Metal hydroxide, positive electrode material, electrochemical device, and electrical device

Patent metadata

Field	Value
Publication number	US-2024239690-A1
Application number	US-202418622079-A
Country	US
Kind code	A1
Filing date	Mar 29, 2024
Priority date	Aug 15, 2022
Publication date	Jul 18, 2024
Grant date	—

Abstract

A metal hydroxide includes Ni element. An axial lattice constant c Å of the metal hydroxide satisfies: 0.363x+4.2≤c≤0.363x+4.4, where, based on a total molar mass of a metal element in the metal hydroxide, a molar percentage of the Ni element in the metal hydroxide is x. The lattice constant c of the metal hydroxide falls within a specified value range. The positive electrode material prepared from the metal hydroxide serving as a precursor is of excellent structural stability in a charging and discharging environment, and improves the cycle performance, high-temperature performance, and safety performance of lithium-ion batteries.

First claim

What is claimed is:

1 . A metal hydroxide, comprising Ni element; wherein based on a total molar mass of metal elements in the metal hydroxide, a molar percentage of the Ni element in the metal hydroxide is x, and an axial lattice constant c Å of the metal hydroxide satisfies: 0.363x+4.2≤c≤0.363x+4.4.

2 . The metal hydroxide according to claim 1 , wherein, a c/a ratio of the axial lattice constant c Å to an in-plane lattice constant a Å of the metal hydroxide satisfies: 1.48≤c/a≤1.50.

3 . The metal hydroxide according to claim 1 , wherein in a Raman spectrum of the metal hydroxide, a peak intensity in a range of 500 cm −1 to 530 cm −1 is I 1 , a peak intensity in a range of 3550 cm −1 to 3610 cm −1 is I 2 , and −4.32x+4≤I 1 /I 2 ≤−4.32x+6.

4 . The metal hydroxide according to claim 1 , wherein the metal hydroxide satisfies at least one of the following conditions:
(1) based on the molar mass of the metal elements in the metal hydroxide, the molar percentage of the Ni element in the metal hydroxide is greater than or equal to 50%; (2) the metal hydroxide further comprises Co element; and, based on the molar mass of the metal element in the metal hydroxide, a molar percentage of the Co element in the metal hydroxide is less than or equal to 50%; (3) the metal hydroxide further comprises Mn element; and, based on the molar mass of the metal element in the metal hydroxide, a molar percentage of the Mn element in the metal hydroxide is less than or equal to 50%; (4) the metal hydroxide further comprises an M element, the M element comprises at least one selected from the group consisting of Na, K, Sr, Ca, Al, Zr, Ti, W, Mg, Sn, Cu, Zn, Fe, Y, Mo, In, Pb, Sb, La, Ce, Yb, Sm, Gd, Sc, Cr, Ga, Ge, Ag, V, Nb, Ba, Ta, Hf, and Pr; and, based on the molar mass of the metal element in the metal hydroxide, a molar percentage of the M element in the metal hydroxide is less than or equal to 10%; or (5) the metal hydroxide comprises Ni x Co y Mn z M k (OH) 2 , wherein, 0.5≤x≤1, 0≤y≤0.5, 0≤z≤0.5, 0≤k≤0.1, and M comprises at least one selected from the group consisting of Na, K, Sr, Ca, Al, Zr, Ti, W, Mg, Sn, Cu, Zn, Fe, Y, Mo, In, Pb, Sb, La, Ce, Yb, Sm, Gd, Sc, Cr, Ga, Ge, Ag, V, Nb, Ba, Ta, Hf, and Pr.

5 . The metal hydroxide according to claim 1 , wherein the metal hydroxide satisfies at least one of the following conditions:
(a) an average particle size Dv 50 of the metal hydroxide satisfies: 1 μm≤Dv 50 ≤20 μm; or (b) the metal hydroxide comprises a secondary particle formed by agglomerating primary particles, and a length-to-diameter ratio of the primary particles is 4 to 14.

6 . A positive electrode material, wherein the positive electrode material comprises a lithium-nickel composite oxide, and an X-ray diffraction spectrum of the positive electrode material comprises a first diffraction peak, a second diffraction peak, and a third diffraction peak distributed sequentially from a low angle to a high angle in a range of 34° to 39°, and 0.25≤(a peak intensity of the second diffraction peak+a peak intensity of the third diffraction peak)/a peak intensity of the first diffraction peak≤0.5.

7 . The positive electrode material according to claim 6 , wherein the X-ray diffraction spectrum of the positive electrode material comprises a fourth diffraction peak in a range of 19° to 20° and a fifth diffraction peak in a range of 43° to 46°, and 1≤a peak intensity of the fourth diffraction peak/a peak intensity of the fifth diffraction peak≤1.5.

8 . The positive electrode material according to claim 6 , wherein, based on a mass of the positive electrode material, a mass percentage of residual lithium on a surface of the positive electrode material is m, m≤0.5%.

9 . The positive electrode material according to claim 6 , wherein, based on a molar mass of metal elements except Li in the positive electrode material, a molar percentage of Ni element in the positive electrode material is greater than or equal to 50%.

10 . The positive electrode material according to claim 6 , wherein the positive electrode material further comprises Co element; and, based on the molar mass of the metal elements except Li in the positive electrode material, a molar percentage of the Co element in the positive electrode material is less than or equal to 50%.

11 . The positive electrode material according to claim 6 , wherein the positive electrode material further comprises Mn element; and, based on the molar mass of the metal elements except Li in the positive electrode material, a molar percentage of the Mn element in the positive electrode material is less than or equal to 50%.

12 . The positive electrode material according to claim 6 , wherein the positive electrode material further comprises an M element; the M element comprises at least one selected from the group consisting of Na, K, Sr, Ca, Al, Zr, Ti, W, Mg, Sn, Cu, Zn, Fe, Y, Mo, In, Pb, Sb, La, Ce, Yb, Sm, Gd, Sc, Cr, Ga, Ge, Ag, V, Nb, Ba, Ta, Hf, and Pr; and, based on the molar mass of the metal elements except Li in the positive electrode material, a molar percentage of the M element in the positive electrode material is less than or equal to 10%.

13 . The positive electrode material according to claim 6 , wherein the positive electrode material comprises Li m Ni x Co y Mn z M k O 2+b R b , wherein 0.2≤m≤1.2, 0.5≤x<1, 0≤y≤0.5, 0≤z≤0.5, 0≤k≤0.1, and 0≤b≤0.1; M comprises at least one selected from the group consisting of Na, K, Sr, Ca, Al, Zr, Ti, W, Mg, Sn, Cu, Zn, Fe, Y, Mo, In, Pb, Sb, La, Ce, Yb, Sm, Gd, Sc, Cr, Ga, Ge, Ag, V, Nb, Ba, Ta, Hf, and Pr; and R comprises at least one selected from the group consisting of P, F, and N.

14 . An electrochemical device, comprising a positive electrode, wherein the positive electrode comprises a positive electrode material, wherein the positive electrode material comprises a lithium-nickel composite oxide; and an X-ray diffraction spectrum of the positive electrode material comprises a first diffraction peak, a second diffraction peak, and a third diffraction peak distributed sequentially from a low angle to a high angle in a range of 34° to 39°; and 0.25≤(a peak intensity of the second diffraction peak+a peak intensity of the third diffraction peak)/a peak intensity of the first diffraction peak≤0.5.

15 . The electrochemical device according to claim 14 , wherein the X-ray diffraction spectrum of the positive electrode material comprises a fourth diffraction peak in a range of 19° to 20° and a fifth diffraction peak in a range of 43° to 46°, and 1≤ a peak intensity of the fourth diffraction peak/a peak intensity of the fifth diffraction peak≤1.5.

16 . The electrochemical device according to claim 14 , wherein, based on a mass of the positive electrode material, a mass percentage of residual lithium on a surface of the positive electrode material is m, m≤0.5%.

17 . The electrochemical device according to claim 14 , wherein, based on a molar mass of metal elements except Li in the positive electrode material, a molar percentage of Ni element in the positive electrode material is greater than or equal to 50%.

18 . The electrochemical device according to claim 14 , wherein the positive electrode material further comprises Co element; and, based on the molar mass of the metal elements except Li in the positive electrode material, a molar percentage of the Co element in the positive electrode material is less than or equal to 50%.

19 . The electrochemical device according to claim 14 , wherein the positive electrode material further comprises Mn element; a

Assignees

• Ningde Amperex Technology Ltd

Inventors

• Cheng Shiyang
• Shitaba Jumpei
• Lang Ye

Classifications

• C01P2002/74

  by peak-intensities or a ratio thereof only · CPC title

• C01G53/506

  with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8 · CPC title

• C01G53/84

  Hydroxides · CPC title

• C01G53/05 Primary

  Hydroxides; Oxyhydroxides · CPC title

• H01M4/36

  Selection of substances as active materials, active masses, active liquids · CPC title