Negative electrode and secondary battery including the same

Patent metadata

Field	Value
Publication number	US-2024413335-A1
Application number	US-202218696759-A
Country	US
Kind code	A1
Filing date	Oct 27, 2022
Priority date	Oct 27, 2021
Publication date	Dec 12, 2024
Grant date	—

Abstract

A negative electrode including: a negative electrode current collector; a first negative electrode active material layer on the negative electrode current collector, where the first negative electrode active material layer includes a first carbon-containing active material, a first silicon-containing active material, and a first binder; and a second negative electrode active material layer on the first negative electrode active material layer, where the second negative electrode active material layer includes a second carbon-containing active material, a second silicon-containing active material, and a second binder, wherein the first binder includes styrene-butadiene rubber, and the second binder includes a copolymer comprising an acrylamide-derived unit, an acrylic acid-derived unit, and an acrylonitrile-derived unit.

First claim

1 . A negative electrode comprising:
a negative electrode current collector; a first negative electrode active material layer present on the negative electrode current collector, wherein the first negative electrode active material layer comprises a first carbon containing active material, a first silicon containing active material, and a first binder; and a second negative electrode active material layer present on the first negative electrode active material layer, wherein the second negative electrode active material layer comprises a second carbon containing active material, a second silicon-containing active material, and a second binder, wherein the first binder comprises styrene-butadiene rubber, and the second binder comprises a copolymer comprising an acrylamide-derived unit, an acrylic acid-derived unit, and an acrylonitrile-derived unit.

2 . The negative electrode of claim 1 , wherein a ratio of a weight percentage of the first binder to a weight of the first negative electrode active material layer is 0.5:1 to 9:1, and a weight percentage of the second binder to a weight of the second negative electrode active material layer is 0.5:1 to 9:1.

3 . The negative electrode of claim 1 , wherein the first binder is present in the first negative electrode active material layer in an amount of 0.5% to 15% by weight.

4 . The negative electrode of claim 1 , wherein the second binder is present in the second negative electrode active material layer in an amount of 0.5% to 15% by weight.

5 . The negative electrode of claim 1 , wherein a total weight of the first binder and the second binder is 0.5% to 15% by weight based on a total weight of the first negative electrode active material layer and the second negative electrode active material layer.

6 . The negative electrode of claim 1 , wherein the second binder comprises a copolymer comprising 55% to 80% by weight of the acrylamide-derived unit, 10% to 30% by weight of the acrylic acid-derived unit, and 5% to 20% by weight of the acrylonitrile-derived unit.

7 . The negative electrode of claim 1 , wherein a thickness ratio of a thickness of the first negative electrode active material layer to a thickness of the second negative electrode active material layer is 1:0.5 to 1:2.

8 . The negative electrode of claim 1 , wherein the first carbon-containing active material and the first silicon containing active material are present in the first negative electrode active material layer in an amount of 90% to 99% by weight, and
a weight ratio of the first carbon-containing active material and the first silicon-containing active material is 83:17 to 99:1.

9 . The negative electrode of claim 1 , wherein the second carbon-containing active material and the second silicon-containing active material are present in the second negative electrode active material layer in an amount of 90% to 99% by weight, and
a weight ratio of the second carbon-containing active material and the second silicon-containing active material is 83:17 to 99:1.

10 . The negative electrode of claim 1 , wherein the first silicon-containing active material comprises a first silicon-containing compound represented by a chemical formula of SiO x , where 0≤x<2 and a first metal doped in the first silicon-containing compound, and
wherein the first metal comprises at least one metal selected from the group consisting of Li, Mg, Ca, and Al.

11 . The negative electrode of claim 1 , wherein the second silicon-containing active material comprises a second silicon-containing compound represented by a chemical formula of SiO y , where 0≤y<2 and a second metal doped in the second silicon-containing compound, and
wherein the second metal comprises at least one metal selected from the group consisting of Li, Mg, Ca, and Al.

12 . The negative electrode of claim 1 , wherein a sum of a loading amount of the first negative electrode active material layer and a loading amount of the second negative electrode active material layer is 4 mAh/cm 2 to 8 mAh/cm 2 .

13 . The negative electrode of claim 1 , wherein a ratio of a loading amount of first negative electrode active material layer and a loading amount of second negative electrode active material layer is 1:0.5 to 1:2.

14 . A secondary battery comprising:
the negative electrode of claim 1 ; a positive electrode facing the negative electrode; a separator interposed between the negative electrode and the positive electrode; and an electrolyte injected in the secondary battery.

15 . The secondary battery of claim 14 , wherein the positive electrode comprises:
a positive electrode current collector; and a positive electrode active material layer present on the positive electrode current collector, wherein the positive electrode active material layer comprises a positive electrode active material comprising a lithium-cobalt-containing oxide.

Assignees

• Lg Energy Solution Ltd

Inventors

• Kim Ye Lin
• Jo Mi Ru
• Park Sung Bin
• Jeong Seung Hwan

Classifications

• H01M4/366

  as layered products · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/48

  of inorganic oxides or hydroxides · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title