Sulfide-based composite solid state electrolytes and related methods

Patent metadata

Field	Value
Publication number	US-2024332611-A1
Application number	US-202318128814-A
Country	US
Kind code	A1
Filing date	Mar 30, 2023
Priority date	Mar 30, 2023
Publication date	Oct 3, 2024
Grant date	—

Abstract

Particular embodiments may provide a solid sulfide electrolyte. Specifically, disclosed herein are methods and systems that can include feeding polymer precursors and sulfides to an extruder, kneading the polymer precursors and the sulfide in the extruder to form a sulfide-polymer composite that includes polyurethane and sulfide, and extruding the sulfide-polymer composite to form a solid sulfide electrolyte.

First claim

1 . A method, comprising:
feeding a polyol, an isocyanate, and a sulfide into an extruder; kneading the polyol, the isocyanate, and the sulfide in the extruder to form a sulfide-polymer composite comprising thermoplastic polyurethane and the sulfide; and extruding the sulfide-polymer composite to form a solid electrolyte layer.

2 . The method of claim 1 , wherein the polyol, the isocyanate, and the sulfide are fed into the same zone of the extruder.

3 . The method of claim 1 , wherein the polyol, the isocyanate, and the sulfide are fed into different zones of the extruder.

4 . The method of claim 1 , wherein an amount of solvent fed to the extruder is such that the solvent is less than 5 wt. % the total weight of all components fed into the extruder.

5 . The method of claim 1 , wherein the polyol comprises polybutadiene diol, polyester diol, or combinations thereof.

6 . The method of claim 1 , wherein the polyol has a molecular weight of 500-5000 g/mol.

7 . The method of claim 1 , wherein the isocyanate comprises aliphatic diisocyanate, aromatic diisocyanate, or combinations thereof.

8 . The method of claim 1 , wherein a ratio of polyol to isocyanate fed into the extruder is 0.5-1.5.

9 . The method of claim 1 , wherein the extruder is a heated twin screw extruder and all temperatures along a length of a screw barrel of the heated twin screw extruder are between 80-120° C.

10 . The method of claim 1 , wherein the solid electrolyte layer has a thickness of 15-100 microns.

11 . The method of claim 1 , further comprising extruding the sulfide-polymer composite on a substrate comprising lithium metal.

12 . The method of claim 1 , further comprising feeding a lubricant into the extruder and/or feeding a solvent compatible with the sulfide into the extruder.

13 . A solid electrolyte comprising:
2-10 wt. % a thermoplastic polyurethane; and 90-98 wt. % sulfide.

14 . The electrolyte of claim 13 , wherein the thermoplastic polyurethane comprises:
hard polymer segments comprising an aliphatic or aromatic isocyanate; and soft polymer segments comprising a polyol having a molecular weight of 500-5000 g/mol.

15 . The electrolyte of claim 14 , wherein the aliphatic or aromatic isocyanate comprises aliphatic or aromatic diisocyanate.

16 . The electrolyte of claim 14 , wherein the polyol comprises polybutadiene diol or polyester diol.

17 . The electrolyte of claim 13 , wherein the solid electrolyte is free of solvent.

18 . The electrolyte of claim 13 , further comprising a lubricant.

19 . A battery comprising an anode, a cathode, and the solid electrolyte of claim 13 .

20 . A system comprising:
an extruder configured to extrude a layer on a substrate comprising lithium metal, wherein the layer comprises 2-10 wt. % a thermoplastic polyurethane and 90-98 wt. % sulfide; and a calendar configured to receive the substrate comprising the layer and configured to receive a cathode film, wherein the calendar is configured to bond at least one surface of the cathode film to the layer on the substrate.

Assignees

• Rivian Ip Holdings Llc

Inventors

• Chinnam Parameswara Rao
• Gittleson Forrest Stephen
• Sharafi Asma
• Chen Chen
• Dong Hui
• Rajput Sonika
• Lin Terri Chai
• Kuppan Saravanan
• Rangasamy Ezhiylmurugan

Classifications

• H01M10/0585

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title

• H01M10/0565 Primary

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• C01B17/22 Primary

  Alkali metal sulfides or polysulfides · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/0562

  Solid materials · CPC title