Electrolyte and rechargeable lithium battery including the same

Patent metadata

Field	Value
Publication number	US-2025023098-A1
Application number	US-202418659854-A
Country	US
Kind code	A1
Filing date	May 9, 2024
Priority date	Jul 12, 2023
Publication date	Jan 16, 2025
Grant date	—

Abstract

An electrolyte and a rechargeable lithium battery including the same are provided. The electrolyte includes a non-aqueous organic solvent, a lithium salt, and a lanthanide metal imide salt.

First claim

What is claimed is:

1 . An electrolyte comprising:
a non-aqueous organic solvent; a lithium salt; and a lanthanide metal imide salt.

2 . The electrolyte of claim 1 , wherein an amount of the lanthanide metal imide salt is about 0.05 to about 5 wt % based on 100 wt % of the electrolyte.

3 . The electrolyte of claim 2 , wherein an amount of the lanthanide metal imide salt is about 0.05 to about 0.25 wt % based on 100 wt % of the electrolyte.

4 . The electrolyte of claim 1 , wherein the lanthanide metal of the lanthanide metal imide salt is lanthanum (La), cerium (Ce), or a combination thereof.

5 . The electrolyte of claim 1 , wherein the lanthanide metal imide salt is LaFSI, lanthanum (III) bis(trifluoromethanesulfonyl) imide (LaTFSI), CeFSI, CeTFSI, or a combination thereof.

6 . The electrolyte of claim 1 , wherein the non-aqueous organic solvent comprises a carbonate-based solvent, an ester-based solvent, an ether-based solvent, a ketone-based solvent, an alcohol-based solvent, and/or an aprotic solvent.

7 . The electrolyte of claim 6 , wherein the non-aqueous organic solvent comprises the carbonate-based solvent in which a cyclic carbonate and a chain carbonate are mixed in a volume ratio of about 1:1 to about 1:9.

8 . The electrolyte of claim 7 , wherein
the cyclic carbonate comprises ethylene carbonate (EC), and the chain carbonate comprises ethyl methyl carbonate (EMC) and dimethyl carbonate (DMC).

9 . The electrolyte of claim 1 , wherein
the lithium salt comprises one or more selected from among LiPF 6 , LiBF 4 , LiSbF 6 , LiAsF 6 , LiClO 4 , LiAlO 2 , LiAlCl 4 , LIPO 2 F 2 , LICl, LiI, LiN (SO 3 C 2 F 5 ) 2 , Li(FSO 2 ) 2 N (lithium bis(fluorosulfonyl)imide (LiFSI), LiC 4 F 9 SO 3 , LiC 4 F 9 SO 3 , LiN (C x F 2x+1 SO 2 ) (C y F 2y+1 SO 2 ), wherein x and y are integers of 1 to 20, lithium trifluoromethane sulfonate, lithium tetrafluoroethanesulfonate, lithium difluorobis(oxalato)phosphate (LiDFOB), and lithium bis(oxalato) borate (LiBOB).

10 . The electrolyte of claim 9 , wherein a concentration of the lithium salt in the electrolyte is about 1.0 M to about 2.0 M.

11 . A rechargeable lithium battery, comprising:
a positive electrode comprising a positive electrode active material; a negative electrode comprising a negative electrode active material; and the electrolyte according to claim 1 .

12 . The rechargeable lithium battery of claim 11 , wherein the positive electrode active material comprises one or more compounds represented by Chemical Formula 1:
Li x M 1 y M 2 z M 3 1−y−z O 2   Chemical Formula 1
wherein, in Chemical Formula 1, 0.5≤x≤1.8; 0<y≤1; 0≤z≤1; 0≤y+z≤1; and M 1 , M 2 , and M 3 are each independently selected from among metals selected from among Ni, Co, Mn, Al, Sr, Mg, La, and combinations thereof.

13 . The rechargeable lithium battery of claim 12 , wherein the positive electrode active material is a compound represented by Chemical Formula 1-1 or Formula 1-2:
Li x1 Ni y1 CO z1 Al 1−y1−z1 O 2 ,  Chemical Formula 1-1
in Chemical Formula 1-1, 1≤x1≤1.2; 0.7≤y1≤1; 0≤z1≤0.3; and 0.7≤y1+z1≤1; and
Li x2 Ni y2 CO z2 Mn 1−y2−z2 O 2 ,  Chemical Formula 5-2

in Chemical Formula 1-2, 1≤x1≤1.2; 0.7≤y2≤1; 0≤z2≤0.3; and 0.7≤y2 z2≤1.

14 . The rechargeable lithium battery of claim 11 , wherein the negative electrode active material comprises a Si-based negative electrode active material.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Cho Erang
• Seo Jinah
• Lim Jin-Hyeok
• Koh Sujeong
• Kim Yunhee

Classifications

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0567 Primary

  characterised by the additives · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title