Ultra-high temperature resistant cement slurry system for cementing and preparation method and use thereof

Patent metadata

Field	Value
Publication number	US-2024336828-A1
Application number	US-202218575671-A
Country	US
Kind code	A1
Filing date	Dec 2, 2022
Priority date	Jun 22, 2022
Publication date	Oct 10, 2024
Grant date	—

Abstract

The present disclosure provides an ultra-high temperature resistant cement slurry system for cementing and the preparation method and use thereof. The cement slurry system comprises cement, an ultra-high temperature strength stabilizer, an ultra-high temperature reinforcing material, a density regulator, an ultra-high temperature suspension stabilizer, a dispersant, a fluid loss additive, a retarder, a defoaming agent and water, wherein the ultra-high temperature suspension stabilizer comprises an ether-based starch, an aluminosilicate and a polyalcohol polymer. The method for preparing the cement slurry system includes dry mixing and wet mixing raw materials homogeneously, respectively, and then homogeneously mixing the dry mix and wet mix to obtain the cement slurry system. The present disclosure further provides use of the cement slurry system for cementing in deep wells and ultra-deep wells at high and ultra-high temperatures. The ultra-high temperature resistant cement slurry system for cementing provided by the present disclosure has a strong temperature resistance, a wide applicable range, and an excellent settlement stability. It can prevent the decline of strength of cement stone at high temperature, ensure the cementing and sealing effect and improve the cementing quality.

First claim

1 . An ultra-high temperature resistant cement slurry system for cementing, comprising by weight: 100 parts of cement, 15-50 parts of an ultra-high temperature strength stabilizer, 15-50 parts of an ultra-high temperature reinforcing material, 0-140 parts of a density regulator, 1-6 parts of an ultra-high temperature suspension stabilizer, 0-2 parts of a dispersant, 2-9 parts of a fluid loss additive, 0.1-9 parts of a retarder, 0.1-0.5 part of a defoaming agent, and 40-120 parts of water, wherein the ultra-high temperature suspension stabilizer comprises by weight: 1-3 parts of an ether-based starch, 1-3 parts of an aluminosilicate, and 1-2 parts of a polyalcohol polymer.

2 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the ether-based starch comprises one or more of carboxymethyl starch, carboxyethyl starch, carboxypropyl starch, carboxyhexyl starch, sulfoethyl starch, and sulfo-2-hydroxypropyl starch.

3 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the aluminosilicate is a nano-sized aluminosilicate.

4 . The ultra-high temperature resistant cement slurry system for cementing according to claim 3 , wherein the nano-sized aluminosilicate comprises one or more of nano-sized orthoclase, nano-sized zeolite, nano-sized anorthite, and nano-sized halloysite.

5 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the polyalcohol polymer comprises one or more of polyvinyl alcohol, polyethylene glycol, and polyethylene oxide.

6 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the ultra-high temperature reinforcing material comprises one or more of halloysite, mullite and tricalcium phosphate.

7 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein:
the ultra-high temperature strength stabilizer comprises quartz sand; the density regulator comprises refined iron mine powder and/or glass microbead; the dispersant comprises an aldehyde-ketone polycondensate-based dispersant and/or a polystyrene sulfonate-based dispersant; the fluid loss additive comprises an acrylamide polymer-based fluid loss additive; the retarder comprises an acrylamide polymer-based retarder and/or a 2-acrylamide-2-methylpropanesulfonic acid polymer-based retarder; and the defoaming agent comprises one or more of an organic ester, polyoxypropylene glycerol ether and polydimethylsiloxane.

8 . The ultra-high temperature resistant cement slurry system for cementing according to claim 7 , wherein:
the ultra-high temperature strength stabilizer comprises high purity acid-washed quartz sand of 100-1500 mesh and/or high purity quartz sand of 100-1500 mesh; the refined iron mine powder has a density of 5.05-7.20 g/cm 3 ; and the glass microbead has a density of 0.44-0.65 g/cm 3 .

9 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the cement comprises a class G oil well cement.

10 . The ultra-high temperature resistant cement slurry system for cementing according to claim 1 , wherein the cement slurry system has a density of 1.35-2.35 g/cm 3 , an applicable temperature of 30° C.-240° C., and a density variation of not more than 0.04 g/cm 3 in the applicable temperature range.

11 . The ultra-high temperature resistant cement slurry system for cementing according to claim 10 , wherein the cement slurry system has an applicable temperature of 200° C.-240° C., and a density variation of not more than 0.04 g/cm 3 in the applicable temperature range.

12 . A method for preparing the ultra-high temperature resistant cement slurry system for cementing according to claim 1 , comprising the steps of:
(1) homogeneously mixing by weight 100 parts of cement, 15-50 parts of the ultra-high temperature strength stabilizer, 15-50 parts of the ultra-high temperature reinforcing material, 0-140 parts of the density regulator, 1-6 parts of the ultra-high temperature suspension stabilizer, and 0-2 parts of the dispersant, to obtain a dry mix; (2) homogeneously mixing by weight 2-9 parts of the fluid loss additive, 0.1-9 parts of the retarder, 0.1-0.5 part of the defoaming agent and 40-120 parts of water, to obtain a wet mix; and (3) under stirring, uniformly adding the dry mix obtained from step (1) into the wet mix obtained from step (2), and continuing to stir for a period of time, to obtain the ultra-high temperature resistant cement slurry system for cementing.

13 . The method for preparing the ultra-high temperature resistant cement slurry system for cementing according to claim 12 , wherein in step (3), the dry mix obtained from step (1) is uniformly added into the wet mix obtained from step (2) at a rotational speed of 4,000±200 r/min, and then the stirring is continued for 35-50 s at a rotational speed of 12,000±500 r/min, to obtain the ultra-high temperature resistant cement slurry system for cementing.

14 . A method of using the ultra-high temperature resistant cement slurry system for cementing according to claim 1 , comprising the step of applying the slurry system to an deep well, a ultra-deep well, and/or an extra-ultra-deep well at high and/or ultra-high temperatures.

15 . The method according to claim 14 , wherein the high and/or ultra-high temperatures are 200° C.-240° C., the deep well has a depth of 4,500-6,000 m, the ultra-deep well has a depth of 6,000-9,000 m, and the extra-ultra-deep well has a depth of 9,000 m or more.

16 . The ultra-high temperature resistant cement slurry system for cementing according to claim 6 , wherein the ultra-high temperature reinforcing material comprises a mixture of halloysite, mullite and tricalcium phosphate in a weight ratio of (1-2):(1-2):(1-2).

17 . The ultra-high temperature resistant cement slurry system for cementing according to claim 7 , wherein the organic ester comprises tributyl phosphate.

18 . The ultra-high temperature resistant cement slurry system for cementing according to claim 11 , wherein the cement slurry system has an applicable temperature of 220° C.-240° C.

19 . The method according to claim 15 , wherein the high and/or ultra-high temperatures are from 220° C. to 240° C.

Assignees

• China Nat Petroleum Corp
• Cnpc Eng Tech Res & Dev Co Ltd
• Beijing Huamei Inc Cnpc

Inventors

• Jin Jianzhou
• Chen Lili
• Guo Yuchao
• Zhang Hua
• Liu Fuchen
• Ma Yong
• Wang Yao
• Zhang Xiaobing
• Zhang Jiaying
• Liu Zishuai
• Zhang Haizhi
• Xu Pu
• Zheng Youzhi
• Yu Yongjin
• Qu Congfeng
• Qi Fengzhong
• Li Yong
• Xu Ming
• Wang Guifu
• Liu Shuoqiong
• Zhang Chi
• Lyu Bin
• Zhou Chongfeng
• Ding Zhiwei
• Zhang Shunping
• Jiang Jiwei
• Han Qin
• Feng Yusi
• Zhou Chenyang
• Sun Yiliu
• Yan Songbing

Classifications

• C09K8/48

  Density increasing or weighting additives · CPC title

• C09K8/473

  Density reducing additives, e.g. for obtaining foamed cement compositions · CPC title

• C04B28/04

  Portland cements · CPC title

• C04B40/0039

  Premixtures of ingredients · CPC title

• C04B2111/285

  Intumescent materials · CPC title