Systems and methods for producing hydrogen gas from methane and carbon dioxide

Patent metadata

Field	Value
Publication number	US-2025059033-A1
Application number	US-202318233574-A
Country	US
Kind code	A1
Filing date	Aug 14, 2023
Priority date	Aug 14, 2023
Publication date	Feb 20, 2025
Grant date	—

Abstract

Hydrogen may be produced by a method that includes a first reaction where methane is reacted with carbon dioxide to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

First claim

What is claimed is:

1 . A method for producing hydrogen gas, the method comprising:
in a first reaction, reacting methane with carbon dioxide to form at least carbon monoxide and hydrogen; in a second reaction, reacting at least water with a metal in a reduced state to form at least hydrogen and a metal in an oxidized state; and in a third reaction, reacting the metal in an oxidized state produced in the second reaction with at least a portion of the carbon monoxide produced in the first reaction to form carbon dioxide and to reduce the metal in the oxidized state.

2 . The method of claim 1 , wherein the second and third reactions are sequentially alternated such that the reducing of the metal in the oxidized state in the third reaction forms the metal in a reduced state utilized in the second reaction.

3 . The method of claim 1 , further comprising:
in a fourth reaction, reacting carbon dioxide and water with the metal in a reduced state to form at least hydrogen and a metal carbonate; and in a fifth reaction, reacting the metal carbonate with water to from the metal in an oxidized state, carbon dioxide, and hydrogen.

4 . The method of claim 1 , wherein the metal in an oxidized state comprises one or more of zinc oxide, iron oxide, tin oxide, cesium oxide, magnesium oxide, cobalt oxide, cadmium oxide, or germanium oxide.

5 . The method of claim 1 , wherein the metal in an oxidized state comprises iron oxide.

6 . The method of claim 1 , wherein the metal in an oxidized state comprises Fe 3 O 4 .

7 . The method of claim 1 , wherein the metal in a reduced state comprises Fe 0 .

8 . The method of claim 1 , wherein the first reaction is in a first reactor, and the second reaction and third reaction are in a second reactor.

9 . A method for producing hydrogen, the method comprising:
passing methane and carbon dioxide to a first reactor, such that the methane and carbon dioxide react to form at least carbon monoxide and hydrogen; passing water to a second reactor comprising a metal in a reduced state, such that the water reacts with the metal in a reduced state to form at least hydrogen and a metal in an oxidized state in the second reactor; and passing at least a portion of the carbon monoxide produced in the first reactor to the second reactor while the metal in an oxidized state is positioned in the second reactor, such that the metal in an oxidized state reacts with carbon monoxide to form at least the metal in a reduced state and carbon dioxide.

10 . The method of claim 9 , wherein the passing of the water to the second reactor and the passing of at least a portion of the carbon monoxide produced in the first reactor to the second reactor are sequentially alternated, such that the metal in a reduced state formed from the reaction of the metal in an oxidized state with carbon dioxide forms the metal in a reduced state that is reacted with water.

11 . The method of claim 9 , further comprising:
passing carbon dioxide to the second reactor comprising the metal in a reduced state such that the metal in a reduced state reacts with carbon dioxide and water to form at least hydrogen and a metal carbonate; and passing water to the second reactor comprising the metal carbonate and hydrogen such that the metal carbonate reacts with the water to form the metal in an oxidized state and carbon dioxide.

12 . The method of claim 11 , wherein passing carbon dioxide to the second reactor comprises:
passing the carbon dioxide produced in the second reactor and hydrogen produced in the second reactor to a second separation unit; separating the carbon dioxide from the hydrogen in the second separation unit; passing the carbon dioxide separated in the second separation unit to a carbon dioxide storage vessel; and passing the carbon dioxide from the carbon dioxide storage vessel to the second reactor.

13 . The method of claim 9 , wherein passing the carbon monoxide produced in the first reactor to the second reactor comprises:
passing at least some of the carbon monoxide produced in the first reactor and the hydrogen produced in the first reactor to a first separation unit; separating the carbon monoxide from the hydrogen in the first separation unit; passing the carbon monoxide separated in the first separation unit to a carbon monoxide storage vessel; and passing the carbon monoxide from the carbon monoxide storage vessel to the second reactor.

14 . The method of claim 9 , wherein passing the carbon monoxide produced in the first reactor to the second reactor comprises directly passing at least a portion of the carbon monoxide produced in the first reactor to the second reactor.

15 . The method of claim 9 , further comprising:
passing water to a third reactor comprising a metal in a reduced state, such that the water reacts with the metal in a reduced state to form at least hydrogen and a metal in an oxidized state in the third reactor; and passing at least a portion of the carbon monoxide produced in the first reactor to the third reactor while the metal in an oxidized state is positioned in the third reactor, such that the metal in an oxidized state reacts with carbon monoxide to form at least the metal in a reduced state and carbon dioxide.

16 . The method of claim 15 , wherein:
the second reactor is oxidizing the metal in the reduced state while the third reactor is reducing the metal in an oxidized state; and the second reactor is reducing the metal in an oxidized state while the third reactor is oxidizing the metal in a reduced state.

17 . The method of claim 9 , wherein the metal in an oxidized state comprises one or more of zinc oxide, iron oxide, tin oxide, cesium oxide, magnesium oxide, cobalt oxide, cadmium oxide, or germanium oxide.

18 . The method of claim 9 , wherein the metal in an oxidized state comprises iron oxide.

19 . The method of claim 9 , wherein the metal in an oxidized state is Fe 3 O 4 .

20 . The method of claim 9 , wherein the metal in a reduced state is Fe 0 .

Assignees

• Saudi Arabian Oil Co

Inventors

• Atilgan Ahmet
• Patel Hasmukh A

Classifications

• C01B3/10

  by reaction of water vapour with metals · CPC title

• C01B2203/80

  Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695 · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/1047

  Group VIII metal catalysts · CPC title

• C01B2203/0475

  the impurity being carbon dioxide · CPC title