System and methods relating to interpenetrating multi-electrodes and fabrication thereof for electrochemical devices

Patent metadata

Field	Value
Publication number	US-2025006887-A1
Application number	US-202318217259-A
Country	US
Kind code	A1
Filing date	Jun 30, 2023
Priority date	Jun 30, 2023
Publication date	Jan 2, 2025
Grant date	—

Abstract

The present disclosure relates to a multi-electrode electrochemical apparatus. In one embodiment the apparatus has a first beam-like structure having a first material coating, with the first beam-like structure forming a first electrode. A second structure is included which has a second material coating. The second structure forms a second electrode. The first and second structures are further configured in an interpenetrating fashion within a defined 3D space to form an electrochemical apparatus, and without physical contact at any point within the defined 3D space.

First claim

What is claimed is:

1 . A multi-electrode electrochemical apparatus, the apparatus comprising:
a first beam-like structure having a first material coating, the first beam-like structure forming a first electrode; a second structure having a second material coating, the second structure forming a second electrode; and the first and second structures being configured in an interpenetrating fashion within a defined 3D space to form an electrochemical apparatus, and without physical contact at any point within the defined 3D space.

2 . The apparatus of claim 1 , wherein the first beam-like structure comprises a beam-like lattice structure of interconnected beam-like elements.

3 . The apparatus of claim 1 , wherein the first beam-like structure comprises a plurality of parallel arranged beam-like elements interconnected at least at one end thereof.

4 . The apparatus of claim 3 , wherein the second structure comprises a plurality of curving, parallel arranged beam-like elements that wrap around ones of the beam-like elements of the first beam-like structure.

5 . The apparatus of claim 4 , wherein:
the plurality of parallel arranged beam-like elements of the first beam-like structure are coupled together at both of first and second opposing ends thereof; and wherein the curving, parallel arranged beam-like elements are coupled together at opposing ends thereof.

6 . The apparatus of claim 1 , wherein the second structure also comprises a beam-like lattice structure.

7 . The apparatus of claim 1 , wherein the second structure comprises a triply periodic minimal surface.

8 . The apparatus of claim 3 , wherein the triply periodic minimal surface comprises a gyroid triply periodic minimal surface.

9 . The apparatus of claim 8 , further comprising a third beam-like lattice structure which is configured in an interpenetrating fashion with the first and second structures within the defined 3D volume, and not in contact with either of the first or second beam-like structures.

10 . The apparatus of claim 1 , wherein at least one of the first or second material coatings is metal.

11 . The apparatus of claim 1 , wherein at least one of the first or second material coatings is at least one of copper or nickel.

12 . The apparatus of claim 1 , wherein the first and second structures comprise are initially formed from polymer, then pyrolyzed, and then plated with the first and second materials.

13 . The apparatus of claim 1 , wherein:
the first structure forms a lattice-like structure with elements radiating out from a first axial center thereof; the second structure forms a lattice-like structure with elements radiating out from a second axial center thereof, and where the second axial center is aligned with the first axial center; and wherein the first and second structures form a disc-like electrochemical cell.

14 . A method for forming a multi-electrode electrochemical apparatus using an additive manufacturing system, the method comprising:
printing first and second structures such that the first and second have portions thereof which form an interpenetrating configuration within a defined 3D volume, and without physically contacting one another within the defined 3D volume; and plating the first and second structures with first and second materials, respectively.

15 . The method of claim 14 , wherein printing the first and second structures comprises printing at least one of the first and second structures as a beam-like structure having a plurality of interconnected beam-like elements forming a lattice structure.

16 . The method of claim 14 , wherein printing the first and second structures comprises printing at least one of the first and second structures as a triply periodic minimal surface structure.

17 . The method of claim 14 , wherein printing the first and second structures comprises printing the first structure as a structure having a plurality of parallel extending rods, and the second structure as a plurality of spiral curving rods which wrap around the plurality of parallel extending rods.

18 . The method of claim 14 , wherein the printing of the first and second beam-like structures comprises printing the first and second beam-like structures from a polymer.

19 . The method of claim 18 , further comprising pyrolyzing the first and second beam-like structures before plating the first and second beam-like structures with the first and second materials.

20 . The method of claim 14 , wherein plating the first and second beam-like structures comprises plating at least one of the first and second beam-like structures with a metal.

Assignees

• L Livermore Nat Security Llc

Inventors

• Dudukovic Nikola
• Clemens Auston Louis
• Chandrasekaran Swetha
• Worsley Marcus A

Classifications

• H01M4/70

  characterised by shape or form · CPC title

• H01M4/0411

  by extrusion · CPC title

• H01M4/133 Primary

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title