Electrochemical impedance spectroscopy current measurement system gain control

Patent metadata

Field	Value
Publication number	US-2024302445-A1
Application number	US-202418595294-A
Country	US
Kind code	A1
Filing date	Mar 4, 2024
Priority date	Mar 6, 2023
Publication date	Sep 12, 2024
Grant date	—

Abstract

A method for selecting one or more gain values in an electrochemical impedance spectroscopy (EIS) current measurement system to provide an improved signal-to-noise characteristic can include selecting a larger one of an electrochemical cell arrangement impedance indication value and a sense resistor arrangement impedance indication value and using the selected impedance indication value as a determined impedance indication value. The method can also include determining, for a plurality of gain setting combinations, an EIS excitation current value at which current measurement circuitry of the current measurement system will reach a specified amount of a non-saturation range of the current measurement system when measuring the determined impedance indication value. The method can also include determining, for the plurality of gain setting combinations, a signal-to-noise characteristic at the determined EIS excitation current based upon a determined noise level in at least one part of the EIS current measurement system.

First claim

What is claimed is:

1 . A method for selecting one or more gain values in an electrochemical impedance spectroscopy (EIS) current measurement system to provide an improved signal-to-noise characteristic, the method comprising:
selecting a larger one of an electrochemical cell arrangement impedance indication value and a sense resistor arrangement impedance indication value and using the selected impedance indication value as a determined impedance indication value; determining, for a plurality of gain setting combinations, an EIS excitation current value at which current measurement circuitry of the current measurement system will reach a specified amount of a non-saturation range of the current measurement system when measuring the determined impedance indication value; and determining, for the plurality of gain setting combinations, a signal-to-noise characteristic at the determined EIS excitation current based upon a determined noise level in at least one part of the EIS current measurement system.

2 . The method of claim 1 , comprising selecting, from the plurality of gain setting combinations, a combination that results in a largest estimated signal-to-noise ratio.

3 . The method of claim 2 , comprising performing an EIS measurement with the one or more gain values corresponding to the selected combination programmed into the EIS current measurement system.

4 . The method of claim 2 , comprising selecting the determined EIS excitation current corresponding to the selected combination.

5 . The method of claim 1 , wherein the electrochemical cell arrangement impedance value is estimated based on a membrane area of an electrolytic cell.

6 . The method of claim 1 , wherein the specified amount of non-saturation range is 80 percent.

7 . The method of claim 1 , wherein the plurality of gain setting combinations include a range of gain values for a pre-gain amplifier of the current measurement circuitry.

8 . The method of claim 1 , comprising determining the EIS excitation current value based on an input voltage value and at least one gain stage, wherein gain values for the at least one gain stage are included in the plurality of gain setting combinations.

9 . The method of claim 1 , wherein the determined noise level in at least one part of the EIS current measurement system includes a determined noise level in an electrolytic power supply.

10 . The method of claim 9 , wherein the determined noise level in at least one part of the EIS current measurement system includes a determined noise level in an EIS current power supply and a noise level in the current measurement circuitry.

11 . The method of claim 1 , comprising generating a look-up-table including the gain setting combination that results in a largest signal-to-noise ratio for each of a plurality of electrochemical cell arrangement impedance indication values.

12 . The method of claim 11 , comprising:
selecting, from the look-up-table, the combination corresponding to a cell arrangement impedance value; and selecting the gain settings corresponding to the selected combination.

13 . The method of claim 1 , wherein the determining an EIS excitation current value at which current measurement circuitry of the EIS current measurement system will reach the specified amount of non-saturation range includes using a DC current in the EIS current measurement system.

14 . The method of claim 1 , wherein the determining the larger one of the electrochemical cell arrangement impedance indication value and the sense resistor arrangement impedance indication value includes measuring the impedance of at least one of the cell arrangement or the sense resistor arrangement using the EIS current measurement system.

15 . The method of claim 1 , comprising:
selecting a gain combination; conducting an EIS current measurement sweep over at least two frequencies; in response to the current measurement circuitry saturating, selecting a gain setting combination with a reduced overall gain for the frequency at which the current measurement circuitry saturated; and re-conducting the EIS current measurement for the frequency at which the current measurement circuitry saturated.

16 . The method of claim 15 , comprising:
in response to the current measurement circuitry saturating, selecting a gain setting combination with a reduced overall gain for the at least two frequencies; and re-conducting the EIS current measurement sweep over the at least two frequencies.

17 . The method of claim 1 , comprising:
selecting a gain combination; conducting an EIS current measurement sweep over at least two frequencies; in response to the current measurement circuitry not saturating, selecting a gain setting combination with an increased overall gain for the frequency at which the current measurement circuitry saturated; and re-conducting the EIS current measurement for the frequency at which the current measurement circuitry saturated.

18 . A method for selecting one or more gain values in an electrochemical impedance spectroscopy (EIS) current measurement system to provide an improved signal-to-noise characteristic, the method comprising:
selecting an excitation current gain such that an excitation current is a specified percentage of a power supply current; selecting a larger one of an electrochemical cell arrangement impedance indication value and a sense resistor arrangement impedance indication value and using the selected impedance indication value as a determined impedance indication value; and selecting a voltage measurement circuitry current gain such that the current measurement system will reach a specified amount of a non-saturation range of the current measurement system when measuring the determined impedance indication value.

19 . The method of claim 18 , comprising performing an EIS measurement with the one or more gain values corresponding to the selected excitation current gain and the selected voltage measurement circuitry current gain programmed into the EIS current measurement system.

20 . The method of claim 18 , comprising:
selecting a gain combination; conducting an EIS current measurement sweep over at least two frequencies; in response to the current measurement system saturating, selecting a gain setting combination with a reduced overall gain for the frequency at which the current measurement circuitry saturated; and re-conducting the EIS current measurement for the frequency at which the current measurement circuitry saturated.

Assignees

• Analog Devices Inc

Inventors

• Harrington Brian
• Seidel Sheila Patricia
• Garber Leah Alexis
• Zheng Sue
• Fischl Kate Danielle
• Yellepeddi Atulya

Classifications

• G01R31/367

  Software therefor, e.g. for battery testing using modelling or look-up tables · CPC title

• G01R31/3842

  combining voltage and current measurements · CPC title

• G01R31/396

  Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery · CPC title

• G01R1/203

  Resistors used for electric measuring, e.g. decade resistors standards, resistors for comparators, series resistors, shunts (resistors in general H01C; microwave or radiowave terminations H01P1/26; coupling devices H01R) · CPC title

• G01R19/0092

  Measuring current only · CPC title