Apparatus for depolymerizing hydrocarbon-based material

Patent metadata

Field	Value
Publication number	US-2024286106-A1
Application number	US-202218573616-A
Country	US
Kind code	A1
Filing date	Jun 23, 2022
Priority date	Jun 23, 2021
Publication date	Aug 29, 2024
Grant date	—

Abstract

An apparatus for depolymerizing a hydrocarbon-based material according to an embodiment of the present disclosure includes a supply unit configured to supply a liquid hydrocarbon, a plasma generation unit configured to generate plasma for supplying thermal energy to the hydrocarbon in the supply unit, a reaction unit provided between the supply unit and the plasma generation unit and configured to convert the liquid hydrocarbon, and a separation unit connected to the reaction unit and configured to separate an unreacted hydrocarbon, a liquid product, and a gaseous product of an aromatic compound that is created by conversion in the reaction unit and introduced.

First claim

1 . An apparatus for depolymerizing a hydrocarbon-based material, the apparatus comprising:
a supply unit configured to supply a liquid hydrocarbon; a plasma generation unit configured to generate plasma for supplying thermal energy to the hydrocarbon in the supply unit; a reaction unit provided between the supply unit and the plasma generation unit and configured to convert the liquid hydrocarbon; and a separation unit connected to the reaction unit and configured to separate an unreacted hydrocarbon, a liquid product, and a gaseous product of an aromatic compound that is created by conversion in the reaction unit and introduced.

2 . The apparatus of claim 1 , wherein:
the plasma generation unit generates arc plasma having a preset temperature range by using hydrogen or a hydrogen-containing gas mixture as a discharge gas.

3 . The apparatus of claim 1 , wherein:
the plasma generation unit comprises a discharge port configured to discharge a plasma jet to the reaction unit and having a small inner diameter, and a high-temperature part connected to the discharge port and having an inner diameter that is larger than the inner diameter of the discharge port and decreases toward the discharge port, and the plasma jet discharged from the discharge port is discharged into the reaction unit.

4 . The apparatus of claim 1 , wherein:
the reaction unit separates and connects the plasma generation unit and the supply unit.

5 . The apparatus of claim 1 , wherein:
the reaction unit includes a downward-inclined surface disposed at a side adjacent to the plasma generation unit and configured to define a space having a narrow upper side directed toward the plasma generation unit, and a wide lower side.

6 . The apparatus of claim 5 , wherein:
the reaction unit further includes an upward-inclined surface disposed at a side adjacent to the supply unit and configured to define a space having a narrow lower side directed toward the supply unit, and a wide upper side.

7 . The apparatus of claim 6 , wherein:
an inner diameter of the supply unit is equal to an inner diameter of a lower end of the upward-inclined surface.

8 . The apparatus of claim 6 , wherein:
the separation unit includes a single chamber or a plurality of chambers connected to the reaction unit and configured to be supplied with the converted hydrocarbon.

9 . The apparatus of claim 8 , wherein:
the chamber comprises: a first discharge port provided at an upper side thereof and configured to discharge the gaseous product; and a second discharge port provided at a lower side thereof and configured to discharge the liquid product.

10 . The apparatus of claim 9 , wherein:
the second discharge port is connected to the supply unit through a circulation line.

11 . The apparatus of claim 1 , wherein:
the aromatic compound created by being converted in the separation unit includes at least one of benzene, toluene, xylene, and an organic solvent having a carbon number of 15 or less.

12 . The apparatus of claim 1 , further comprising:
a catalyst reaction unit connected to the separation unit and configured to create light olefin by additionally converting a liquid product and an unreacted hydrocarbon that are separated by the separation unit and have a small molecular weight.

13 . The apparatus of claim 1 , wherein:
the reaction unit includes a downward-inclined surface disposed at a side adjacent to the plasma generation unit and configured to define a space having a narrow upper side directed toward the plasma generation unit, and a wide lower side, and a lower end directed toward the separation unit is connected to a neck portion having a smaller inner diameter than the reaction unit in order to define a high-temperature reaction space in which a flow temporarily stays.

14 . The apparatus of claim 13 , wherein:
the supply unit comprises at least one injection nozzle provided on the downward-inclined surface and configured to inject a liquid hydrocarbon into the reaction unit.

15 . The apparatus of claim 14 , wherein:
the injection nozzle is provided as a pair of injection nozzles, and injection centerlines of the pair of injection nozzles deviate from a center of a planar cross-section of the reaction unit and are positioned in parallel with each other.

16 . The apparatus of claim 13 , wherein:
the separation unit is connected to the reaction unit through the neck portion, the separation unit has a first discharge port provided at an upper side thereof and configured to discharge the gaseous product, and the separation unit has a second discharge port provided at a lower side thereof and configured to discharge the liquid product.

17 . The apparatus of claim 16 , wherein:
the second discharge port is connected to the supply unit through a circulation line.

18 . The apparatus of claim 13 , wherein:
the separation unit is connected to the reaction unit through the neck portion, and the separation unit has a solvent nozzle provided at one side thereof to inject a solvent toward an inner surface of the separation unit, and a discharge port disposed at a lowermost side and configured to discharge the liquid product.

19 . The apparatus of claim 18 , wherein:
the separation unit further comprises a discharge port provided below the solvent nozzle and configured to discharge the gaseous product, and the discharge port configured to discharge the liquid product is connected to the supply unit through a circulation line.

Assignees

• Korea Inst Mach & Materials

Inventors

• Kim You-Na
• Lee Dae-Hoon
• Song Younghoon
• Kim Kwan-Tae
• Kang Hong Jae
• Lee Heesoo
• Song Hohyun

Classifications

• B01J19/088 Primary

  giving rise to electric discharges (for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00) · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J19/245 Primary

  placed in series · CPC title

• B01J2219/0896

  Cold plasma · CPC title

• B01J2219/0879

  Solid · CPC title