Method of Cladding Ceramic Optical Fibers

Patent metadata

Field	Value
Publication number	US-2025059099-A1
Application number	US-202418802679-A
Country	US
Kind code	A1
Filing date	Aug 13, 2024
Priority date	Aug 14, 2023
Publication date	Feb 20, 2025
Grant date	—

Abstract

A method of forming a crystalline core/crystalline clad (C4) optical fiber. The method comprises coextruding a cladding mixture of a plasticizer and a binder with a yttrium aluminum garnet (YAG) core. The coextrusion dynamically clads a polycrystalline cladding onto the YAG core to yield a green C4 optical fiber. The C4 optical fiber is then densified, preferably in two steps sintering and hot isostatic pressing. The resulting optical C4 fiber has greater power capacity than a glass fiber labor host.

First claim

What is claimed is:

1 . A method of forming a crystalline core/crystalline clad (C4) optical fiber, the method comprising the steps of:
providing a coextrusion mixture comprising a binder, yttrium aluminum garnet (YAG) powder, a binder and optionally a plasticizer, in a pressurized vessel, the pressurized vessel having a coextrusion mixture inlet for receiving the coextrusion mixture, a core inlet for receiving a crystalline core having an outer surface and an extrusion nozzle for extruding a green C4 fiber therethrough; drawing the YAG core into the core inlet, through the pressurized vessel and outwardly through the extrusion nozzle to dynamically clad the coextrusion mixture within the vessel onto the outer surface of the core to yield a green C4 fiber; and densifying the green C4 fiber to yield an optically transparent C4 fiber.

2 . A method according to claim 1 wherein the YAG core is a single crystal YAG core.

3 . A method according to claim 2 wherein the binder of the coextrusion mixture comprises a solvent soluble polymer.

4 . A method according to claim 2 wherein the binder of the coextrusion mixture comprises ceramic powder and organic materials and the plasticizer of the coextrusion mixture comprises glycerol.

5 . A method according to claim 4 wherein the coextrusion mixture has a viscosity of 7000 cps to 200000 cps.

6 . A method according to claim 5 wherein the coextrusion mixture is inserted into the coextrusion inlet, pressure fed through the vessel towards the extrusion nozzle while joined to the core to extrude the core with cladding joined thereto outwardly through the extrusion nozzle to yield the green C4 fiber.

7 . A method according to claim 6 wherein the green C4 fiber is extruded at a rate of 1 cm/sec to 5 cm/sec.

8 . A method of forming a crystalline core/crystalline clad (C4) optical fiber, the method comprising the steps of:
providing a coextrusion mixture comprising a plasticizer and a binder in a pressurized vessel, the pressurized vessel having a coextrusion mixture inlet for receiving the coextrusion mixture, a core inlet for receiving an elongate yttrium aluminum garnet (YAG) core having an outer surface and an extrusion nozzle for extruding a green C4 fiber therethrough; drawing the YAG core into the core inlet, through the pressurized vessel and outwardly through the extrusion nozzle to dynamically clad the coextrusion mixture within the vessel onto the outer surface of the core to yield a green C4 fiber; thermally drying the green C4 fiber; and densifying the green C4 fiber to yield an optically transparent C4 fiber.

9 . A method according to claim 8 wherein the green C4 fiber is densified in two stages.

10 . A method according to claim 9 wherein the green C4 fiber is dried by raising the oxygen air temperature from room temperature to a temperature of 550° C. to 700° C. for a period of 6 to 16 hours, then cooling the C4 fiber to 20° C.

11 . A method according to claim 10 further comprising the step of applying tension to the green C4 fiber during drying.

12 . A method according to claim 11 wherein the two stages of densification comprise sintering followed by hot isostatic pressing.

13 . A method of forming a crystalline core/crystalline clad (C4) optical fiber, the method comprising the steps of:
providing a coextrusion mixture comprising a plasticizer and a binder in a pressurized vessel, the pressurized vessel having a coextrusion mixture inlet for receiving the coextrusion mixture, a core inlet for receiving an elongate yttrium aluminum garnet (YAG) core having an outer surface and an extrusion nozzle for extruding a green C4 fiber therethrough; drawing the YAG core into the core inlet, through the pressurized vessel and outwardly through the extrusion nozzle to dynamically clad the coextrusion mixture within the vessel onto the outer surface of the core to yield a green C4 fiber; thermally drying the green C4 fiber; and thermally densifying the green C4 fiber to yield an optically transparent C4 optical fiber.

14 . A method according to claim 13 wherein the step of thermally densifying the comprises:
sintering the green C4 fiber by raising the ambient temperature from 20° C. to a temperature of 1550° C. to 1700° C. at a rate of 5° C./min. to 15° C./min.;
holding the green C4 fiber at 1550° C. to 1700° C. for a period of 2 hours to 10 hours; and
cooling the green C4 fiber to 20° C. at a rate of 10° C./min. to 40° C./min.

15 . A method according to claim 14 further comprising the step of sintering the C4 fiber under ambient atmosphere following the step of cooling.

16 . A method according to claim 15 further comprising the step of hot isostatically pressing the C4 fiber following the step of sintering the C4 fiber.

17 . A method according to claim 16 wherein the step of hot isostatically pressing the C4 fiber comprises:
heating the green C4 fiber from room temperature to a range of 1550° C. to 1700° C.;
holding the green C4 fiber at 1550° C. to 1700° C. for a period of 2 hours to 10 hours; and
cooling the green C4 fiber to room temperature.

18 . A method according to claim 17 wherein the step of thermally densifying the C4 fiber comprises hot isostatically pressing the C4 fiber in an argon atmosphere.

19 . A method according to claim 18 wherein the argon atmosphere is held at a pressure of 10 ksig TO 50 ksig.

20 . A method according to claim 18 further comprising the step of sintering the C4 fiber prior to the step of hot isostatically pressing the C4 fiber.

Assignees

• Us Gov Air Force

Inventors

• Kim Hyunjun
• Hay Randall
• Averett Kent
• Corns Randall
• Gray Benjamin
• Sirn Brian

Classifications

• C23C14/34

  Sputtering · CPC title

• C23C14/08

  Oxides (C23C14/10 takes precedence) · CPC title

• G02B6/03694 Primary

  Multiple layers differing in properties other than the refractive index, e.g. attenuation, diffusion, stress properties · CPC title

• C04B2235/6567

  Treatment time · CPC title

• C04B2235/6565

  Cooling rate · CPC title