Method of preparing dry electrode, system for preparing dry electrode, and lithium battery including dry electrode prepared through the method

Patent metadata

Field	Value
Publication number	US-2024322107-A1
Application number	US-202418607179-A
Country	US
Kind code	A1
Filing date	Mar 15, 2024
Priority date	Mar 26, 2023
Publication date	Sep 26, 2024
Grant date	—

Abstract

Provided are a method of preparing a dry electrode, a system for preparing a dry electrode, and a lithium battery including a dry electrode prepared according to the method, wherein the method includes preparing a cut electrode current collector, applying a dry mixture onto the cut electrode current collect to prepare a first dry electrode plate, and rolling the first dry electrode plate to prepare a dry electrode, wherein the applying of the dry mixture is performed by using a cartridge including a drum having a surface on which a plurality of protrusions are provided.

First claim

What is claimed is:

1 . A method of preparing a dry electrode, the method comprising:
preparing a cut electrode current collector; applying a dry mixture onto at least a portion of the cut electrode current collect to prepare a first dry electrode plate; and rolling the first dry electrode plate to prepare a dry electrode, wherein the applying of the dry mixture is performed by using a cartridge comprising a drum having a surface on which a plurality of protrusions are provided.

2 . The method as claimed in claim 1 , wherein a width W of the cut electrode current collector is in a range of about 100 mm to about 500 mm, and
a length L of the cut electrode current collector is in a range of about 200 mm to about 600 mm.

3 . The method as claimed in claim 1 , wherein the cut electrode current collector has a form selected from a sheet, foil, a film, a plate, a porous body, a mesoporous body, a through-hole-containing body, a polygonal ring body, a mesh body, a foam body, a woven body, and a nonwoven body.

4 . The method as claimed in claim 1 , wherein the cut electrode current collector comprises a base film and a metal layer on one surface or two surfaces of the base film,
wherein the base film comprises a polymer, the polymer comprising polyethylene terephthalate (PET), polyethylene (PE), polypropylene (PP), polybutylene terephthalate (PBT), polyimide (PI), or a combination thereof, and the metal layer comprises indium (In), copper (Cu), magnesium (Mg), titanium (Ti), iron (Fe), cobalt (Co), nickel (Ni), zinc (Zn), aluminum (Al), germanium (Ge), lithium (Li), and/or an alloy thereof.

5 . The method as claimed in claim 1 , wherein the preparing of the cut electrode current collector comprises preparing an electrode current collector sheet; providing an interlayer on the electrode current collector sheet; and cutting the electrode current collector sheet on which the interlayer is formed.

6 . The method as claimed in claim 5 , wherein the interlayer comprises a binder.

7 . The method as claimed in claim 5 , wherein the interlayer comprises a carbon-based conductive material.

8 . The method as claimed in claim 1 , wherein the preparing of the first dry electrode plate comprises: preparing the dry mixture; and applying the dry mixture onto at least the portion of the cut electrode current collector by using the cartridge.

9 . The method as claimed in claim 8 , wherein the preparing of the dry mixture comprises mixing together a dry electrode active material and a dry binder to prepare the dry mixture.

10 . The method as claimed in claim 9 , wherein the dry binder comprises a fluorine-based binder, a glass transition temperature (T g ) of the dry binder is in a range of about 15° C. to about 100° C., and a content of the dry binder is in a range of about 0.1 wt % to about 5 wt % with respect to a total weight of the dry mixture.

11 . The method as claimed in claim 9 , wherein the dry mixture further comprises a dry conductive material,
the dry conductive material comprises a carbon-based conductive material, the carbon-based conductive material comprises a fibrous carbon-based material having an aspect ratio of 10 or more, a particulate carbon-based material having an aspect ratio of 5 or less, or a combination thereof, and a content of the dry conductive material is in a range of about 0.1 wt % to about 5 wt % with respect to a total weight of the dry mixture.

12 . The method as claimed in claim 1 , wherein a height h of each of the protrusions on the surface of the drum is in a range of about 0.1 mm to about 20 mm, and
a width w between the adjacent protrusions is in a range of about 0.01 mm to about 0.1 mm.

13 . The method as claimed in claim 1 , wherein the preparing of the first dry electrode plate comprises applying the dry mixture having an average particle diameter of about 0.05 mm to about 1.0 mm onto the cut electrode current collector by using the cartridge.

14 . The method as claimed in claim 1 , wherein the preparing of the dry electrode comprises: inserting the first dry electrode plate between calender rolls; and rolling the first dry electrode plate by using the calender rolls to prepare the dry electrode.

15 . The method as claimed in claim 14 , wherein the calender rolls roll the first dry electrode plate at a temperature of about 150° C. to about 300° C. and a pressure of about 800 kgf/cm 2 to about 3,500 kgf/cm 2 .

16 . The method as claimed in claim 14 , wherein the preparing of the dry electrode comprises rolling the first dry electrode plate by using the calender rolls to form a fibrillized dry electrode film on the cut electrode current collector in a machine direction (MD).

17 . A dry electrode prepared according to the method of preparing the dry electrode as claimed in claim 1 .

18 . A system for preparing a dry electrode, the system comprising:
a cutting portion for preparing a cut electrode current collector; an applicator for preparing a first dry electrode plate by applying a dry mixture onto the cut electrode current collector; and a rolling portion for preparing a dry electrode by rolling the first dry electrode plate, wherein the applicator comprises a cartridge comprising a drum having a surface on which protrusions are provided.

19 . A lithium battery comprising:
a cathode; an anode; and an electrolyte between the cathode and the anode, wherein at least one selected from the cathode and the anode is the dry electrode as claimed in claim 17 .

20 . The lithium battery as claimed in claim 19 , wherein the electrolyte

Assignees

• Samsung Sdi Co Ltd

Inventors

• Kwon Ilkyong
• Lee Jinhyon
• Kwon Seunguk
• Kim Seongdae
• Nam Junghyun

Classifications

• H01M4/667

  in the form of layers, e.g. coatings · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/623

  fluorinated polymers · CPC title