Electrode

Patent metadata

Field	Value
Publication number	US-2024304817-A1
Application number	US-202218274706-A
Country	US
Kind code	A1
Filing date	Jan 28, 2022
Priority date	Jan 29, 2021
Publication date	Sep 12, 2024
Grant date	—

Abstract

The present application relates to an electrode comprising a current collector and an active material layer, which can provide an electrode capable of ensuring adhesion force between particles, and adhesion force between the active material layer and the current collector in high levels compared with a binder content in the active material layer. The present application can also provide a use of the electrode.

First claim

1 . An electrode, comprising:
a current collector; and an active material layer on one or both sides of the current collector, wherein the active material layer comprises an electrode active material and a particulate binder, wherein the electrode comprises a network region and a blank region observed on a surface of the current collector after a standard peel test, wherein the network region is a region comprising the particulate binder, and having a height of 3 times or more an average particle diameter of the particulate binder, wherein the blank region is a region that does not comprise the particulate binder or a region comprising the particulate binder, and having a height of 1.5 times or less the average particle diameter of the particulate binder, wherein a ratio of an area occupied by the particulate binder on the blank region is 20% or less, and wherein the standard peel test is a process of attaching a tape on the active material layer and then peeled off the tape from the active material layer, which is repeated until no component from the active material layer is observed on the tape.

2 . The electrode according to claim 1 , wherein a ratio of an area occupied by the blank region on the surface of the current collector is 50% or more.

3 . The electrode according to claim 1 , wherein a content ratio (O/N) of oxygen to nitrogen on the surface of the current collector is 60 or less.

4 . The electrode according to claim 1 , wherein the surface of the current collector has a water contact angle of 15 degrees or less.

5 . The electrode according to claim 1 , wherein the binder comprises one or more selected from the group consisting of PVDF (poly(vinylidene fluoride)), PVA (poly(vinyl alcohol)), polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, an ethylene-propylene-diene terpolymer (EPDM), a sulfonated EPDM, SBR (styrene-butadiene rubber), and fluororubber.

6 . The electrode according to claim 1 , wherein the network region has a height of 1.4 μm or more.

7 . The electrode according to claim 1 , wherein an area occupied by the network region satisfies Equation 1:
A/W≤ 30  [Equation 1]
wherein A is a ratio (unit: %) of an area occupied by the network region relative to the total area of the surface of the current collector and W is a content (weight %) of the binder in the active material layer.

8 . The electrode according to claim 1 , wherein an amount of the binder included in the active material layer is from 0.5 weight % to 10 weight %.

9 . The electrode according to claim 1 , wherein a ratio (D90/D10) of a 90% volume cumulative particle diameter (D90) of the electrode active material to a 10% volume cumulative particle diameter (D10) of the electrode active material is 15 or less.

10 . The electrode according to claim 1 , wherein the electrode active material is a particulate material having an average particle diameter in a range of 1 μm to 100 μm.

11 . The electrode according to claim 1 , wherein a ratio (D1/D2) of an average particle diameter (D1) of the electrode active material to an average particle diameter (D2) of the particulate binder is from 10 to 1,000.

12 . The electrode according to claim 1 , wherein the electrode active material is comprised in an amount of 1000 to 10000 parts by weight relative to 100 parts by weight of the binder.

13 . The electrode according to claim 1 , wherein the active material layer has a thickness in a range of 10 μm to 500 μm.

14 . An electrochemical element, comprising:
the electrode of claim 1 as a negative electrode or a positive electrode.

15 . A secondary battery, comprising:
the electrode of claim 1 as a negative electrode or a positive electrode.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Geun Sung
• Park Jin Woo
• Lee Il Ha
• Song In Taek
• Kim Ki Hwan

Classifications

• H01G11/30

  characterised by their material · CPC title

• H01G11/38

  Carbon pastes or blends; Binders or additives therein · CPC title

• H01G11/28

  arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title

• H01M4/64

  Carriers or collectors · CPC title

• H01M4/621

  Binders · CPC title