Diamond sensor

Patent metadata

Field	Value
Publication number	US-2025060430-A1
Application number	US-202218721327-A
Country	US
Kind code	A1
Filing date	Dec 19, 2022
Priority date	Dec 23, 2021
Publication date	Feb 20, 2025
Grant date	—

Abstract

A sensor assembly comprising single crystal diamond material, the single crystal diamond material comprising a surface which is configured in use to contact a fluid, the surface comprising a sensing surface region, wherein the single crystal diamond material comprises a plurality of quantum spin defects in proximity to the sensing surface region. The sensor assembly further comprises a first electrode and a second electrode. The electrodes are located such that, in use, they generate an electric field proximate to a surface of the sensing surface region, the electric field being sufficient to generate oxidising species in the fluid for removing contaminant material from the sensing surface region.

First claim

1 . A sensor assembly comprising:
single crystal diamond material, the single crystal diamond material comprising a surface which is configured in use to contact a fluid, the surface comprising a sensing surface region, wherein the single crystal diamond material comprises a plurality of quantum spin defects in proximity to the sensing surface region; a first electrode; a second electrode wherein the electrodes are located such that, in use, they generate an electric field proximate to a surface of the sensing surface region, the electric field being sufficient to generate oxidising species in the fluid for removing contaminant material from the sensing surface region.

2 . The sensor assembly according to claim 1 , wherein the contaminant material comprises organic material.

3 . The sensor assembly according to claim 1 , wherein the first electrode is located at a first electrode surface region of the single crystal diamond material, and comprises any of:
electrically conducting boron doped diamond; graphite; and a metal material deposited on the surface of the sensor.

4 . The sensor assembly according to claim 1 , wherein the second electrode is located at a second electrode surface region of the single crystal diamond material, and comprises any of:
electrically conducting boron doped diamond; graphite; and a metal material deposited on the surface of the sensor.

5 . The sensor assembly according to claim 1 , wherein the quantum spin defects are selected from any of:
silicon containing defects; nickel containing defects; chromium containing defects; germanium containing defects; tin containing defects; nitrogen containing defects; and negatively charged nitrogen-vacancy defects, NV − .

6 .- 9 . (canceled)

10 . The sensor assembly according to claim 1 , further comprising a plurality of sensing surface regions, wherein the first electrode surface region is located such that, in use, it generates an electric field over a surface of the plurality of sensing surface regions.

11 . (canceled)

12 . (canceled)

13 . A single crystal diamond comprising:
a surface which is configured, in use, to contact a fluid, the surface comprising a sensing surface region, wherein the single crystal diamond comprises a plurality of quantum spin defects in proximity to the sensing surface region; the surface further comprising at least one electrode region, the at least one electrode region configured, in use, to generate an electric field proximate to the sensing surface region, the electric field being sufficient to generate oxidising species in the fluid for removing contaminant material from the sensing surface region.

14 . The single crystal diamond according to claim 13 , wherein the electrode region comprises any of:
electrically conducting boron doped diamond; graphite; and a metal material deposited on the surface of the single crystal diamond.

15 . The single crystal diamond according to claim 13 , wherein the quantum spin defects are selected from any of:
silicon containing defects; nickel containing defects; chromium containing defects; germanium containing defects; tin containing defects; nitrogen containing defects; and negatively charged nitrogen-vacancy defects, NV − .

16 .- 18 . (canceled)

19 . The single crystal diamond according to claim 13 , further comprising a plurality of sensing surface regions.

20 . (canceled)

21 . (canceled)

22 . A method of using a sensor assembly, the sensor assembly comprising single crystal diamond material, a first electrode and a second electrode, the single crystal diamond material comprising a sensing surface region comprising a plurality of quantum spin defects, the method comprising:
allowing a fluid to pass over the sensing surface region of the single crystal diamond material; and generating an electric field between the first electrode and the second electrode and proximate to the sensing surface region, such that the field generates oxidising species in the fluid, the oxidising species for removing contaminant material from the sensing surface region.

23 . The method according to claim 22 , further comprising alternating the electric field polarity between the first and second electrodes.

24 . The method according to claim 22 , wherein the electric field is generated periodically.

25 . The method according to claim 22 , comprising, prior to generating the electric field, determining that the electric field is to be generated.

26 . The method according to claim 25 , wherein the determining step comprises determining that a measurement obtained from the sensing surface region has deviated from a predetermined value by a predetermined amount.

27 . (canceled)

Assignees

• Element Six Tech Ltd

Inventors

• Edmonds Andrew Mark
• Markham Matthew Lee

Classifications

• C30B29/04 Primary

  Diamond · CPC title

• G01N24/10

  by using electron paramagnetic resonance (G01N24/12 takes precedence) · CPC title

• C30B33/04

  using electric or magnetic fields or particle radiation · CPC title

• C30B33/00

  After-treatment of single crystals or homogeneous polycrystalline material with defined structure (C30B31/00 takes precedence) · CPC title

• C30B31/20

  Doping by irradiation with electromagnetic waves or by particle radiation · CPC title