Carbon Electrode Material for Improving the Performance of Supercapacitors and Method of Making Carbon Electrode Material

Patent metadata

Field	Value
Publication number	US-2025054708-A1
Application number	US-202418780828-A
Country	US
Kind code	A1
Filing date	Jul 23, 2024
Priority date	Aug 9, 2023
Publication date	Feb 13, 2025
Grant date	—

Abstract

One or more embodiments relate to a CEM having a hierarchical, interconnected, 3D network of thin, crumpled, graphene sheets, wherein the graphene sheets have irregularly shaped, micro-, macro- and meso-scale pore structures, where the CEM material has a BET SSA between approximately 1400 m2 g−1 and approximately 2200 m2 g−1, and where the CEM has a Raman ID/IG intensity ratio between approximately 0.05 to approximately 1.2, and a Raman I2D/IG intensity ratio between approximately 0.4 and approximately 0.8, and supercapacitors using the CEM as electrodes.

First claim

What is claimed is:

1 . A carbon electrode material (CEM) comprising:
a hierarchical, interconnected, 3D network of thin, crumpled, graphene sheets, wherein the graphene sheets comprise irregularly shaped, micro-, meso- and macro-scale pore structures, wherein the CEM comprises a BET SSA between approximately 1400 m 2 g −1 and approximately 2200 m 2 g −1 , and wherein the CEM comprises a Raman I D /I G intensity ratio between approximately 0.05 to approximately 1.2.

2 . The CEM of claim 1 further comprising a Raman I 2D /I G intensity ratio between approximately 0.2 to approximately 0.8.

3 . The CEM of claim 1 further comprising an atomic carbon/oxygen (C/O) ratio between approximately 20 to approximately 100.

4 . The CEM of claim 1 further comprising a total pore volume between approximately 1.5 cm 3 g −1 and approximately 2.5 cm 3 g −1 .

5 . The CEM of claim 1 wherein the pores have a diameter between approximately 0.5 nm and approximately 200 nm.

6 . The CEM of claim 1 wherein the CEM further comprises a conductivity between approximately 1000 Sm −1 and approximately 2500 Sm −1 .

7 . The CEM of claim 1 wherein the CEM further comprises a conductivity of at least 1000 Sm −1 .

8 . The CEM of claim 1 wherein the CEM is configured to have a conductivity of at least 1000 Sm −1 when an electrical current is applied to the CEM.

9 . A supercapacitor comprising:
a first electrode, a second electrode, a porous separator positioned between the first and second electrodes, and an electrolyte in electronic and physical contact with the first and second electrodes and the porous separator, wherein at least one of the first and second electrodes comprise a carbon electrode material (CEM), the CEM comprising:
a hierarchical, interconnected, 3D network of thin, crumpled, graphene sheets, wherein the graphene sheets comprise irregularly shaped, micro-, meso- and macro-scale pore structures, wherein the CEM comprises a BET SSA between approximately 1400 m 2 g −1 and approximately 2200 m 2 g −1 , and wherein the CEM comprises a Raman I D /I G intensity ratio between approximately 0.05 to approximately 1.2.

10 . The supercapacitor of claim 9 wherein the CEM further comprises a Raman I 2D /I G intensity ratio between approximately 0.2 to approximately 0.8.

11 . The supercapacitor of claim 9 wherein the CEM further comprises an atomic carbon/oxygen (C/O) ratio between approximately 20 to approximately 100.

12 . The supercapacitor of claim 9 wherein the CEM further comprises a total pore volume between approximately 1.5 cm 3 g −1 and approximately 2.5 cm 3 g −1 .

13 . The supercapacitor of claim 9 wherein the pores have a diameter between approximately 0.5 nm and approximately 200 nm.

14 . The supercapacitor of claim 9 wherein the CEM further comprises a conductivity between approximately 1000 Sm −1 and approximately 2500 Sm −1 .

15 . The supercapacitor of claim 9 wherein the CEM further comprises a conductivity of at least 1000 Sm −1 .

16 . The supercapacitor of claim 9 further comprising a maximum gravimetric energy density at current density of 1.0 A/g between approximately 8.0 Wh kg −1 and approximately 20.0 Wh kg −1 .

17 . The supercapacitor of claim 9 further comprising a gravimetric specific capacitance between approximately 150 F/g and approximately 250 F/g per gram CEM at a current density of 1.0 A/g of CEM.

18 . The supercapacitor of claim 9 further comprising a gravimetric specific capacitance of at least 150 F/g of CEM at a current density of 1.0 A/g of CEM.

Assignees

• Us Energy

Inventors

• Matranga Christopher
• Wang Congjun
• Pham Viet Hung
• Weidman Jennifer
• Gao Yuan

Classifications

• H01G11/26

  characterised by their structure, e.g. multi-layered, porosity or surface features · CPC title

• H01G11/32

  Carbon-based · CPC title

• H01G11/36

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01G11/24

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title

• C01B32/184

  Preparation · CPC title