Polyimide-based binder for power storage device, electrode mixture paste, negative electrode active material layer, negative electrode sheet for power storage device, and power storage device
US-12176543-B2 · Dec 24, 2024 · US
US2024387808A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2024387808-A1 |
| Application number | US-202418630533-A |
| Country | US |
| Kind code | A1 |
| Filing date | Apr 9, 2024 |
| Priority date | May 16, 2023 |
| Publication date | Nov 21, 2024 |
| Grant date | — |
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The present disclosure provides a method for manufacturing a silicon clathrate positive electrode active material capable of removing at least a portion of a type I silicon clathrate, and a method for manufacturing a lithium-ion battery comprising manufacturing such a silicon clathrate electrode active material. Disclosed methods of making silicon clathrate electrode active material, comprising the following steps: (a) providing silicon clathrate particle that contain a type I silicon clathrate and a type II silicon clathrate, and (b) contacting the silicon clathrate particle with a hydrofluoric solution to remove at least a portion of the type I silicon clathrate.
Opening claim text (preview).
1 . A method for manufacturing a silicon clathrate electrode active material, comprising the following steps: (a) providing a silicon clathrate particle containing a type I silicon clathrate and a type II silicon clathrate, and (b) contacting the silicon clathrate particle with a hydrogen fluoride solution to remove at least a portion of the type I silicon clathrate. 2 . The method according to claim 1 , wherein in the step (b), the ratio of the amount of substance of the hydrogen fluoride solution to the mass of the silicon clathrate particle is greater than 0.0060 mol/g and less than 0.2500 mol/g. 3 . The method according to claim 1 , wherein the solvent of the hydrogen fluoride solution is a mixed solvent of water and an organic solvent. 4 . The method according to claim 1 , wherein in the mixed solvent, the ratio of the mass of the water to a total mass of the water and the organic solvent is 30% by mass or greater and 90% by mass or less. 5 . The method according to claim 1 , wherein the silicon clathrate electrode active material is for a negative electrode active material of lithium-ion batteries. 6 . A method for manufacturing a lithium-ion battery, comprising the following steps: manufacturing a silicone clathrate electrode active material by the method according to claim 1 , and forming an electrode active material layer containing the silicon clathrate electrode active material.
Construction or manufacture · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
Silicon or alloys based on silicon · CPC title
Preparation (chemical coating from the vapour phase C23C16/00) · CPC title
Electrodes based on metals, Si or alloys · CPC title
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