Method of recovering active metal of lithium secondary battery

Patent metadata

Field	Value
Publication number	US-2024318280-A1
Application number	US-202418615001-A
Country	US
Kind code	A1
Filing date	Mar 25, 2024
Priority date	Mar 24, 2023
Publication date	Sep 26, 2024
Grant date	—

Abstract

In a method of recovering an active metal of a lithium secondary battery, an acidic leaching liquid is added to a material to be recovered which contains a lithium metal oxide to form a mixture including a first active metal solution and a leached residue. The formed mixture is subjected to solid-liquid separation for separating the first active metal solution from the leached residue to form a second active metal solution. A lithium hydroxide aqueous solution containing an iron salt is added to the second active metal solution to form a third active metal solution from which impurities are removed or reduced. A lithium precursor is recovered from the third active metal solution.

First claim

What is claimed is:

1 . A method of recovering an active metal of a lithium secondary battery, comprising:
adding an acidic leaching liquid to a material to be recovered which contains a lithium metal oxide to form a mixture including a first active metal solution and a leached residue; subjecting the formed mixture to solid-liquid separation for separating the first active metal solution from the leached residue to form a second active metal solution; adding a lithium hydroxide aqueous solution containing an iron salt to the second active metal solution to form a third active metal solution from which impurities are removed or reduced; and recovering a lithium precursor from the third active metal solution.

2 . The method of claim 1 , further comprising:
washing the leached residue to generate a washing liquid; and supplying the washing liquid to the mixture or the second active metal solution.

3 . The method of claim 2 , wherein the washing is repeatedly performed in a plurality of cycles,
the washing liquid generated from earlier cycles of the plurality of cycles is supplied to the second active metal solution, and the washing liquid generated from later cycles of the plurality of cycles is supplied to the mixture.

4 . The method according to claim 1 , wherein the lithium metal oxide includes a lithium iron phosphate-based active material, and
the first active metal solution includes lithium sulfate, lithium chloride or lithium nitrate, and the leached residue includes an iron phosphate-based material.

5 . The method of claim 1 , wherein the material to be recovered is obtained by pulverizing a waste lithium secondary battery.

6 . The method of claim 1 , wherein the impurities contain iron (Fe), phosphorus (P) and aluminum (Al).

7 . The method of claim 1 , wherein the iron salt includes iron sulfate, iron chloride or iron nitrate, and a residual phosphorus is precipitated from the second active metal solution in the form of iron phosphate.

8 . The method of claim 1 , wherein the lithium hydroxide aqueous solution does not contain a salt of an alkali metal other than lithium or an alkaline earth metal.

9 . The method of claim 1 , wherein recovering the lithium precursor comprises converting lithium sulfate, lithium chloride or lithium nitrate into lithium hydroxide by an electrodialysis.

10 . The method of claim 9 , further comprising recycling a portion of lithium hydroxide generated by the electrodialysis to the formation of the third active metal solution.

11 . The method of claim 9 , wherein the acidic leaching liquid includes sulfuric acid, hydrochloric acid or nitric acid, and
the method further comprises recycling sulfuric acid, hydrochloric acid or nitric acid produced by the electrodialysis to the formation of the mixture.

12 . The method of claim 1 , wherein the acidic leaching liquid includes at least one oxidizing agent selected from the group consisting of hydrogen peroxide, oxygen, ozone and lithium persulfate.

13 . The method of claim 1 , wherein the lithium hydroxide aqueous solution is added in an amount from 0.1 wt % to 0.5 wt % based on a total weight of the second active metal solution.

Assignees

• Sk Innovation Co Ltd

Inventors

• Yoo Su Min
• Lee Hyeon Hui
• Park Se Eun

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• C01D15/02 Primary

  Oxides; Hydroxides · CPC title

• B09B2101/16

  Batteries · CPC title

• C25B1/16

  Hydroxides (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title