Separator and electrochemical device comprising the same

Patent metadata

Field	Value
Publication number	US-2025158227-A1
Application number	US-202418946922-A
Country	US
Kind code	A1
Filing date	Nov 14, 2024
Priority date	Nov 15, 2023
Publication date	May 15, 2025
Grant date	—

Abstract

Embodiments of the present disclosure relate to a separator comprising a porous substrate; and an inorganic particle layer disposed on at least one surface of the porous substrate, the inorganic particle layer comprising a binder and inorganic particles, wherein the separator has a Gurley permeability of 10 to 250 sec/100 cc, a puncture strength of 0.3 N/μm or more, tensile strengths in the machine direction and in the transverse direction of 1500 kgf/cm 2 or more, heat shrinkage rates in the machine direction and in the transverse direction measured after being allowed to stand at 130° C. for 60 minutes of 5% or less, and a saturated moisture content measured by a Karl Fischer method of 350 to 1000 ppm.

First claim

What is claimed is:

1 . A separator for an electrochemical device, the separator comprising:
a porous substrate; and an inorganic particle layer disposed on at least one surface of the porous substrate, the inorganic particle layer comprising a binder and inorganic particles, wherein the separator has a Gurley permeability of 10 to 250 sec/100 cc, a puncture strength of 0.3 N/μm or more, tensile strengths in the machine direction and in the transverse direction of 1500 kgf/cm 2 or more, heat shrinkage rates in the machine direction and in the transverse direction measured after being allowed to stand at 130° C. for 60 minutes of 5% or less, and a saturated moisture content measured by a Karl Fischer method of 350 to 1000 ppm.

2 . The separator of claim 1 , wherein the Gurley permeability is 90 to 230 sec/100 cc, and the saturated moisture content is 450 to 1000 ppm.

3 . The separator of claim 1 , wherein the porous substrate has an average thickness of 5 to 15 μm, and a ratio between the average thickness of the porous substrate and an average thickness of the separator is 0.7 or more.

4 . The separator of claim 1 , wherein a total thickness of the inorganic particle layer formed on the porous substrate is 3.2 μm or less.

5 . The separator of claim 1 , wherein the binder comprises a polyacrylamide-based resin.

6 . The separator of claim 5 , wherein the polyacrylamide-based resin is a copolymer comprising a unit derived from a (meth)acrylamide-based monomer.

7 . The separator of claim 6 , wherein the polyacrylamide-based resin comprises a structural unit derived from the (meth)acrylamide-based monomer and a structural unit derived from a (meth)acryl-based monomer containing a hydroxyl group.

8 . The separator of claim 5 , wherein the polyacrylamide-based resin has a weight average molecular weight of 100,000 to 2,000,000 g/mol.

9 . The separator of claim 5 , wherein the binder further comprises one or two or more water-based polymer selected from the group consisting of polyvinyl alcohol, polyvinylidene fluoride, carboxymethyl cellulose, styrene butadiene rubber, polyacrylic acid, polyethylene glycol, polyacrylonitrile, polyvinylpyrrolidone, and copolymers thereof.

10 . The separator of claim 9 , wherein a content of the water-based polymer is 0.1 to 30 wt % of the total content of the binder.

11 . The separator of claim 1 , wherein the inorganic particles have a BET specific surface area of 3 to 7 m 2 /g.

12 . The separator of claim 1 , wherein the inorganic particles have an average particle diameter (D50) of 0.5 to 1.5 μm.

13 . The separator of claim 1 , wherein the inorganic particles comprise one or two or more selected from the group consisting of metal hydroxides, metal oxides, metal nitrides, and metal carbides.

14 . The separator of claim 1 , wherein the inorganic particle layer has a weight ratio between the inorganic particles and the binder of 50:50 to 99.9:0.1.

15 . The separator of claim 1 , wherein the inorganic particle layer is formed to have a coating amount of 0.5 to 10 g/m 2 .

16 . An electrochemical device comprising the separator according to claim 1 .

17 . The electrochemical device of claim 16 , wherein the electrochemical device is a secondary battery exhibiting increased battery capacity and performance characteristics in high energy applications, including electric vehicles, thereby supporting reduced reliance in carbon-based fuels by enabling broader adoption of electric-powered transportation.

18 . A separator for an electrochemical device, the separator comprising:
a porous substrate comprising a polyethylene porous film having an average thickness of 5 to 15 μm; and an inorganic particle layer disposed on at least one surface of the porous substrate, wherein the inorganic particle layer comprises a binder and inorganic particles, wherein the porous substrate comprises a polar functional group on the surface, the polar functional group comprising a carboxyl group, an aldehyde group, a hydroxyl group, and the like, and wherein a ratio between the average thickness of the porous substrate and an average thickness of the separator is 0.7 to 0.99, and wherein the separator is designed to extend battery capacity and performance characteristics in high energy applications, thereby supporting reduced reliance in carbon-based fuels.

Assignees

• Sk Innovation Co Ltd
• Sk Ie Tech Co Ltd

Inventors

• Kwon Tae Wook
• Cho Kyu Young
• Bae Heung Taek

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M50/489 Primary

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/449 Primary

  having a layered structure · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M50/423

  Polyamide resins · CPC title