Hot-dip galvanized steel plate and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-2024271257-A1
Application number	US-202218567521-A
Country	US
Kind code	A1
Filing date	Jun 7, 2022
Priority date	Jun 7, 2021
Publication date	Aug 15, 2024
Grant date	—

Abstract

Provided are a manufacturing method for a hot-dip galvanized steel plate, and the hot-dip galvanized steel plate. The method comprises: hot rolling a slab into a steel plate, and pickling and cold rolling after coiling; performing continuous annealing, an annealing temperature being 840-870° C., and an annealing dew point being −10-0° C.; cooling to 710-730° C. at a cooling rate of ≤10° C./s, and then cooling to 220-320° C. at a cooling speed of ≥50° C./s; then heating to 410-460° C. for heat preservation for 20-100 s; and galvanization to obtain the hot-dip galvanized steel plate, the chemical element composition thereof being: C: 0.17-0.21 wt %; Si: 1.2-1.7 wt %; Al: 0.02-0.05%; Mn: 1.60-2.1 wt %; N: ≤0.008 wt %; and the reminder being Fe and impurities. The hot-dip galvanized steel plate of the present invention has a yield strength of 400-600 Mpa, a tensile strength of 730-900 Mpa, an elongation of 25-35%, and a hole expansion ratio of 35-60%.

First claim

1 . A method of manufacturing a hot-dip galvanized steel plate, wherein the method includes the following steps:
S 1 : hot rolling a slab into a steel plate, coiling the steel plate, and then pickling and cold-rolling the steel plate; S 2 : performing continuous annealing at an annealing temperature of 840 to 870° C./s and an annealing dew point of −10 to 0° C./s; cooling at a cooling rate of ≤10° C./s to a starting temperature of rapid cooling of 710 to 730° C./s; cooling at a cooling rate of ≥50° C./s to an end temperature of the rapid cooling of 220 to 320° C./s; heating to a reheating temperature of 410 to 460° C./s; and holding for 20 to 100 s; S 3 : performing galvanization, after which the steel plate is cooled to room temperature to obtain the hot-dip galvanized steel plate; wherein the hot-dip galvanized steel plate consists of the following chemical elements by mass percentage: C: 0.17 to 0.21 wt %; Si: 1.2 to 1.7 wt %; Al: 0.02 to 0.05%; Mn: 1.60 to 2.1 wt %; N: ≤0.008 wt %; and a balance of Fe and unavoidable impurities.

2 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein the hot-dip galvanized steel plate has a microstructure consisting of ferrite, partitioned martensite and metastable austenite; wherein, by volume fraction, the phase proportion of the ferrite is 30 to 50%; the phase proportion of the partitioned martensite is 40 to 60%; and the phase proportion of the metastable austenite is 10 to 20%.

3 . The method of manufacturing a hot-dip galvanized steel plate according to claim 2 , wherein the ferrite has a statistical stored dislocation of 5.0×10 13 /m 2 to 1×10 14 /m 2 ; the ferrite has a hardness of 180 to 230 HV; the partitioned martensite has a hardness of 315 to 380 HV; and a hardness ratio of the partitioned martensite to the ferrite is ≤1.8.

4 . The method of manufacturing a hot-dip galvanized steel plate according to claim 3 , wherein the hot-dip galvanized steel plate has a yield strength of 400 to 600 MPa, a tensile strength of 730 to 900 MPa, an elongation of 25 to 35%, and a hole expansion ratio of 35 to 60%.

5 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein in step S 1 , before the hot rolling, the slab is heated and held at a temperature of 1230 to 1260° C.

6 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein in step S 1 , a finish rolling temperature of the hot rolling is 920±30° C.

7 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein in step S 1 , a temperature for the coiling is 450 to 550° C.; during the cold rolling, a cold-rolling deformation amount is 20 to 60%.

8 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein in step S 2 , the steel plate is cooled at a cooling rate of 2 to 10° C./s to the starting temperature of the rapid cooling of 710 to 730° C.

9 . The method of manufacturing a hot-dip galvanized steel plate according to claim 1 , wherein in step S 2 , the steel plate is cooled at a cooling rate of 50 to 100° C./s from the starting temperature of the rapid cooling to the end temperature of the rapid cooling of 220 to 320° C.

10 . The method of manufacturing a hot-dip galvanized steel plate according to claim 3 , wherein the hardness ratio of the partitioned martensite to the ferrite is 1.4 to 1.8.

11 . A hot-dip galvanized steel plate, wherein the hot-dip galvanized steel plate consists of the following chemical elements by mass percentage: C: 0.17 to 0.21 wt %; Si: 1.2 to 1.7 wt %; Al: 0.02 to 0.05%; Mn: 1.60 to 2.1 wt %; N: ≤0.008 wt %; and a balance of Fe and unavoidable impurities, wherein the hot-dip galvanized steel plate has a microstructure consisting of ferrite, partitioned martensite and metastable austenite; wherein, by volume fraction, the phase proportion of the ferrite is 30 to 50%; the phase proportion of the partitioned martensite is 40 to 60%; and the phase proportion of the metastable austenite is 10 to 20%.

12 . The hot-dip galvanized steel plate according to claim 11 , wherein the ferrite has a statistical stored dislocation of 5.0×10 13 /m 2 to 1×10 14 /m 2 ; the ferrite has a hardness of 180 to 230 HV; the partitioned martensite has a hardness of 315 to 380 HV; and a hardness ratio of the partitioned martensite to the ferrite is ≤1.8.

13 . The hot-dip galvanized steel plate according to claim 11 , wherein the hot-dip galvanized steel plate has a yield strength of 400 to 600 MPa, a tensile strength of 730 to 900 MPa, an elongation of 25 to 35%, and a hole expansion ratio of 35 to 60%.

14 . The hot-dip galvanized steel plate according to claim 12 , wherein the hardness ratio of the partitioned martensite to the ferrite is 1.4 to 1.8.

15 . A hot-dip galvanized steel plate manufactured by the method of manufacturing a hot-dip galvanized steel plate according to claim 1 .

16 . The method of manufacturing a hot-dip galvanized steel plate according to claim 3 , wherein the partitioned martensite has a hardness of 320 to 380 HV.

17 . The method of manufacturing a hot-dip galvanized steel plate according to claim 4 , wherein the hot-dip galvanized steel plate has a tensile strength of 730 to 900 MPa.

18 . The hot-dip galvanized steel plate according to claim 12 , wherein the partitioned martensite has a hardness of 320 to 380 HV.

19 . The hot-dip galvanized steel plate according to claim 13 , wherein the hot-dip galvanized steel plate has a tensile strength of 780 to 900 MPa.

20 . The hot-dip galvanized steel plate according to claim 15 , wherein:
in step S 1 , before the hot rolling, the slab is heated and held at a temperature of 1230 to 1260° C.; in step S 1 , a finish rolling temperature of the hot rolling is 920±30° C.; in step S 1 , a temperature for the coiling is 450 to 550° C.; during the cold rolling, a cold-rolling deformation amount is 20 to 60%; in step S 2 , the steel plate is cooled at a cooling rate of 2 to 10° C./s to the starting temperature of the rapid cooling of 710 to 730° C.; and/or in step S 2 , the steel plate is cooled at a cooling rate of 50 to 100° C./s from the starting temperature of the rapid cooling to the end temperature of the rapid cooling of 220 to 320° C.

Assignees

• Baoshan Iron & Steel

Inventors

• Zhong Yong
• Chen Mengxiao
• Wang Li

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C23C2/06 Primary

  Zinc or cadmium or alloys based thereon · CPC title

• C22C38/06

  containing aluminium · CPC title

• C22C38/02 Primary

  containing silicon · CPC title

• C21D2211/008

  Martensite · CPC title