Reversible System Comprising A Reversible Fuel Cell And A Metal Hydride Storage Device

Patent metadata

Field	Value
Publication number	US-2024243326-A1
Application number	US-202318526521-A
Country	US
Kind code	A1
Filing date	Dec 1, 2023
Priority date	Dec 1, 2022
Publication date	Jul 18, 2024
Grant date	—

Abstract

The invention relates to a system comprising: a fuel cell able to operate in a first and a second operating mode, such that: in the first mode, the fuel cell consumes energy in order to produce hydrogen, and in the second mode, the fuel cell produces energy by consuming hydrogen; a first storage device for storing hydrogen produced by the fuel cell when the fuel cell is in the first mode, the first storage device being able to absorb hydrogen at a first pressure and to release hydrogen at a second pressure, greater than the first pressure; and, a second storage device able to store hydrogen coming from the first storage device, the second storage device being able to absorb hydrogen by forming, with the hydrogen, a second metal hydride when the hydrogen is at the second pressure.

First claim

1 . A system comprising:
a fuel cell configured to operate selectively in a first operating mode and in a second operating mode, such that: in the first operating mode, the fuel cell consumes electrical energy in order to produce hydrogen and oxygen, and in the second operating mode, the fuel cell produces electrical energy while consuming hydrogen and oxygen; a first storage device for storing hydrogen produced by the fuel cell when the fuel cell is in the first operating mode, the first storage device comprising a first material able configured to absorb hydrogen (by forming, with the hydrogen, a first metal hydride when the hydrogen is at a first pressure, and releasing hydrogen by desorption when the hydrogen is at a second pressure, greater than the first pressure, the first metal hydride having a first enthalpy of absorption; a second storage device configured to store hydrogen coming from the first storage device, the second storage device comprising a second material, different from the first material, the second material being configured to absorb hydrogen by forming, with the hydrogen, a second metal hydride when the hydrogen is at the second pressure, the second metal hydride having a second enthalpy of absorption, greater, in absolute value, than the first enthalpy of absorption of the first metal hydride.

2 . The system according to claim 1 , further comprising a first heating device configured to heating the first metal hydride, and to take a pressure of hydrogen stored in the first storage device from the first pressure to the second pressure.

3 . The system according to claim 2 , wherein the first heating device is configured to be supplied with heat by a residual water which has not been consumed by the fuel cell when the fuel cell operates in the first operating mode.

4 . The system according to claim 1 , wherein the second material is configured to produce, during a storage by absorption of hydrogen in the second material, a quantity of heat necessary to vaporise water supplying the fuel cell when the fuel cell operates in the first operating mode.

5 . The system according to claim 1 , further comprising a first heat exchanger configured to transfer the heat produced during the storage by absorption of hydrogen in the second material, to water supplying the fuel cell when the fuel cell operates in the first operating mode.

6 . The system according to claim 5 , wherein the first heat exchanger is configured to transfer heat from water produced by the fuel cell to the second metal hydride causing desorption of the hydrogen stored in the second storage device, in order to supply the fuel cell with the hydrogen when the fuel cell operates in the second operating mode.

7 . The system according to claim 1 , further comprising a second heat exchanger configured to transfer heat from the hydrogen produced by the fuel cell to water supplying the fuel cell, to supply the fuel cell with steam when the fuel cell operates in the first operating mode.

8 . The system according to claim 7 , wherein the second heat exchanger is configured to transfer heat from water produced by the fuel cell to hydrogen coming from the first storage device and/or the second storage device, and to supply the fuel cell with heated hydrogen when the fuel cell operates in the second operating mode.

9 . The system according to claim 1 , further comprising a condenser for separating hydrogen produced by the fuel cell and the residual water which has not been consumed by the fuel cell when the fuel cell operates in the first operating mode.

10 . The system according to claim 1 , wherein the first storage device comprises:
a plurality of storage cells and an inlet/outlet line, each storage cell being configured to be supplied with hydrogen coming from the fuel cell and to be discharged of hydrogen to the second storage device via the inlet/outlet line; and a valve configured to be controlled in order to selectively connect the inlet/outlet line of each storage cell to a line for transporting hydrogen, the line being configured to transport hydrogen between the fuel cell and/or the first storage device and/or the second storage device, independently of the other storage cells.

11 . The system according to claim 1 , further comprising a connection valve configured to selectively connect the second storage device;
to the first storage device, in order to supply the second storage device with hydrogen coming from the first storage device when the fuel cell operates in the first operating mode; or to the fuel cell in order to supply the fuel cell with hydrogen coming from the second storage device when the fuel cell operates in the second operating mode.

12 . The system according to claim 1 , further comprising a second heating device and a regulator configured to control the second heating device in order to keep the fuel cell at a predefined nominal operating temperature between 650° and 850°.

13 . The system according to claim 1 , wherein the first material of the first storage device comprises a compound chosen from lanthanum, titanium, vanadium, nickel or a combination of lanthanum, titanium, vanadium, nickel.

14 . The system according to claim 1 , wherein the second material of the second storage device comprises magnesium.

15 . A method for operating a system according to claim 1 , wherein the fuel cell operates in the first operating mode, the method comprising the steps of:
storing, by absorption, hydrogen produced by the fuel cell at the first pressure in the first storage device; heating the first metal hydride so as to take the hydrogen stored in the first storage device from the first pressure to the second pressure; releasing, by desorption, the hydrogen stored in the first storage device; and storing, by absorption, the hydrogen released from the first storage device in the second storage device at the second pressure, the second storage device storing the hydrogen released at the same speed as the first storage device releases the stored hydrogen.

16 . The method for operating a system according to claim 1 , wherein the fuel cell operates in the second operating mode, the method comprising:
heating the second metal hydride to cause a desorption of hydrogen stored in the second storage device, and supplying the fuel cell with the hydrogen desorbed from the second storage device.

17 . The method according to claim 16 , further comprising:
heating the first metal hydride so as to cause a desorption of hydrogen stored in the first storage device, and supplying the fuel cell with the hydrogen desorbed from the first storage device.

Assignees

• Electricite De France

Inventors

• Leon Aline

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/04298

  Processes for controlling fuel cells or fuel cell systems · CPC title

• H01M8/04097

  with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence) · CPC title

• H01M8/04029

  Heat exchange using liquids · CPC title

• H01M8/04007

  related to heat exchange · CPC title