Sustainable steel production with co-generation of hydrogen

Patent metadata

Field	Value
Publication number	US-2024327939-A1
Application number	US-202318295050-A
Country	US
Kind code	A1
Filing date	Apr 3, 2023
Priority date	Apr 3, 2023
Publication date	Oct 3, 2024
Grant date	—

Abstract

Solar energy is concentrated and transferred to a heat transfer fluid, thereby heating the heat transfer fluid. The heat transfer fluid includes solid particles. Heat from the heat transfer fluid is used to melt a metal. While transferring heat to the furnace, at least a portion of the melted metal is oxidized to form steel. Heat is transferred from a first portion of the heat transfer fluid to a working fluid. The working fluid is then flowed through a turbine generator, which generates electrical power in response. A first water stream is electrolyzed using the electrical power generated by the turbine generator to produce a first oxygen stream and a first hydrogen stream. Heat is transferred from a second portion of the heat transfer fluid to a reactor that houses a recycling agent to thermochemically split a second water stream into a second oxygen stream and a second hydrogen stream.

First claim

What is claimed is:

1 . A system comprising:
a particle receiver containing a heat transfer fluid comprising a plurality of solid particles, the particle receiver configured to receive and concentrate solar energy and transfer the concentrated solar energy to the heat transfer fluid to heat the heat transfer fluid; a furnace coupled to the particle receiver, the furnace comprising a housing configured to receive a metal feedstock comprising metal, the housing configured to transfer heat from the heat transfer fluid to the metal feedstock to melt the metal, the housing comprising an inlet port configured to inject an oxidizing stream comprising oxygen into the housing to oxidize at least a portion of the melted metal to form steel; a power generation unit downstream of the furnace, the power generation unit configured to receive a first portion of the heat transfer fluid from the furnace, the power generation unit comprising:
a heat exchanger configured to transfer heat from the first portion of the heat transfer fluid to a working fluid; and
a turbine generator in fluid communication with the heat exchanger, the turbine generator configured to receive the working fluid that has been heated by the heat exchanger, the turbine generator configured to generate electrical power as the working fluid expands through the turbine generator;
an electrolytic cell electrically coupled to the turbine generator, the electrolytic cell configured to receive a first water stream, the electrolytic cell configured to utilize the electrical power generated by the turbine generator to electrolyze the first water stream into a first oxygen stream and a first hydrogen stream; and a reactor downstream of the furnace, the reactor comprising a recycling agent, the reactor configured to receive a second portion of the heat transfer fluid from the furnace, the reactor configured to receive a second water stream, the reactor configured to transfer heat from the second portion of the heat transfer fluid to the recycling agent and the second water stream to thermochemically split the second water stream into a second oxygen stream and a second hydrogen stream.

2 . The system of claim 1 , wherein the plurality of solid particles of the heat transfer fluid are made of a eutectic alloy comprising lead and bismuth, and the particle receiver is configured to transfer the concentrated solar energy to the heat transfer fluid to heat the heat transfer fluid to about 1,500 degrees Celsius (° C.).

3 . The system of claim 2 , wherein a mass ratio of the first portion of the heat transfer fluid to the second portion of the heat transfer fluid is about 3:1.

4 . The system of claim 3 , wherein the electrolytic cell is configured to receive the first portion of the heat transfer fluid from the heat exchanger, and the electrolytic cell is configured to transfer heat from the first portion of the heat transfer fluid to the first water stream to maintain an electrolysis operating temperature in the electrolytic cell in a range of from about 70° C. to about 850° C.

5 . The system of claim 4 , wherein the reactor is configured to transfer heat from the second portion of the heat transfer fluid to the recycling agent and the second water stream to maintain a thermochemical water splitting operating temperature in the reactor in a range of from about 250° C. to about 1,400° C.

6 . The system of claim 5 , comprising a direct reduced iron production unit configured to receive as a hydrogen source the first hydrogen stream from the electrolytic cell, the second hydrogen stream from the reactor, or both, the direct reduced iron production unit configured to contact iron ore with the hydrogen source to reduce the iron ore into iron.

7 . The system of claim 6 , wherein at least a portion of the metal feedstock is sourced from the iron produced by the direct reduced iron production unit.

8 . The system of claim 7 , wherein at least a portion of the oxidizing stream is sourced from the first oxygen stream from the electrolytic cell, the second oxygen stream from the reactor, or both.

9 . The system of claim 8 , wherein the furnace comprises a plurality of electrodes configured to generate an electric arc between the plurality of electrodes and the metal feedstock within the housing to melt the metal feedstock when sufficient solar energy is unavailable for heating the heat transfer fluid to about 1,500° C.

10 . A method comprising:
concentrating and transferring solar energy to a heat transfer fluid, thereby heating the heat transfer fluid, wherein the heat transfer fluid comprises a plurality of solid particles; after transferring solar energy to the heat transfer fluid, transferring heat from the heat transfer fluid to a furnace that houses metal to melt the metal; while transferring heat to the furnace, injecting an oxidizing stream comprising oxygen into the furnace to oxidize at least a portion of the melted metal to form steel; after transferring heat to the furnace, transferring heat from a first portion of the heat transfer fluid to a working fluid; after transferring heat to the working fluid, flowing the working fluid through a turbine generator; generating, by the turbine generator, electrical power in response to the working fluid flowing through the turbine generator; electrolyzing a first water stream using the electrical power generated by the turbine generator to produce a first oxygen stream and a first hydrogen stream; and after transferring heat to the furnace, transferring heat from a second portion of the heat transfer fluid to a reactor that houses a recycling agent to thermochemically split a second water stream into a second oxygen stream and a second hydrogen stream.

11 . The method of claim 10 , wherein the plurality of solid particles of the heat transfer fluid are made of a eutectic alloy comprising lead and bismuth, and transferring heat to the heat transfer fluid comprises heating the heat transfer fluid to about 1,500 degrees Celsius (° C.).

12 . The method of claim 11 , comprising, after transferring heat to the furnace, dividing the heat transfer fluid into the first portion of the heat transfer fluid and the second portion of the heat transfer fluid, wherein a mass ratio of the first portion of the heat transfer fluid to the second portion of the heat transfer fluid is about 3:1.

13 . The method of claim 12 , wherein the first water stream is electrolyzed by an electrolytic cell, and the method comprises, after transferring heat to the working fluid, transferring heat from the first portion of the heat transfer fluid to the electrolytic cell to maintain an electrolysis operating temperature in the electrolytic cell in a range of from about 70° C. to about 850° C.

14 . The method of claim 13 , wherein transferring heat to the reactor comprises maintaining a thermochemical water splitting operating temperature in the reactor in a range of from about 250° C. to about 1,400° C.

15 . The method of claim 14 , comprising contacting an iron ore with the first hydrogen stream from the electrolytic cell, the second hydrogen stream from the reactor, or both to reduce the iron ore into iron.

16 . The method of claim 15 , wherein at least a portion of the metal housed in the furnace is sourced from the iron produced by reduction of the iron ore.

17 . The method of claim 16 , wherein at least a portion of the oxidizing stream is sourced from the first oxygen stream from the electrolytic cell, the second oxygen stream from the reactor, or both.

18 . The method

Assignees

• Saudi Arabian Oil Co

Inventors

• Almutairi Faisal B
• Al-Ugla Ali Abdulaziz

Classifications

• F24S20/30

  Solar heat collectors for heating objects, e.g. solar cookers or solar furnaces · CPC title

• F24S20/20

  Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants · CPC title

• F01K23/064

  in combination with an industrial process, e.g. chemical, metallurgical · CPC title

• F01K17/02

  for heating purposes, e.g. industrial, domestic (F01K17/06 takes precedence; domestic- or space-heating systems, e.g. central-heating systems, in general F24D1/00, F24D3/00, F24D9/00) · CPC title

• C21C7/00 Primary

  Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 (treating molten metals during moulding B22D1/00, B22D27/00) · CPC title