Method for producing renewable fuels

Patent metadata

Field	Value
Publication number	US-2025145896-A1
Application number	US-202519016388-A
Country	US
Kind code	A1
Filing date	Jan 10, 2025
Priority date	Nov 15, 2019
Publication date	May 8, 2025
Grant date	—

Abstract

The present disclosure provides a diesel fuel component produced from feedstock of biological origin and a method for producing the same. The present disclosure provides diesel fuel blends containing the diesel fuel component of biological origin and at least one additional diesel fuel.

First claim

1 . A method for combined production of aviation fuel and diesel fuel both of biological origin, the method comprising:
providing feedstock of biological origin containing fatty acids and/or esters of fatty acids; and subjecting the feedstock to hydrotreatment and isomerization to obtain a paraffinic hydrocarbon intermediate; and fractionating said paraffinic hydrocarbon intermediate into at least two fractions, a lighter fraction fulfilling a specification ASTM D7566-20 Annex A2 for aviation fuel, and a heavier fraction fulfilling a specification EN 15940-18 for renewable diesel fuel; and adjusting a production capacity of the lighter fraction and a production capacity of the heavier fraction by selection of process conditions, and/or the isomerization process conditions, wherein yield of the lighter fraction is from 20 to 90 wt-% of a total weight of the formed fractions, and yield of the heavier fraction is from 10 to 80 wt-% of a total weight of the formed fraction; wherein a combined yield of the two fractions is at least 98 wt-% of the paraffinic hydrocarbon intermediate of biological origin.

2 . The method according to claim 1 , comprising:
performing the hydrotreatment, and/or a hydrodeoxygenation under a hydrogen pressure from 10 to 150 bar, and/or 20-120 bar, and/or 30-100 bar, and at a temperature from 200 to 400° C., and/or 250-380° C., and/or 280-360° C.

3 . The method according to claim 1 , comprising:
performing the hydrotreatment in a presence of one or more catalyst(s) selected from hydrogenation metal on a support, and/or a catalyst selected from a group consisting of Pd, Pt, Ni, Co, Mo, Ru, Rh, W and/or any combination thereof, and/or a catalyst containing one or more catalyst(s) selected from CoMo, NiMo, NiW, CoNiMo on a support, and/or an alumina support.

4 . The method according to claim 1 , comprising:
performing the isomerization, and/or hydroisomerization, at a temperature of 200-500° C., and/or 280-370° C., and at a pressure of 10-150 bar, and/or 20-50 bar.

5 . The method according to claim 1 , comprising:
performing the isomerization in a presence of one or more catalyst(s) containing a Group VIII metal on a support, where the support is selected from silica, alumina, clays, titanium oxide, boron oxide, zirconia, which can be used alone or as a mixture, and/or as silica and/or alumina.

6 . The method according to claim 1 , comprising:
subjecting the feedstock, after hydrotreatment and isomerization, to stabilization at a pressure lower than the isomerization pressure.

7 . The method according to claim 6 , comprising:
forming, during stabilization, an overhead fraction containing hydrocarbons in a naphtha range (C4-C8); and recycling an amount of 60 wt-% or more, and/or 90 wt-% or more, and/or from 90 to 95 wt-%, of the formed hydrocarbons in the naphtha range at the stabilization column overhead back to the stabilization.

8 . A diesel fuel component of biological origin comprising:
0-5 wt-% of n-paraffins in C16-C20 range; and 90-97 wt-% isoparaffins in C16-C20 range, with from 21 wt-% to 45 wt-% of C17 paraffins and from 50 wt-% to 75 wt-% of C18 paraffins.

9 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component comprises:
0-8 wt-% of n-paraffins in C17-C19 range, and/or 0-5 wt-% of n-paraffins in C17-C19.

10 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component comprises:
85-95 wt-% isoparaffins in C17-C20 range, and/or 88-95 wt-% of n-paraffins in C17-C20.

11 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component comprises:
from 21 to 43 wt-% of C17 paraffins.

12 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component comprises:
from 45 wt-% to 75 wt-% of C18 paraffins, and/or from 53 wt % to 75 wt-% of C18 paraffins.

13 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component comprises:
0-4 wt-% of n-paraffins in C17-C18 range; and 85-90 wt % isoparaffins in C17-C18 range.

14 . The diesel fuel component of biological origin according to claim 8 , wherein the diesel fuel component has at least one or more of the following properties:
oxidation stability EN 16091 is at least 60 min, and/or at least 75 min, and/or at least 100 min; density at 15° C. EN ISO 12185 is between 765-800 kg/m 3 , and/or at least 786 kg/m 3 , and/or at least 788 kg/m 3 ; cetane number EN 15195 is at least 75, and/or at least 80, and/or at least 82; total aromatics EN 12916 is less than 1.1 wt-%, and/or less than 0.7 wt-%, and/or less than 0.6 wt-%; kinematic viscosity at 40° C. EN ISO 3104 is below 4.5 mm 2 /s, and/or below 4.0 mm 2 /s, and/or below 3.8 mm 2 /s; flash point EN ISO 2719 is at least 100° C., and/or at least 130° C., and/or at least 145° C.; cloud point ASTM D7689 is less than −20° C., and/or less than −25° C., and/or less than −30° C., and/or −32° C. or less; net heat of combustion ASTM D4809 is within a range of 33 to 36 MJ/I; and/or modern carbon content (pMC, ASTM D6866) is about 100%.

15 . The diesel fuel component produced by the method according to claim 1 .

16 . The diesel fuel component of biological origin according to claim 8 , in a diesel fuel or a diesel fuel blend fulfilling the requirements of EN 15940-18 or EN590-14.

17 . A diesel fuel blend comprising:
from 1 wt-% to 99 wt-% of the diesel fuel component according to claim 8 ; and from 1 wt-% to 99 wt-% of fossil diesel fuel.

18 . A diesel fuel blend comprising:
from 1 wt-% to 99 wt-% of the diesel fuel component according to claim 8 ; and from 1 wt-% to 99 wt-% of renewable diesel fuel.

19 . A diesel fuel blend comprising:
from 1 wt-% to 98 wt-% of the diesel fuel component according to claim 8 ; from 1 wt-% to 98 wt-% of renewable diesel; and from 1 wt-% to 98 wt-% of fossil diesel fuel.

20 . A diesel fuel blend comprising:
from 1 wt-% to 98 wt-% of the diesel fuel component according to claim 8 ; from 1 wt-% to 98 wt-% of biodiesel; and from 1 wt-% to 98 wt-% of fossil diesel fuel.

21 . A diesel fuel blend comprising:
from 1 wt-% to 97 wt-% of the diesel fuel component according to claim 8 ; from 1 wt-% to 97 wt-% of renewable diesel fuel; from 1 wt-% to 97 wt-% of biodiesel; and from 1 wt-% to 97 wt-% of fossil diesel fuel.

Assignees

• Neste Oyj

Inventors

• Vilja Jesse
• Kuronen Markku
• Nortio Jenni

Classifications

• C10M2203/003

  used as base material · CPC title

• C10M109/02

  Reaction products · CPC title

• C10G2400/10

  Lubricating oil · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G2300/4006

  Temperature · CPC title