Electrode for hypochlorite evolution

Patent metadata

Field	Value
Publication number	US-2024409444-A1
Application number	US-202218697637-A
Country	US
Kind code	A1
Filing date	Oct 26, 2022
Priority date	Oct 27, 2021
Publication date	Dec 12, 2024
Grant date	—

Abstract

An electrode for hypochlorite evolution comprising a conductive substrate and a catalytic coating applied over the substrate and a multilayer method for producing the same.

First claim

1 . A method for producing an electrode for hypochlorite evolution comprising at least two sequential stages (I) and (II):
(I) executing the following steps a)-b) at least once over a valve metal substrate:
a) apply a first active coating comprising at least one layer of a first composition, where said first composition comprises precursors of Ta and Ir having the following weight ratio referred to the elements: 20-70% Ta, 30-80% Ir, and where each layer is dried for 5-15 minutes at 45-75° C. and subsequently baked for 5-15 minutes at 480-530° C.;
b) apply a second active coating comprising at least one layer of a second composition over said first active coating, where said second composition comprises precursors of Ru and Ti having the following weight ratio referred to the elements: 20-50% Ru, 50-80% Ti, and where each layer is dried for 5-15 minutes at 45-75° C. and subsequently baked for 5-15 minutes at 480-530° C.;
(II) executing step a) over the electrode resulting from stage (I), and optionally performing a postbake at 480-530° C. for 1-6 hours.

2 . The method according to claim 1 wherein the first active coating composition further comprises a precursor solution of Rh, and where the precursors of Ta, Ir and Rh have the following weight ratio referred to the elements: 20-45% Ta, 30-70% Ir, 10-25% Rh.

3 . The method according to claim 1 wherein the precursors of Ta and Ir in the first active coating composition have the following weight ratio referred to the elements: 20-45% Ta, 55-80% Ir.

4 . The method according to claim 1 wherein the first active coating is applied in 1-4 layers and the second active coating is applied in 2-10 layers.

5 . The method according to claim 1 wherein the second active composition further comprises a precursor solution of one or more doping agents X chosen from the following list: scandium, strontium, hafnium, bismuth, zirconium, aluminum, and combinations thereof, and X is between 0.5-5% 0.5-5% expressed in weight percentage referred to the elements.

6 . The method according to claim 1 wherein the second active composition further comprises a precursor solution of one or more doping agents Y chosen from the following list: copper, platinum and combinations thereof, and Y is between 0.3-3.2% expressed in weight percentage referred to the elements.

7 . The method according to claim 1 where in stage (I) steps a)-b) are consecutively executed 1-6 times before stage (II).

8 . The method according to claim 2 wherein stage (I) and (II) are performed until reaching a total load of group 9 noble metal elements of 2-6 g/m 2 .

9 . The electrode obtainable with the method according to claim 1 .

10 . An electrode for hypochlorite evolution comprising a valve metal substrate, preferably made of Ti or alloys thereof, and an active coating applied over said substrate characterized in that said coating has an average thickness “T” between 10-30 microns and comprises metal oxides of Ti, Ta, Ir, Ru and optionally Rh according to the following relative weight percentages referred to the elements: 4-35% Ir, 1.5-22.5% Ta, 10-45.5% Ru, 25-75% Ti, and optionally 0.5-12.5% Rh and the relative weight percentage of Ta, Ir, Ru and optionally Rh varies with the coating thickness so that:
Ir, Ta, and Rh, if present, exhibit a peak in weight percentage centered at 2-25% of the coating thickness T, starting from the substrate, with a full width at half maximum (FWHM) of 1-10% of T;
Ru increases in weight percentage until reaching 10-40% of the coating thickness T, where it substantially stabilizes;

said weight percentage being measured by performing on the sample an average of standardless semiquantitative EDAX-SEM line scans, where each line scan is performed over at least 100 acquisition points along the thickness T of the catalytic coating, with a ZAF correction.

11 . A bipolar electrolyser comprising the electrode according to claim 9 and an electrolyte.

12 . The bipolar electrolyser according to claim 11 wherein the electrolyte substantially consists of tap water.

13 . A hypochlorite mediated water disinfection method using the bipolar electrolyser according to claim 11 for hypochlorite mediated water disinfection.

Assignees

• Industrie De Nora Spa

Inventors

• Ramunni Anna
• Kato Akihiro
• Cazzaniga Cristina

Classifications

• C02F2303/04

  Disinfection · CPC title

• C02F2001/46142

  Catalytic coating · CPC title

• C02F2001/46128

  Bipolar electrodes · CPC title

• C02F1/4674 Primary

  with halogen or compound of halogens, e.g. chlorine, bromine · CPC title

• C02F2201/46105

  Details relating to the electrolytic devices · CPC title