Insulated wire and cable using halogen-free flame-retardant resin composition
US-2018158571-A1 · Jun 7, 2018 · US
US2024425687A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2024425687-A1 |
| Application number | US-202218698528-A |
| Country | US |
| Kind code | A1 |
| Filing date | Oct 5, 2022 |
| Priority date | Oct 5, 2021 |
| Publication date | Dec 26, 2024 |
| Grant date | — |
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The invention provides a cable, preferably a power cable, comprising one or more conductors surrounded by at least one layer, preferably an insulation layer, wherein said layer comprises a polymer composition comprising: (i) at least 75 wt % of an ethylene based plastomer; and (ii) 0.2 to 10 wt % of an amine filler, oxide filler or mixture thereof; and wherein said polymer composition has a dielectric loss expressed as tan δ (50 Hz) of 200×10 −4 or less, when measured at 500 V/mm and 90° C. as described in the description part under “Determination methods”.
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1 . A cable comprising one or more conductors surrounded by at least one layer, wherein said layer comprises a polymer composition comprising: at least 75 wt % of an ethylene based plastomer; and 0.2 to 10 wt % of an amine filler, an oxide filler, or mixtures thereof, and wherein said polymer composition has a dielectric loss expressed as tan δ (50 Hz) of 200×10 −4 or less, when measured at 500 V/mm and 90° C. as described in the description part under “Determination methods”. 2 . A cable comprising one or more conductors surrounded by at least one layer wherein said layer comprises a polymer composition comprising: (i) 5 to 50 wt % of an ethylene based plastomer; and (ii) 50 to 95 wt % of a polyolefin (a) selected from the group consisting of an LDPE, polypropylene homopolymer, random heterophasic polypropylene copolymer and mixtures thereof; and wherein said polymer composition has a dielectric loss expressed as tan δ (50 Hz) of 200×10 −4 or less, when measured at 500 V/mm and 90° C. as described in the description part under “Determination methods”. 3 . The cable of claim 2 , wherein the polymer composition further comprises (iii) 0.2 to 10 wt % of an amine filler, oxide filler, or mixtures thereof; and wherein said polymer composition has a dielectric loss expressed as tan δ (50 Hz) of 50×10 −4 or less, when measured at 500 V/mm and 90° C. as described in the description part under “Determination methods”. 4 . The cable as claimed in claim 1 , wherein said ethylene based plastomer is an ethylene copolymer with one or more alpha-olefin comonomers. 5 . The cable as claimed in claim 1 , wherein said amine filler, oxide filler or mixture thereof is present in an amount of 0.5 to 8.0 wt %, relative to the weight of the polymer composition as a whole. 6 . The cable as claimed in claim 1 , wherein said amine filler is a derivative of cyanamide. 7 . The cable as claimed in claim 1 , wherein said oxide filler is a metal or metalloid oxide. 8 . The cable as claimed in claim 1 , wherein said oxide filler has: a specific surface area (BET) of 50 to 600 m 2 /g, when measured as described in the description part under “Determination methods”; an average particle size of 5 to 50 nm, when measured as described in the description part under “Determination methods”; a tamped density of 25 to 100 g/l, when measured as described in the description part under “Determination methods”; or a combination thereof. 9 . The cable as claimed in claim 2 , wherein the ethylene based plastomer is present in an amount of 10 to 40 wt %, relative to the weight of the polymer composition as a whole. 10 . The cable as claimed in claim 2 , wherein said polyolefin (a) is present in an amount of 60 to 90 wt %, relative to the weight of the polymer composition as a whole. 11 . The cable as claimed in claim 2 , wherein the LDPE is an LDPE homopolymer or copolymer. 12 . The cable as claimed in claim 2 , wherein the polypropylene homopolymer is an isotactic polypropylene homopolymer. 13 . The cable as claimed in claim 2 , wherein the random heterophasic polypropylene copolymer comprises 50 to 90 wt % of a propylene copolymer rubber component and 10 to 50 wt % of a propylene homopolymer or copolymer matrix component. 14 . The cable as claimed in claim 1 , wherein said polymer composition is crosslinked in the presence of a crosslinking agent. 15 . A process for producing the cable as claimed in claim 1 , the process comprising the steps of: applying on one or more conductors, the layer comprising the polymer composition. 16 . The cable as claimed in claim 2 , wherein said ethylene based plastomer is an ethylene copolymer with one or more alpha-olefin comonomers. 17 . The cable as claimed in claim 3 , wherein said amine filler, oxide filler or mixture thereof is present in an amount of 0.5 to 8.0 wt %, relative to the weight of the polymer composition as a whole. 18 . The cable as claimed in claim 3 , wherein said amine filler is a derivative of cyanamide. 19 . The cable as claimed in claim 3 , wherein said oxide filler is a metal or metalloid oxide. 20 . The cable as claimed in claim 3 , wherein said oxide filler has: a specific surface area (BET) of 50 to 600 m 2 /g, when measured as described in the description part under “Determination methods”; an average particle size of 5 to 50 nm, when measured as described in the description part under “Determination methods”; a tamped density of 25 to 100 g/l, when measured as described in the description part under “Determination methods”; or a combination thereof. 21 . The cable as claimed in claim 2 , wherein said polymer composition is crosslinked in the presence of a crosslinking agent. 22 . A process for producing the cable as claimed in claim 2 , the process comprising the steps of: applying on one or more conductors, the layer comprising the polymer composition.
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LDPE (radical process) · CPC title
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