Crosslinked cellulose as precursor in production of high-grade cellulose derivatives and related technology
US-10428459-B2 · Oct 1, 2019 · US
US2025146219A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2025146219-A1 |
| Application number | US-202519011926-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jan 7, 2025 |
| Priority date | Nov 6, 2020 |
| Publication date | May 8, 2025 |
| Grant date | — |
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Disclosed are non-wood pulps having a fiber length greater than about 1.70 mm and a brightness of about 80% or greater. The relatively high degree of brightness is achieved without a loss fiber length or pulp yield. The high degree of brightness and relatively long fiber length makes the pulps well suited for the manufacture of wet-laid fibrous products, particularly wet-laid tissue products. The pulps may be prepared from plants of the family Asparagaceae by mechanical pulping and more preferably by a chemi-mechanical pulping using a sodium hydroxide alkaline peroxide solution where the primary pulp is cleaned to reduce debris prior to bleaching. Preferably the cleaned primary pulp has less than about 5% debris prior to bleaching.
Opening claim text (preview).
We claim: 1 . A method of manufacturing a non-wood pulp comprising the steps of: a. providing a non-wood biomass derived from a plant of the family Asparagaceae; b. cutting the non-wood biomass to a nominal length; c. extracting water soluble solids from the cut biomass to produce bagasse; d. impregnating the bagasse with a first sodium hydroxide alkaline peroxide and maintaining the impregnation for a first reaction time to produce impregnated bagasse; e. feeding the impregnated bagasse to a refiner comprising a refining disc encased in a housing having an inlet and an outlet; f. refining the impregnated bagasse under first refining conditions to produce a primary pulp; g. discharging the primary pulp out of the refining housing through the outlet and adding a second sodium hydroxide alkaline peroxide solution to the discharged primary pulp; h. cleaning the primary pulp to yield a cleaned primary pulp having less than about 5% debris; i. delivering the cleaned primary pulp to a bleaching vessel; and j. adding a third sodium hydroxide alkaline peroxide solution to the cleaned primary pulp in the bleaching vessel to yield a bleached primary pulp having a fiber length greater than about 1.70 mm and a brightness of about 80% or greater. 2 . The method of claim 1 wherein the first sodium hydroxide alkaline peroxide solution comprises at least about 2% peroxide, at least about 1.5% sodium hydroxide, and at least about 1% stabilizer, based upon the dry weight of the bagasse, the second sodium hydroxide alkaline peroxide solution comprises at least about 3% peroxide, at least about 2% sodium hydroxide, and at least about 2% stabilizer, based upon the dry weight of the primary pulp, and the third sodium hydroxide alkaline peroxide solution comprises at least about 5% peroxide and 4% sodium hydroxide, based upon the dry weight of the cleaned primary pulp. 3 . The method of claim 1 wherein the biomass is derived from one or more plants of the genus Hesperaloe. 4 . The method of claim 3 wherein the one or more plants are selected from H. funifera, H. parviflora, H. nocturna, H. chiangii, H. tenuifolia, H. engelmannii and H. malacophylla. 5 . The method of claim 1 further comprising the step of compressing and macerating the bagasse using a plug screw having a compression ratio of at least 2:1. 6 . The method of claim 1 wherein the refiner housing comprises a superatmospheric casing and the step of refining comprises feeding the impregnated bagasse having a consistency from about 20 to about 60% to the refiner and refining at a pressure of at least about 240 kP. 7 . The method of claim 1 wherein the primary pulp temperature is at least about 80° C. when the second sodium hydroxide alkaline peroxide solution is added. 8 . The method of claim 1 further comprising the step of mixing the sodium hydroxide alkaline peroxide solution and the primary pulp after the second sodium hydroxide alkaline peroxide solution is added. 9 . The method of claim 8 wherein the sodium hydroxide alkaline peroxide solution and the primary pulp are mixed for at least one hour. 10 . The method of claim 1 further comprising the steps of washing the bleached primary pulp, thickening the bleached primary pulp and adding a fourth sodium hydroxide alkaline peroxide solution to the washed and thickened bleached primary pulp.
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