Ternary additives for electrolytes of batteries including silicon oxide-containing negative electrodes and batteries including the same

Patent metadata

Field	Value
Publication number	US-2025046855-A1
Application number	US-202318454359-A
Country	US
Kind code	A1
Filing date	Aug 23, 2023
Priority date	Aug 4, 2023
Publication date	Feb 6, 2025
Grant date	—

Abstract

A battery that cycles lithium ions includes a negative electrode and an ionically conductive electrolyte. The negative electrode includes an electroactive material comprising a silicon oxide-based material. The electrolyte includes an organic solvent, a lithium salt, and a ternary additive system comprising a phosphite compound, a borate compound, and a sulfate compound.

First claim

What is claimed is:

1 . A battery that cycles lithium ions, the battery comprising:
a negative electrode comprising an electroactive material comprising a silicon oxide-based material; and an electrolyte in physical contact with the negative electrode, the electrolyte comprising:
an organic solvent;
a lithium salt; and
a ternary additive system comprising a phosphite compound, a borate compound, and a sulfate compound.

2 . The battery of claim 1 , wherein the phosphite compound consists of tris(trimethylsilyl)phosphite.

3 . The battery of claim 1 , wherein the borate compound comprises lithium bis(oxalato)borate.

4 . The battery of claim 1 , wherein the sulfate compound consists of 1,3,2-dioxathiolane 2,2-dioxide.

5 . The battery of claim 1 , wherein the ternary additive system constitutes, by weight, greater than or equal to about 0.3% to less than or equal to about 9% of the electrolyte.

6 . The battery of claim 1 , wherein the phosphite compound constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte, the borate compound constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte, and the sulfate compound constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte.

7 . The battery of claim 1 , wherein the electroactive material constitutes, by weight, greater than or equal to about 90% to less than or equal to about 99% of the negative electrode, and wherein the electroactive material comprises the silicon oxide-based material and a carbon-based material.

8 . The battery of claim 7 , wherein the silicon oxide-based material comprises lithium silicon oxide, Li y SiO x , where x is greater than zero and less than or equal to 2 and y is greater than zero and less than or equal to 1.

9 . The battery of claim 7 , wherein the carbon-based material comprises graphite.

10 . The battery of claim 7 , wherein the silicon oxide-based material constitutes, by weight, greater than or equal to about 10% to less than or equal to about 30% of the electroactive material, and wherein the carbon-based material constitutes, by weight, greater than or equal to about 70% to less than or equal to about 90% of the electroactive material.

11 . The battery of claim 1 , wherein, during initial charge of the battery, at least one of the phosphite compound, the borate compound, or the sulfate compound decomposes and forms a solid electrolyte interface on surfaces of the electroactive material that isolates the electroactive material from physical contact with the electrolyte, and wherein, during subsequent cycling of the battery, the solid electrolyte interface prevents chemical reactions between the electroactive material and the electrolyte.

12 . The battery of claim 1 , wherein the lithium salt comprises lithium hexafluorophosphate.

13 . The battery of claim 1 , wherein the organic solvent comprises a mixture of ethylene carbonate and dimethyl carbonate.

14 . The battery of claim 13 , wherein the electrolyte further comprises a secondary additive comprising fluoroethylene carbonate (FEC), vinylene carbonate (VC), or a combination thereof.

15 . A battery that cycles lithium ions, the battery comprising:
a positive electrode comprising a lithium transition metal oxide; a negative electrode spaced apart from the positive electrode, the negative electrode comprising an electroactive material comprising a silicon oxide-based material; and an electrolyte that provides an ionically conductive pathway for the transport of lithium ions between the positive electrode and the negative electrode, the electrolyte comprising:
an organic solvent comprising a mixture of ethylene carbonate and dimethyl carbonate;
a lithium salt comprising lithium hexafluorophosphate; and
a ternary additive system comprising tris(trimethylsilyl)phosphite, lithium bis(oxalato)borate, and 1,3,2-dioxathiolane 2,2-dioxide.

16 . The battery of claim 15 , wherein the tris(trimethylsilyl)phosphite constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte, the lithium bis(oxalato)borate constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte, and the 1,3,2-dioxathiolane 2,2-dioxide constitutes, by weight, greater than or equal to about 0.1% to less than or equal to about 3% of the electrolyte.

17 . The battery of claim 15 , wherein the electroactive material constitutes, by weight, greater than or equal to about 90% to less than or equal to about 99% of the negative electrode, wherein the electroactive material comprises greater than or equal to about 10% to less than or equal to about 30% lithiated silicon oxide and greater than or equal to about 70% to less than or equal to about 90% of a carbon-based material.

18 . The battery of claim 17 , wherein the lithium silicon oxide is represented by formula Li y SiO x , where x is greater than zero and less than or equal to 2 and y is greater than zero and less than or equal to 1, and wherein the carbon-based material comprises graphite.

19 . The battery of claim 15 , wherein the lithium transition metal oxide is selected from the group consisting of lithium nickel manganese aluminum oxide, lithium nickel cobalt manganese aluminum oxide, lithium nickel manganese cobalt oxide, and combinations thereof.

20 . The battery of claim 15 , wherein the electrolyte further comprises a secondary additive comprising fluoroethylene carbonate (FEC), vinylene carbonate (VC), or a combination thereof.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Kong Dewen
• Chen Si
• Liu Haijing
• Verbrugge Mark W

Classifications

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/483

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title