Poly(vinyl alcohol)-containing and silica nanoparticle multilayer coatings and methods
US-9926458-B2 · Mar 27, 2018 · US
US2025178027A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2025178027-A1 |
| Application number | US-202519052296-A |
| Country | US |
| Kind code | A1 |
| Filing date | Feb 13, 2025 |
| Priority date | Aug 31, 2022 |
| Publication date | Jun 5, 2025 |
| Grant date | — |
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A film including a layer A, and a layer B on at least one surface of the layer A, in which a dielectric loss tangent is 0.01 or less, and a surface free energy on a surface of the layer B on a side opposite to a layer A side is 30 mJ/m 2 or less, a film including a layer A, and a layer B on at least one surface of the layer A, in which a dielectric loss tangent is 0.01 or less, and an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, on a surface of the layer B on a side opposite to a layer A side, is larger than an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, inside the layer B, and a laminate using the film.
Opening claim text (preview).
What is claimed is: 1 . A film comprising: a layer A; and a layer B on at least one surface of the layer A, wherein a dielectric loss tangent is 0.01 or less, and a surface free energy on a surface of the layer B on a side opposite to a layer A side is 30 mJ/m 2 or less. 2 . The film according to claim 1 , wherein the surface free energy on the surface of the layer B on the side opposite to the layer A side is 15 mJ/m 2 to 30 mJ/m 2 . 3 . The film according to claim 1 , wherein a ratio of an elastic modulus of the layer A at 160° C. to an elastic modulus of the layer B at 160° C. is 1.2 or more. 4 . The film according to claim 1 , wherein an elastic modulus of the layer B at 160° C. is 10 MPa or less. 5 . The film according to claim 1 , wherein a dielectric loss tangent of the layer B is 0.01 or less. 6 . The film according to claim 1 , wherein the layer B contains a liquid crystal polymer. 7 . The film according to claim 1 , wherein the layer B contains an aromatic polyester amide. 8 . The film according to claim 1 , wherein the layer B contains a thermoplastic resin having a constitutional unit having an aromatic hydrocarbon group. 9 . The film according to claim 1 , wherein a dielectric loss tangent of the layer A is 0.01 or less. 10 . The film according to claim 1 , wherein the layer A contains a liquid crystal polymer. 11 . The film according to claim 1 , wherein the layer A contains an aromatic polyester amide. 12 . A laminate comprising: the film according to claim 1 ; and a metal layer or a metal wire disposed on at least one surface of the film. 13 . A film comprising: a layer A; and a layer B on at least one surface of the layer A, wherein a dielectric loss tangent is 0.01 or less, and an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, on a surface of the layer B on a side opposite to a layer A side, is larger than an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, inside the layer B. 14 . The film according to claim 13 , wherein a ratio of an elastic modulus of the layer A at 160° C. to an elastic modulus of the layer B at 160° C. is 1.2 or more. 15 . The film according to claim 13 , wherein an elastic modulus of the layer B at 160° C. is 10 MPa or less. 16 . The film according to claim 13 , wherein a dielectric loss tangent of the layer B is 0.01 or less. 17 . The film according to claim 13 , wherein the layer B contains a liquid crystal polymer. 18 . The film according to claim 13 , wherein the layer B contains an aromatic polyester amide. 19 . The film according to claim 13 , wherein the layer B contains a thermoplastic resin having a constitutional unit having an aromatic hydrocarbon group. 20 . The film according to claim 13 , wherein a dielectric loss tangent of the layer A is 0.01 or less. 21 . The film according to claim 13 , wherein the layer A contains a liquid crystal polymer. 22 . The film according to claim 13 , wherein the layer A contains an aromatic polyester amide. 23 . A laminate comprising: the film according to claim 13 ; and a metal layer or a metal wire disposed on at least one surface of the film. 24 . A laminate comprising, in the following order: a layer A; a layer B; and a metal layer or a metal wire, wherein a dielectric loss tangent is 0.01 or less, and a surface free energy on a surface of the layer B on a side opposite to a layer A side is 30 mJ/m 2 or less. 25 . A laminate comprising, in the following order: a layer A; a layer B; and a metal layer or a metal wire, wherein a dielectric loss tangent is 0.01 or less, and an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, on a surface of the layer B on a side opposite to a layer A side, is larger than an ion intensity derived from a fluorine atom or a silicone structure, which is measured by time-of-flight secondary ion mass spectrometry, inside the layer B.
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