Lithium recovery system for black mass

Patent metadata

Field	Value
Publication number	US-2025163543-A1
Application number	US-202418810637-A
Country	US
Kind code	A1
Filing date	Aug 21, 2024
Priority date	Nov 20, 2023
Publication date	May 22, 2025
Grant date	—

Abstract

Disclosed is a lithium recovery system for black mass, including: a heat treatment unit that performs heat treatment to convert the black mass into soluble substances and insoluble substances; a water leaching unit that leaches the heat-treated black mass with water to separate the heat-treated black mass into a water leaching solution, which contains lithium ions and carbonate ions, and insoluble substances; and an impurity removal unit that removes impurities contained in the water leaching solution by lowering pH of the water leaching solution through addition of carbon dioxide-containing gas to the water leaching solution.

First claim

What is claimed is:

1 . A lithium recovery system for black mass, comprising:
a heat treatment unit that performs heat treatment to convert the black mass into soluble substances and insoluble substances; a water leaching unit that leaches the heat-treated black mass with water to separate the heat-treated black mass into a water leaching solution, which contains lithium ions and carbonate ions, and insoluble substances; and an impurity removal unit that removes impurities contained in the water leaching solution by lowering pH of the water leaching solution through addition of carbon dioxide-containing gas to the water leaching solution.

2 . The lithium recovery system of claim 1 , wherein aluminum ions are precipitated in the impurity removal unit.

3 . The lithium recovery system of claim 1 , wherein calcium hydroxide (Ca(OH) 2 ) is supplied to the impurity removal unit, and reacts with fluoride ions to precipitate calcium fluoride (CaF 2 ).

4 . The lithium recovery system of claim 1 , wherein the carbon dioxide-containing gas is supplied continuously or intermittently to maintain the pH of the water leaching solution below 8 in the impurity removal unit.

5 . The lithium recovery system of claim 4 , wherein the pH of the water leaching solution in the impurity removal unit is maintained at 6 or more and 7 or less.

6 . The lithium recovery system of claim 1 , wherein the carbon dioxide-containing gas is derived from exhaust gas discharged after combustion in the heat treatment unit.

7 . The lithium recovery system of claim 6 , wherein the exhaust gas is supplied to the water leaching solution after passing through a dust collector.

8 . The lithium recovery system of claim 3 , wherein a molar concentration of calcium hydroxide supplied to the impurity removal unit is 1.2 to 2 times a molar concentration of fluoride ions in the water leaching solution separated from the water leaching unit.

9 . The lithium recovery system of claim 1 , further comprising:
a reverse osmosis (RO) concentration unit that concentrates the water leaching solution, from which impurities have been removed in the impurity removal unit, using reverse osmosis; and a crystallization unit that crystallizes lithium carbonate by raising temperature of concentrated water concentrated in the RO concentration unit.

10 . The lithium recovery system of claim 9 , wherein
the RO concentration unit comprises a first RO device and a second RO device, and the reverse osmosis is performed in either one of the first RO device and the second RO device, while flushing is concurrently performed in the other one.

11 . The lithium recovery system of claim 9 , wherein treated water used for the reverse osmosis in the RO concentration unit is supplied to the water leaching unit.

12 . The lithium recovery system of claim 9 , wherein a crystallization filtrate non-crystallized in the crystallization unit joins the water leaching solution, from which impurities have been removed in the impurity removal unit, and is then supplied to the RO concentration unit.

13 . The lithium recovery system of claim 12 , further comprising a heat exchange unit that exchanges heat between the crystallization filtrate and the concentrated water.

14 . The lithium recovery system of claim 13 , wherein the crystallization filtrate is cooled through the heat exchange unit to 40° C. or lower.

15 . The lithium recovery system of claim 12 , further comprising:
a separation unit that separates lithium carbonate crystallized in the crystallization unit and the crystallization filtrate into solid and liquid, wherein a main channel through which the crystallization filtrate flows from the separation unit to a confluence for joining the water leaching solution, and a bypass channel branched from the main channel are provided, and wherein an ion exchange resin is provided in the bypass channel.

16 . The lithium recovery system of claim 10 , wherein the first RO device comprises a first concentration chamber to which the water leaching solution is supplied, a first treatment chamber to which treated water is collected, and a first RO membrane positioned between the first concentration chamber and the first treatment chamber.

17 . The lithium recovery system of claim 16 , wherein the second RO device comprises a second concentration chamber to which the water leaching solution is supplied, a second treatment chamber to which treated water is collected, and a second RO membrane positioned between the second concentration chamber and the second treatment chamber.

18 . A lithium recovery method for black mass, comprising:
a heat treatment process of performing heat treatment to convert the black mass into soluble substances and insoluble substances; a water leaching process of leaching the heat-treated black mass with water to separate the heat-treated black mass into a water leaching solution, which contains lithium ions and carbonate ions, and insoluble substances; and an impurity removal process of supplying carbon dioxide-containing gas to the water leaching solution to lower pH of the water leaching solution.

19 . The lithium recovery method of claim 18 , wherein aluminum ions contained in the water leaching solution are removed by the impurity removal process.

20 . The lithium recovery method of claim 18 , wherein the impurity removal process comprises additionally supplying calcium hydroxide (Ca(OH) 2 ) to the water leaching solution, and fluoride ions contained in the water leaching solution are removed by the impurity removal process.

Assignees

• Doosan Enerbility Co Ltd

Inventors

• You Jang Yong
• Shin Kwang Hee
• You Su Nam
• Lee Jin Woon
• Jo Ho Yong

Classifications

• C22B7/007

  by acid leaching · CPC title

• C22B7/006

  Wet processes · CPC title

• C22B26/12 Primary

  Obtaining lithium · CPC title

• C01D15/08 Primary

  Carbonates; Bicarbonates · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title