a gas electrolyte, and to transfer the gas electrolyte to the second battery module; and controlling a second temperature of the second battery module to liquefy the gas received by the second battery module into a second liquefied gas electrolyte.

14 . The method of claim 13 , comprising creating a pressure difference between the first battery module and the second battery module by controlling the first temperature to be higher than the second temperature.

15 . The method of claim 13 , wherein the first liquefied gas electrolyte includes spent liquefied gas solvent molecules, and the second liquefied gas electrolyte includes liquefied gas solvent molecules converted from the spent liquefied gas solvent molecules for reuse.

16 . A method of recycling electrolyte salts for lithium-ion batteries, comprising:
placing, in a container, spent battery materials obtained from spent batteries or manufacturing scraps; applying dimethyl ether (Me 2 O) gas at a predetermined vapor pressure to the container to solvate salts used in the spent battery materials; and increasing a temperature of the container to obtain recycled battery materials.

17 . The method of claim 16 , wherein the used battery materials include lithium salts.

18 . The method of claim 17 , wherein the lithium salts include at least one of lithium hexafluorophosphate (LiPF 6 ), lithium bis(fluorosulfonyl)imide (LiFSI), or lithium bis(trifluoromethanesulfonyl)imide (LiTFSI).

Assignees

• Univ California

Inventors

• Meng Ying Shirley
• Yin Yijie
• Yang Yangyuchen
• Mayer Matthew
• Li Weikang
• Raghavendran Ganesh
• Chen Zheng

Classifications

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title