Veneer type tube or hose with diffusion barrier

Patent metadata

Field	Value
Publication number	US-2025035240-A1
Application number	US-202418782600-A
Country	US
Kind code	A1
Filing date	Jul 24, 2024
Priority date	Jul 25, 2023
Publication date	Jan 30, 2025
Grant date	—

Abstract

The disclosure relates to a multilayered hose ( 1, 10 ) with a plurality of coaxially arranged sheaths ( 2, 3, 4, 5, 6, 7, 8, 12, 13 ). The multilayered hose ( 1, 10 ) includes at least a force bearing sheath ( 2, 6 ), a diffusion reducing sheath ( 4 ), and an adhesion promoting layer ( 3, 5 ) that is arranged between the force bearing sheath ( 2, 6 ) and the diffusion reducing sheath ( 4 ) and that increases the bonding force between said force bearing sheath ( 2, 6 ) and said diffusion reducing sheath ( 4 ). The adhesion promoting layer ( 3, 5 ) includes a mixture of: 65 to 85 parts of acrylonitrile butadiene rubber, 15 to 35 parts of styrene butadiene rubber, 75 to 125 parts of carbon black N990, 30 to 100 parts of calcium magnesium carbonate, 5 to 15 parts of zinc oxide, 5 to 20 parts of magnesium-aluminium hydroxycarbonate, 25 to 125 parts of resin package blend, 2 to 10 parts of N-(1.3-dimethylbutyl)-N′-phenyl-p-phenylendiamine, 5 to 15 parts of triallyl cyanurate, and 0.5 to 5 parts of a vulcanizing agent.

First claim

What is claimed is:

1 . A multilayered tube or hose comprising a plurality of coaxially arranged sheaths, wherein the coaxially arranged sheaths are bonded together, the multilayered tube or hose comprising at least:
a force bearing sheath, a diffusion reducing sheath, and an adhesion promoting layer that is arranged between the force bearing sheath and the diffusion reducing sheath and that increases the bonding force between said force bearing sheath and said diffusion reducing sheath, wherein said adhesion promoting layer that comprises a mixture of: 65 to 85 parts by weight of acrylonitrile butadiene rubber, 15 to 35 parts by weight of styrene butadiene rubber, 75 to 125 parts by weight of carbon black N990, 5 to 15 parts by weight of zinc oxide, 2 to 10 parts by weight of N-(1.3-Dimethylbutyl)-N′-phenyl-p-phenylendiamine, 0.5 to 5 parts by weight of a vulcanizing agent, and 25 to 125 parts by weight of resin package blend, wherein the resin package blend comprises 5 to 25 parts by weight of hexa(methoxymethyl) melamine liquid resin; 5 to 15 parts by weight of self-curing modified phenolic resin ingredient; 5 to 25 parts by weight of aliphatic-aromatic soft resin; 5 to 25 parts by weight of benzene-1,3-diol bonding agent; 5 to 25 parts by weight of aromatic hydrocarbon resin ingredient, in particular per 100 parts by weight of elastomer comprising acrylonitrile butadiene rubber and styrene butadiene rubber, 5 to 15 parts by weight of triallyl cyanurate, 30 to 100 parts by weight of calcium magnesium carbonate, and 5 to 20 parts of by weight magnesium-aluminium hydroxycarbonate.

2 . The multilayered tube or hose according to claim 1 , wherein the acrylonitrile butadiene rubber comprises 18 to 28 weight-% acrylonitrile and/or in that the styrene butadiene rubber comprises 10 to 25 weight-% of styrene, wherein the butadiene fraction is preferably composed of 60 to 70 weight-% trans-1,4 configuration, 15 to 20 weight-% cis-1,4 configuration, balancing 1,2 configuration, in particular per 100 parts of the elastomer comprising acrylonitrile butadiene rubber and styrene butadiene rubber.

3 . The multilayered tube or hose according to claim 1 , wherein the vulcanizing agent comprises dicumyl peroxide.

4 . The multilayered tube or hose according to claim 1 , wherein said diffusion reducing sheath comprises a polyamide plastic material, preferably a poly[azanediyl(1-oxohexane-1,6-diyl)] or poly(azanediyladipoylazanediylhexane-1,6-diyl) material.

5 . The multilayered tube or hose according to claim 1 , wherein said at least one force bearing sheath comprises acrylonitrile butadiene rubber, styrene butadiene rubber and/or ethylene propylene diene monomer.

6 . The multilayered tube or hose according to claim 1 , wherein at least a second force bearing sheath, wherein the diffusion reducing sheath is preferably embedded between at least two force bearing sheaths.

7 . The multilayered tube or hose according to claim 1 , wherein at least a low flammable layer, in particular a low flammable sheath or coating, said low flammable layer preferably comprising nitrile rubber and/or poly vinyl chloride.

8 . The multilayered tube or hose according to claim 1 , wherein at least a strength reinforcing means, in particular a strength reinforcing fabrics, more preferably a crimped or non-crimped fabrics.

9 . The multilayered tube or hose according to claim 1 , wherein at least an abrasion resistant sheath, in particular on the inside of the multilayered tube or hose, where the abrasion resistant sheath preferably comprises a thermoplastic polyurethane material.

10 . The multilayered tube or hose according to claim 9 , wherein at least a second type of adhesion promoting sheath between said abrasion resistant sheath and the at least one adjacent sheath, preferably the at least one adjacent force bearing sheath.

11 . The multilayered tube or hose according to claim 10 , wherein said second type of adhesion promoting sheath comprises a mixture of:
55 to 85 parts by weight of acrylonitrile butadiene rubber, 5 to 25 parts by weight of styrene butadiene rubber, 5 to 25 parts by weight of ethylene propylene diene monomer 75 to 125 parts by weight of carbon black N990, 30 to 90 parts by weight of calcium magnesium carbonate, 5 to 15 parts by weight of zinc oxide, 5 to 25 parts by weight of magnesium-aluminium hydroxycarbonate, 2 to 10 parts by weight of N-(1.3-dimethylbutyl)-N′-phenyl-p-phenylendiamine, 5 to 15 parts by weight of triallyl cyanurate, 0.5 to 5 parts by weight of a vulcanizing agent, and 20 to 95 parts by weight of resin package blend, wherein the resin package blend comprises 5 to 25 parts by weight of hexa(methoxymethyl) melamine liquid resin; 5 to 15 parts by weight of self-curing modified phenolic resin ingredient; 5 to 25 parts by weight of aliphatic-aromatic soft resin; 5 to 25 parts by weight of benzene-1,3-diol bonding agent; 5 to 25 parts by weight of aromatic hydrocarbon resin ingredient, in particular per 100 parts by weight of elastomer comprising acrylonitrile butadiene rubber and styrene butadiene rubber.

12 . The multilayered tube or hose according to claim 11 , wherein the ethylene propylene diene monomer comprises 44 to 85 weight-% of ethylene and 2.8 to 11 weight-% ethylidene norbornene, in particular per 100 parts of the elastomer comprising acrylonitrile butadiene rubber and styrene butadiene rubber.

Assignees

• Danfoss As

Inventors

• Can Karabulut Burcu
• Eren Muslum
• Sasmaz Semih
• Cebeci Okan
• Arslan Abdurrahman
• Muco Recep
• Aptiogullari Erhan

Classifications

• C08K2003/2296

  of zinc · CPC title

• B32B2307/554

  Wear resistance · CPC title

• B32B2250/24

  All layers being polymeric · CPC title

• B32B2597/00

  Tubular articles, e.g. hoses, pipes · CPC title

• F16L11/045

  with four or more layers without reinforcement · CPC title