Manganese oxide, manganese oxide particles, near-infrared transmission material, and near-infrared transmission film

Patent metadata

Field	Value
Publication number	US-2024400406-A1
Application number	US-202218687712-A
Country	US
Kind code	A1
Filing date	Sep 7, 2022
Priority date	Sep 13, 2021
Publication date	Dec 5, 2024
Grant date	—

Abstract

Provided is a manganese oxide represented by A-Mn—O as constituent elements, in which the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I.

First claim

1 - 38 . (canceled)

39 . A manganese oxide represented by A-Mn—O as constituent elements, wherein the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I, and a reflectance of light at a wavelength of 550 nm and a reflectance of light at a wavelength of 700 nm of the manganese oxide are 20% or less.

40 . The manganese oxide according to claim 39 , wherein the manganese oxide represented by A-Mn—O as constituent elements, the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I, and the manganese oxide is used for a near-infrared transmission material.

41 . The manganese oxide according to claim 39 , wherein a compositional formula of the manganese oxide is represented by AxMnyOz, and x/y=0.001 or more and 2.00 or less.

42 . The manganese oxide according to claim 39 , wherein the constituent element A contains Li.

43 . The manganese oxide according to claim 39 , wherein the constituent element A contains Li, a compositional formula of the manganese oxide is represented by AxMnyOz, and x/y=0.001 or more and 2.00 or less.

44 . The manganese oxide according to claim 39 , wherein the constituent element A contains Li and one or more elements selected from Mg, Ca, Al, Ti, Fe, Zn, Bi, and Y.

45 . The manganese oxide according to claim 39 , wherein the constituent element A contains Li and Mg and/or Al.

46 . The manganese oxide according to claim 39 , wherein the constituent element A contains Y.

47 . The manganese oxide according to claim 39 , wherein the constituent element A contains Y, a compositional formula of the manganese oxide is represented by AxMnyOz, and x/y=0.001 or more and 2.00 or less.

48 . The manganese oxide according to claim 39 , wherein the constituent element A contains Y, and an intensity ratio (211)/(112) of a peak intensity derived from a (211) plane appearing at 2θ=35.5 to 36.5° to a peak intensity derived from a (112) plane appearing at 2θ=32.5 to 33.5° in an XRD spectrum of the manganese oxide is 2.50 or less.

49 . The manganese oxide according to claim 39 , wherein the constituent element A contains Y and one or more elements selected from Li, Ca, Al, Ti, Fe, Zn, and Bi.

50 . The manganese oxide according to claim 39 , wherein the constituent element A contains Y and Zn.

51 . A manganese oxide particle represented by A-Mn—O as constituent elements, wherein the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I, and a reflectance of light at a wavelength of 550 nm and a reflectance of light at a wavelength of 700 nm of the manganese oxide particle are 20% or less.

52 . The manganese oxide particle according to claim 51 , wherein the manganese oxide particle represented by A-Mn—O as constituent elements, the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I, and the manganese oxide particle has an L* of 45 or less as measured by CIE1976.

53 . The manganese oxide particle according to claim 51 , wherein the manganese oxide particle represented by A-Mn—O as constituent elements, the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I, and the manganese oxide particle is used for a near-infrared transmission material.

54 . The manganese oxide particle according to claim 51 , wherein an average value of a secondary particle diameter of the manganese oxide particle by SEM observation is 10 nm or more and 20 μm or less.

55 . A near-infrared transmission material comprising manganese oxide particles and a dispersion containing a component that transmits near-infrared rays, wherein the manganese oxide is represented by A-Mn—O as constituent elements, and the constituent element A is one or more elements selected from H, an alkali metal, an alkaline-earth metal, a rare earth element, Be, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Ru, Co, Os, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, Sb, Bi, S, Se, Te, F, Cl, Br, and I.

56 . A near-infrared transmission film comprising the near-infrared transmission material according to claim 55 .

57 . A near-infrared sensor comprising an optical filter on which the near-infrared transmission film according to claim 56 is formed.

58 . A method for producing a near-infrared transmission film, comprising a step of coating the near-infrared transmission material according to claim 55 onto a base material and drying the coated near-infrared transmission material to form a near-infrared transmission film.

Assignees

• Mitsui Mining & Smelting Co Ltd

Inventors

• Yoneda Yoshihiro
• Tanaka Akinobu

Classifications

• C01G45/1264

  containing rare earths, e.g. (La1-xCax)MnO3 or LaMnO3 · CPC title

• C01G45/1221 Primary

  Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof · CPC title

• C01G45/125

  of the type (MnO3)n-, e.g. CaMnO3 · CPC title

• C01P2006/64

  b* (yellow-blue axis) · CPC title

• C01P2006/63

  a* (red-green axis) · CPC title